Dissolved oxygen probe

• US 4,259,165 A
• Filed: 12/10/1979
• Issued: 03/31/1981
• Est. Priority Date: 12/20/1978
• Status: Expired due to Term

• Current Assignee: Hokushin Electric Works Limited
• Original Assignee: Hokushin Electric Works Limited
• Inventors: Miyake, Yoshihiro
• Primary Examiner(s): Tung, T.
• Application Number:
  US06/102,148
• Time in Patent Office: 477 Days
• Field of Search: 204/1 P, 204/195 P
• US Class Current: 204/415
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

A probe submersible in a liquid to continuously analyze the concentration of a gas such as oxygen dissolved therein. The probe is constituted by a casing having an open mouth covered by a gas-permeable membrane to define a chamber filled with an electrolyte. Disposed within the chamber is a measuring electrode and a counter-electrode, the front face of the measuring electrode being slightly spaced from the rear surface of the membrane to create a gap that is filled by the electrolyte. Holes are formed in the measuring electrode to permit the passage of electrolyte between the front and rear faces thereof, the rear face being coated with an insulating layer to prevent an electrochemical reaction between this face and the electrolyte whereby the probe is then insensitive to dissolved gas contained in the electrolyte and responds only to gas contained in the liquid being analyzed. The walls of the holes may also be lined with an insulation layer for the same purpose.

Claims

1. A galvanic cell probe submersible in a liquid to continuously analyze the concentration of a gas, such as oxygen, dissolved therein, said probe comprising:

A a casing having an open mouth covered by a gas permeable membrane to define a chamber filled with an electrolyte;

B a measuring electrode disposed in said chamber with its front face closely adjacent the inner surface of the membrane to create a gap that is occupied by the electrolyte, said measuring electrode having holes therein to form an electrolyte passage between the front face and the rear face of the electrode, said rear face having an insulating layer thereon to prevent a reaction between the rear face and the electrolyte whereby the probe is rendered substantially insensitive to dissolved gas contained in the electrolyte and responds only to dissolved gas contained in the liquid being analyzed, said insulating layer having holes therein all of which being in registration with all of the holes in the measuring electrode on a one-to-one basis; and

C a counter-electrode disposed in said chamber whereby the current passing between the measuring electrode and the counter-electrode through said electrolyte as a result of galvanic action is a function of the concentration of dissolved gas in said liquid.

2. A probe as set forth in claim 1, wherein said holes are lined with an insulation layer.

3. A probe as set forth in claim 1, wherein said casing has a rear wall and said counter-electrode is mounted thereon.

4. A probe as set forth in claim 1, wherein said casing is cylindrical in form and said measuring electrode is a metal disc secured at its periphery to the inner wall of the casing adjacent the mouth thereof.

5. A probe as set forth in claim 1, wherein said casing is cylindrical in form and said measuring electrode is in the form of a dome whose rim is secured to said casing at the mouth thereof, said membrane having a form corresponding to that of said measuring electrode.