Ion-selective electrode device for polarographic measurement of oxygen

• US 4,263,115 A
• Filed: 07/03/1978
• Issued: 04/21/1981
• Est. Priority Date: 07/03/1978
• Status: Expired

• Current Assignee: Max-Planck-Gesellschaft Zur Foerderung Der Wissenschaften e.V. (Max-Planck-Gesellschaft zur Frderung der Wissenschaften e)
• Original Assignee: Max-Planck-Gesellschaft Zur Foerderung Der Wissenschaften e.V. (Max-Planck-Gesellschaft zur Frderung der Wissenschaften e)
• Inventors: Kessler, Manfred, Hoper, Jens
• Primary Examiner(s): Williams, Howard S.
• Application Number:
  US05/921,259
• Time in Patent Office: 1,023 Days
• Field of Search: 204/195 P, 204/195 M, 204/195 L
• US Class Current: 204/418
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors
• CPC Class Codes: G01N 27/48 using polarography, i.e. measuring changes in current under a slowly-varying voltage

Abstract

An ion-selective electrode device for measuring oxygen concentrations comprises a noble metal reduction electrode connected to a voltage source; a reference electrode connected to said reduction electrode; an ion-selective carrier or ligand membrane disposed in front of the reduction electrode and containing a cation-selective ligand and being permeable to hydrogen ion; a closure membrane to seal the device against the outside atmosphere, the said closure membrane being permeable to oxygen and impermeable to water, and an electroyte containing the ligand cation of said ligand membrane, the said electrolyte being disposed between the said ligand membrane and said closure membrane.

Claims

1. An ion-selective electrode device for measuring oxygen concentrations comprising

a source of potential voltage;

a reduction electrode for the oxygen composed of a noble metal and connected to said voltage source;

a reference electrode annularly disposed about said reduction electrode;

a ligand membrane provided in front of the reduction electrode, the said ligand membrane containing a cation-selective carrier and being permeable to hydrogen ions;

a closure membrane to seal the said electrodes against the outside space, the closure membrane being permeable to oxygen and impermeable to water, and an aqueous electrolyte containing the ligand cation of the said ligand membrane, the said electrolyte being disposed between said ligand membrane and said closure membrane.

2. The device of claim 1 in which said ligand membrane is a solvent-impregnated PVC containing said ion-selective ligand.

3. The device of claim 2 in which the ion-selective ligand of the ligand membrane is Na⁺ selective and the solvent is dibenzylether.

4. The device of claim 2 in which the said ion selective cation ligand is K⁺ selective and the solvent is (bis- (2-ethylhexyl) phthalate).

5. The device of claim 1 in which the cation selective ligand is a molecule selected from the group consisting of

N,N,N,N-tetrabenzyl-3,6-dioxaoctane diamide, N,N'"'"'-dibenzyl-N,N'"'"'-diphenyl-1,2-phenylenedioxydiacetamide,

3,6-dioxaoctanediacid-bis-diphenylamine, and valinomycin.

6. The device of claim 1 in which the electrolyte consists of 0.1 M HCl and 0.01 M NaCl if the ligand membrane is Na⁺ sensitive and contains 0.1 M HCl and 0.01 M KCl if the reference electrode membrane contains a K⁺ sensitive molecule.

7. The device of claim 1 which includes an amplifier for indicating the measurement produced by the device, the said amplifier having an input resistance of 10¹² Ω

.

8. The device of claim 1 wherein the reduction electrode is composed of platinum.

9. The device of claim 1 wherein the closure membrane is of polymerized tetrafluoroethylene.

10. The device of claim 1, which includes a reference membrane disposed in front of the reference electrode and containing a ligand different from the cation ligand of said ligand membrane, and wherein said electrolyte is in contact with said ligand membrane and said closure membrane and contains the ligand of the reference membrane in addition to the ligand of the ligand membrane.

11. The device of claim 10, wherein the ion of the ligand membrane is Na⁺ and the ion of the reference membrane is K⁺ or reverse and wherein the electrolyte contains both the Na⁺ and K⁺ ions.

12. The device of claim 10 wherein the reference electrode is arranged in ring-shape around said reduction electrode.