Method of pretreating raw water for reverse osmosis units

• US 4,261,833 A
• Filed: 05/19/1980
• Issued: 04/14/1981
• Est. Priority Date: 05/18/1979
• Status: Expired due to Term

• Current Assignee: L & C Steinmã¼Ller GmbH (Babcock Borsig AG)
• Original Assignee: L & C Steinmã¼Ller GmbH (Babcock Borsig AG)
• Inventors: Pohl, Kurt M., Winkler, Gerhard
• Primary Examiner(s): Therkorn, Ernest G.
• Application Number:
  US06/151,465
• Time in Patent Office: 330 Days
• Field of Search: 210/23 F, 210/23 H, 210/45, 210/46, 210/47, 210/51, 210/52, 210/53, 210/54, 210/73 R, 210/259, 210/321 R, 210/433 M, 210/78
• US Class Current: 210/639
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 2311/18 pH control
• CPC Class Codes: B01D 2311/2642 Aggregation, sedimentation, flocculation, precipitation or coagulation
• CPC Class Codes: B01D 61/025 Reverse osmosis; Hyperfiltration
• CPC Class Codes: B01D 61/04 Feed pretreatment
• CPC Class Codes: C02F 1/441 by reverse osmosis

Abstract

A method of pretreating raw water, for instance sea water, which is intended for supplying reverse osmosis units. An aqueous solution of acid salt and acid with the same anions is mixed with the raw water, whereby the most advantageous pH value is adjusted for the reverse osmosis, and whereby the acid salt is converted into the corresponding hydroxide. After possible addition of flocking or flaking additives, the resulting hydroxide flakes are separated, in a strongly concentrated form, by way of a centrifuge, particularly a plate or disc centrifuge, and together with fresh metal salt, are again brought into solution as a salt by means of the previously mentioned acid and, after mechanical purification in a second centrifuge, likewise particularly a plate or disc centrifuge, are again supplied to the raw water. The pretreated raw water leaves under pressure from the separator through which it flows and, alternatively, a chemical reducing agent may be added to this departing water flow. With a small requirement for metal salts, the recirculation can be eliminated. Also, the addition of the reducing agent to the pretreated raw water can be eliminated.

Claims

1. A method of pretreating raw water intended for supplying reverse osmosis units, said method including the steps of:

mixing with said raw water an aqueous solution, of acid salt and acid having the same anions, for the purpose of adjusting the pH value of said raw water to the value most advantageous to said reverse osmosis, and for converting said acid salt into flakes of the corresponding hydroxide;

centrifuging said solution to strongly concentrate said hydroxide flakes and to separate them from said solution;

redissolving said hydroxide flakes, along with fresh metallic salt, by means of said acid, as salt;

mechanically purifying said last mentioned solution solution in a second centrifuge;

repeating with this solution said steps of mixing said solution with said raw water and subsequently centrifuging said flakes and withdrawing said pretreated raw water; and

withdrawing said pretreated raw water from said centrifuge-separator under pressure.

2. A method according to claim 1, which includes, prior to said centrifuging step, the further step of adding a flocking additive to said solution for at least partially aggregating said hydroxide flakes.

3. A method according to claim 1, which includes the step of adding a chemical reducing agent to said withdrawn pretreated raw water.