Iridium oxide based electrochromic devices

• US 4,258,984 A
• Filed: 09/14/1979
• Issued: 03/31/1981
• Est. Priority Date: 09/14/1979
• Status: Expired due to Term

• Current Assignee: Bell Telephone Laboratories, Inc. (Nokia Corporation)
• Original Assignee: Bell Telephone Laboratories, Inc. (Nokia Corporation)
• Inventors: Beni, Gerardo, Dautremont-Smith, William C., Schiavone, Lawrence M., Shay, Joseph L.
• Primary Examiner(s): Davie, James W.
• Application Number:
  US06/075,718
• Time in Patent Office: 564 Days
• Field of Search: 350/357, 29/570, 427/39, 427/58, 427/108, 427/109, 427/165, 427/166
• US Class Current: 359/273
• CPC Class Codes: G02F 1/15245 based on iridium oxide or hydroxide
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte

Abstract

Electrochromic devices based on electrochromic iridium oxide electrodes are disclosed. These electrodes are iridium oxide entities produced by vacuum deposition techniques such as by sputtering from an iridium target in the presence of an oxygen atmosphere. All solid state electrochromic devices utilizing such electrodes are possible.

Claims

1. A device comprising an electrochromic electrode and a counterelectrode in intimate contact with an electrolyte characterized in that said electrochromic electrode comprises a vacuum deposited iridium oxide film.

2. The device of claim 1 wherein said iridium oxide film is deposited on a conducting substrate.

3. The device of claim 2 wherein said conducting substrate comprises tantalum.

4. The device of claim 2 wherein said conducting substrate comprises indium tin oxide.

5. The device of claim 2 wherein said conducting substrate is said electrolyte.

6. The device of claim 1 wherein said electrolyte comprises perfluorosulfonic acid resin.

7. The device of claim 6 wherein said electrolyte is opacified.

8. The device of claim 1 wherein said iridium oxide film is a sputtered deposited film.

9. The device of claim 1 wherein said vacuum deposition is done in an environment comprising oxygen and an inert gas.