Admixtures and method for accelerating the setting of portland cement compositions

• US 4,264,368 A
• Filed: 12/12/1977
• Issued: 04/28/1981
• Est. Priority Date: 04/07/1975
• Status: Expired due to Term

• Current Assignee: SIKA Chemical Corporation
• Original Assignee: SIKA Chemical Corporation
• Inventors: Schutz, Raymond J.
• Primary Examiner(s): Rutledge, L. Dewayne
• Assistant Examiner(s): Sheehan, John P.
• Application Number:
  US05/859,874
• Time in Patent Office: 1,233 Days
• Field of Search: 106/90, 106/315, 106/97
• US Class Current: 106/728
• CPC Class Codes: C04B 24/06 containing hydroxy groups
• CPC Class Codes: C04B 24/12 Nitrogen containing compounds organic derivatives of hydrazine hydrazine C04B22/00
• CPC Class Codes: C04B 28/04 Portland cements

Abstract

A method of and compositions for accelerating the setting time of portland cement compositions are disclosed. Certain α-hydroxy carbonyl compounds in particular ranges of concentrations relative to the cement are employed as accelerators. The concentration of admixture relative to cement necessary to achieve acceleration depends upon the identity of the admixture, the water-cement ratio, and the amount and type of aggregate in the composition, among other factors. The accelerators are especially useful in shotcrete applications.

Claims

1. A process of accelerating the setting time of a quantity of portland cement composition for a particular water-cement ratio, comprising the steps of:

(a) providing, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, lithium, zinc, and triethanolamine salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof; and

(b) admixing with said cement composition an amount of said α

-hydroxy carbonyl compound sufficient to accelerate the setting time of the portland cement composition, at such water-cement ratio, as compared with its setting time in the absence of any admixture.

2. The process according to claim 1 in which said chemical admixture, and portland cement are essentialy the only constituents of the composition influencing its setting time.

3. The process according to claim 1 in which said chemical admixture, portland cement, and water are essentially the only constituents of the composition influencing its setting time.

4. The process according to claim 3 in which the α

-hydroxy carbonyl compound is sodium hydroxyacetate.

5. The process according to claim 4 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in a range whereby the final setting time of the composition as measured by the Vicat Needle test is less than one hour.

6. The process according to claim 5 in which the portland cement composition includes a quantity of water to constitute a cement paste and the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 0.5 to about 10 weight percent.

7. The process according to claim 5 in which the portland cement composition includes quantities of water and aggregate to constitute a mortar or a concrete and the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

8. A process of accelerating the setting time of a quantity of an aggregate containing portland cement composition for a particular water-cement ratio, comprising the steps of:

(a) providing, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, lithium, zinc, and triethanolamine salts;

lactic acid and its sodium, potassium, and calcium salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof; and

(b) admixing with said cement composition an amount of said α

-hydroxy carbonyl compound sufficient to accelerate the setting time of the portland cement composition, at such water-cement ratio, as compared with its setting time in the absence of any admixture;

wherein said chemical admixture, portland cement aggregate, and water are essentially the only constituents of the composition influencing its setting time.

9. The process according to claim 8 in which the α

-hydroxy carbonyl compound is sodium lactate.

10. The process according to claim 8 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in a range whereby the final setting time of the composition as measured by the Vicat Needle test is less than one hour.

11. A process of preparing a quantity of portland cement composition for shotcreting, comprising the steps of:

(a) providing, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, calcium, lithium, zinc, and triethanolamine salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

(b) mixing portland cement, aggregate, and water to form a quantity of shotcrete having a particular water-cement ratio; and

(c) admixing with the portland cement, aggregate, and water an amount of said α

-hydroxy carbonyl compound sufficient to accelerate the final setting time as measured by the Proctor Needle test, at such water-cement ratio, to a value of less than fifteen minutes, the setting time of the shotcrete thereby being accelerated as compared with its setting time in the absence of any admixture.

12. The process according to claim 11 in which said chemical admixture, aggregate, water, and portland cement are essentially the only constituents of the composition influencing its setting time.

13. The process according to claim 12 in which the α

-hydroxy carbonyl compound is calcium hydroxyacetate.

