Light sensitive jet inks

• US 4,258,367 A
• Filed: 03/29/1979
• Issued: 03/24/1981
• Est. Priority Date: 03/29/1979
• Status: Expired due to Term

• Current Assignee: United States Gypsum Company (GEBR Knauf Verwaltungsgesellschaft KG)
• Original Assignee: The Whitaker Corporation (Meggitt PLC)
• Inventors: Mansukhani, Ishwar R.
• Primary Examiner(s): MILLER JR, GEORGE
• Application Number:
  US06/025,115
• Time in Patent Office: 726 Days
• Field of Search: 346/1, 346/75, 346/140 R
• US Class Current: 347/101
• CPC Class Codes: C09D 11/36 based on non-aqueous solvents
• CPC Class Codes: G01D 15/18 Nozzles emitting recording material

Abstract

Light sensitive ink compositions suitable for ink jet printing on metal, plastic, or paper surfaces, the ink characterized by opaque properties in light, incorporating in solution, at least one diazo derivative and at least one solvent.

According to another of its aspects, this invention is a process for information recording comprising producing a fine jet of liquid containing at least one diazo derivative, directing said jet of liquid onto a recording medium, modulating the density of said applied jet by an electric field in accordance with the information to be recorded, thereby recording said information, and thereafter applying ultraviolet light to said recording medium bearing said recorded information, thereby rendering said recording opaque.

Claims

1. A process for information recording comprising producing a fine jet of liquid containing a diazo light sensitive material, modulating the charge density of the jet by applying an electric field in accordance with the information to be recorded, directing the jet of liquid to a recording medium to record said informtion, and thereafter subjecting said recorded information to ultraviolet light, thereby rendering the information visible.

2. The process of claim 1 wherein the recorded information is subjected to ultraviolet light for from 1 to 95 seconds.

3. The process of claim 1 wherein the recorded information is exposed to an alkaline atmosphere after application of ultraviolet light.

4. The process of claim 1 wherein the liquid exhibits a viscosity of up to 25 cps. and a resistivity of under 10,000 ohm-cm.

5. A visibly colorless ink composition suitable for use in jet printing operations consisting essentially of a solution of the following components:

a. a visibly colorless diazo containing composition which decomposes to form a visible material in ultraviolet light, said diazo composition being present in an amount below about 90 weight percent, and

b. at least one solvent whereby the ink exhibits a viscosity of up to 25 cps. and exhibits a resistivity of up to 10,000 ohm-cm.

6. The composition of claim 5 wherein the colorless composition is a composition containing a diazo component, a coupling component and an acidic coupling inhibitor.

7. The composition of claim 5 wherein the diazo component has the formula ArNX, in which X represents a stabilizing anion, and Ar is selected from the group consisting of aryl, alkaryl and substituted ary and alkaryl substituents.

8. The composition of claim 7 containing a Lewis acid in the diazo component.

9. The composition of claim 5 wherein the solvent comprises a mixture of from 30 to 80% by weight of an aliphatic monovalent alcohol of from 1 to 8 carbon atoms and from 20 to 70% of a member selected from the group consisting of ketones, aldehydes, ethers, esters, hydrocarbons, glycols, glycol ethers, lactones and mixtures thereof.

10. The composition of claim 9 wherein the alcohol is present in a range of from 40 to 80% and the other solvent is present in a range of from 20 to 60%.