Process for preparing a composite amphoteric ion exchange membrane

• US 4,262,041 A
• Filed: 02/02/1978
• Issued: 04/14/1981
• Est. Priority Date: 02/02/1978
• Status: Expired due to Term

• Current Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
• Original Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
• Inventors: Mori, Seiichi, Eguchi, Tamiyuki, Shimokawa, Masaaki
• Primary Examiner(s): Smith, Ronald H.
• Assistant Examiner(s): Page, Thurman K.
• Application Number:
  US05/874,687
• Time in Patent Office: 1,167 Days
• Field of Search: 260/2.2 R, 260/2.1 M, 260/2.1 E, 427/245, 427/340, 427/385 R, 210/500 M, 210/506, 521/27, 521/28, 521/32, 521/33
• US Class Current: 427/245
• CPC Class Codes: C08J 2327/06 Homopolymers or copolymers of vinyl chloride
• CPC Class Codes: C08J 5/2275 Heterogeneous membranes

Abstract

A process for preparing a composite amphoteric ion exchange membrane, which comprises forming a thin membrane not exceeding 5 microns thick by applying to a surface of a microporous polymer substrate having a physical, selective permeability of its own, a coating consisting of a polymer having either a cation or anion exchange group and a functional group capable of receiving another ion exchange group having an opposite sign from the cation or anion exchange group or a mixture of two polymers one of which has either a cation or an anion exchange group and the other of which has a functional group capable of receiving an ion exchange group having an opposite sign from the cation or anion exchange group, and introducing the ion exchange group having an opposite sign to said functional group to provide a ratio of anion to cation exchange capacity in the range of from 0.5 to 2.0.

Claims

1. A process for preparing a composite amphoteric ion exchange membrane, which comprises forming a thin membrane not exceeding 5 microns thick by applying to a microporous polymer substrate having a physical, selective permeability of its own, a coating consisting of a polymer having either a cation or anion exchange group and a functional group capable of receiving another ion exchange group having an opposite sign from the cation or anion exchange group or a mixture of two polymers one of which was either a cation or an anion exchange group and the other of which has a functional group capable of receiving an ion exchange group having an opposite sign from the cation or anion exchange group, and introducing the ion exchange group having an opposite sign to said functional group to provide a ratio of anion to cation exchange capacity in the range of from 0.5 to 2.0.

2. The process according to claim 1, wherein the ratio of anion to cation exchange capacity is in the range of from 0.67 to 1.5.

3. The process according to claim 2, wherein the ratio of anion to cation exchange capacity is in the range of from 0.8 to 1.25.

4. The process according to claim 1, wherein the microporous polymer substrate is coated with a composition containing a polymer having a quaternary ammonium group and a functional group capable of receiving a sulfonic acid group, the composition is cross-linked in the presence of concentrated sulfuric acid, and the introduction of the sulfonic acid group and cross-linking are simultaneously carried out in the presence of concentrates sulfuric acid.

5. The process according to claim 1, wherein the microporous polymer substrate is coated with a composition containing two polymers, one of which has a quaternary ammonium group and a functional group capable of being cross-linked in the presence of sulfuric acid and the other of which has a functional group capable of receiving a sulfonic acid group and a functional group capable of being cross-linked in the presence of sulfuric acid, the introduction of the sulfonic acid group and the cross-linking being simultaneously carried out in the presence of concentrated sulfuric acid.

6. The process according to claim 4, wherein the functional group capable of receiving a sulfonic acid group is a phenyl group and the functional group capable of being cross-linked is a phenyl group having attached thereto an alkyl halide group.

7. The process according to claim 5, wherein the functional group capable of receiving a sulfonic acid group is a phenyl group and the functional group capable of being cross-linked is a phenyl group having attached thereto an alkyl halide group.

8. The process according to claim 4, wherein a polystyrene in which some benzene rings have an alkyl halide group is modified to possess a quaternary ammonium group by the use of tertiary amine which reacts with a part of said alkyl halide group and the microporous polymer substrate is coated with the polymer thus modified.

9. The process according to claim 4, wherein the concentration of sulfuric acid is 90 percent by weight or more.

10. The process according to claim 5, wherein the concentration of sulfuric acid is 90 percent by weight or more.

11. The process according to claim 8, wherein the concentration of sulfuric acid is 94 to 97 percent by weight.

12. The process according to claim 1, wherein the anion is one member or a mixture of at least two members selected from the group consisting of a primary, a secondary and a tertiary ammonium group and the cation is carboxylic acid.

13. The process according to claim 1, wherein the microporous polymer substrate is polyvinyl chloride.

14. A process for preparing a composite amphoteric ion exchange membrane, which comprises forming a thin membrane not exceeding 5 microns thick by applying to a microporous polymer substrate having a physical, selective permeability of its own, a coating consisting of a polymer having an ion exchange group which is either a quaternary ammonium group or a sulfonic acid group and a functional group capable of receiving the other exchange group or of a mixture of two polymers one of which has an ion exchange group which is either a quaternary ammonium group or a sulfonic acid group and the other of which has a functional group capable of receiving the other exchange group;

and introducing said other ion exchange group to said functional group to provide a ratio of anion to cation exchange capacity in the range of 0.5 to 2.0.