14. The process according to claim 12 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

15. A process of preparing a quantity of portland cement composition for shotcreting, comprising the steps of:

(a) providing, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, lithium, zinc, and triethanolamine salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

(b) mixing portland cement, aggregate, and water to form a quantity of shotcrete having a particular water-cement ratio; and

(c) admixing with the portland cement, aggregate, and water an amount of said α

-hydroxy carbonyl compound sufficient to accelerate the final setting time as measured by the Proctor Needle test, at such water-cement ratio, to a value of less than fifteen minutes, the setting time of the shotcrete thereby being accelerated as compared with its setting time in the absence of any admixture.

16. The process according to claim 15 in which said chemical admixture, aggregate, water, and portland cement are essentially the only constituents of the composition influencing its setting time.

17. The process according to claim 16 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

18. A process of preparing a quantity of portland cement composition for shotcreting, comprising the steps of:

(a) providing, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, calcium, lithium, zinc, and triethanolamine salts;

lactic acid and its sodium, potassium, and calcium salts;

sodium 2-methyllacetate;

sodium dl-mandelate; and

mixtures thereof;

(b) mixing portland cement, aggregate, and water to form a quantity of shotcrete having a particular water-cement ratio; and

(c) admixing with the portland cement, aggregate, and water an amount of said α

-hydroxy carbonyl compound sufficient to accelerate the final setting time as measured by the Proctor Needle test, at such water-cement ratio, to a value of less than fifteen minutes, the setting time of the shotcrete thereby being accelerated as compared with its setting time in the absence of any admixture;

wherein said chemical admixture, aggregate, water, and portland cement are essentially the only constituents of the composition influencing its setting time.

19. The process according to claim 18 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

20. A portland cement concrete patching compound mixable with water to a selected water-cement ratio and comprising portland cement, aggregate, and, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, lithium, zinc, and triethanolamine salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

the concentration of the α

-hydroxy carbonyl compound relative to the cement being sufficient to accelerate the final setting time, as measured by the Vicat Needle test at such water-cement ratio, to a value of less than one hour, the setting time of the concrete patching compound thereby being accelerated as compared with its setting time in the absence of any admixture.

21. The portland cement conrete patching compound according to claim 20 in which said chemical admixture, aggregate, and portland cement are essentially the only constituents of the composition influencing its setting time.

23. The portland cement quick-setting-mortar compound according to claim 20 in which said chemical admixture, aggregate, and portland cement are essentially the only constituents of the composition influencing its setting time.

29. The portland cement concrete patching compound according to claim 20 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

22. A portland cement quick-setting-mortar compound mixable with water to a selected water-cement ratio and comprising portland cement, aggregate, and, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, calcium, lithium, zinc, and triethanolamine salts;

sodium 2-methyllacetate;

sodium dl-mandelate; and

mixtures thereof;

the concentration of the α

-hydroxy carbonyl compound relative to the cement being sufficient to accelerate the final setting time, as measured by the Vicat Needle test, at such water-cement ratio, to a value of less than thirty minuts, the setting time of the concrete patching compound thereby being accelerated as compared with its setting time in the absence of any admixture.

30. The portland cement quick-setting-mortar compound according to claim 22 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

24. A portland cement plugging compound mixable with water to a selected water-cement ratio and comprising portland cement, aggregate, and, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, calcium, lithium, zinc, and triethanolamine salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

the concentration of the α

-hydroxy carbonyl compound relative to the cement being sufficient to accelerate the final setting time, as measured by the Vicat Needle test, as such water-cement ratio, to a value of less than fifteen minutes, the setting time of the concrete patching compound thereby being accelerated as compared with its setting time in the absence of any admixture.

25. The portland cement plugging compound according to claim 24 in which said chemical admixture, aggregate, and portland cement are essentially the only constituents of the composition influencing its setting time.

31. The portland cement plugging compound according to claim 24 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

26. A portland cement concrete patching compound mixable with water to a selected water-cement ratio and consisting of portland cement, aggregate, and, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, lithium, zinc, and triethanolamine salts;

lactic acid and its sodium, potassium, and calcium salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

the concentration of the α

-hydroxy carbonyl compound relative to the cement being sufficient to accelerate the final setting time, as measured by the Vicat Needle test at such water-cement ratio, to a value of less than one hour, the setting time of the concrete patching compound thereby being accelerated as compared with its setting time in the absence of any admixture.

32. The portland cement concrete patching compound according to claim 26 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

27. A portland cement quick-setting-mortar compound mixable with water to a selected water-cement ratio and consisting of portland cement, aggregate, and, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, calcium, lithium, zinc, and triethanolamine salts;

lactic acid and its sodium, potassium, and calcium salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

the concentration of the α

-hydroxy carbonyl compound relative to the cement being sufficient to accelerate the final setting time, as measured by the Vicat Needle test, at such water-cement ratio, to a value of less than thirty minutes, the setting time of the quick-setting-mortar compound thereby being accelerated as compared with its setting time in the absence of any admixture.

33. The portland cement quick-setting-mortar compound according to claim 27 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

28. A portland cement plugging compound mixable with water to a selected water-cement ratio and consisting of portland cement, aggregate, and, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, calcium, lithium, zinc, and triethanolamine salts;

lactic acid and its sodium, potassium, and calcium salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

the concentration of the α

-hydroxy carbonyl compound relative to the cement being sufficient to accelerate the final setting time, as measured by the Vicat Needle test, at such water-cement ratio, to a value of less than fifteen minutes, the setting time of the plugging compound thereby being accelerated as compared with its setting time in the absence of any admixture.

34. The portland cement plugging compound according to claim 28 in which the concentration of the α

-hydroxy carbonyl compound relative to the cement is in the range of from about 1.1 to about 10 weight percent.

35. A process of accelerating the setting time of a quantity of portland cement composition for a particular water-cement ratio, comprising the steps of:

(a) providing, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, lithium, zinc, and triethanolamine salts;

lactic acid and its sodium, potassium, and calcium salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof; and

(b) admixing with said cement composition an amount of said α

-hydroxy carbonyl compound sufficient to accelerate the setting time of the portland cement composition, at such water-cement ratio, as compared

with its setting time in the absence of any admixture;

wherein the accelerated composition contains only noncaustic ingredients.

36. A portland cement concrete patching compound mixable with water to a selected water-cement ratio and consisting essentially of portland cement, aggregate, and, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, lithium zinc, and triethanolamine salts;

lactic acid and its sodium, potassium, and calcium salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

the concentration of the α

-hydroxy carbonyl compound relative to the cement being sufficient to accelerate the final setting time, as measured by the Vicat Needle test at such water-cement ratio, to a value of less than one hour, the setting time of the concrete patching compound thereby being accelerated as compared with its setting time in the absence of any admixture, the portland cement aggregate, and the α

-hydroxy carbonyl compound being the only constituents of the concrete patching compound influencing its setting time.

37. A portland cement quick-setting-mortar compound mixable with water to a selected water-cement ratio and consisting essentially of portland cement, aggregate, and, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, calcium, lithium, zinc, and triethanolamine salts;

lactic acid and its sodium, potassium, and calcium salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

the concentration of the α

-hydroxy carbonyl compound relative to the cement being sufficient to accelerate the final setting time, as measured by the Vicat Needle test, at such water-cement ratio, to a value of less than thirty minutes, the setting time of the quick-setting-mortar compound thereby being accelerated as compared with its setting time in the absence of any admixture, the portland cement aggregate, and the α

-hydroxy carbonyl compound being the only constituents of the quick-setting-mortar compound influencing its setting time.

38. A portland cement plugging compound mixable with water to a selected water-cement ratio and consisting essentially of portland cement, aggregate, and, as a chemical admixture, an α

-hydroxy carbonyl compound selected from the group consisting of hydroxyacetic acid and its sodium, potassium, calcium, lithium, zinc, and triethanolamine salts;

lactic acid and its sodium, potassium, and calcium salts;

sodium 2-methyllactate;

sodium dl-mandelate; and

mixtures thereof;

the concentration of the α

-hydroxy carbonyl compound relative to the cement being sufficient to accelerate the final setting time, as measured by the Vicat Needle test, at such water-cement ratio, to a value of less than fifteen minutes, the setting time of the plugging compound thereby being accelerated as compared with its setting time in the absence of any admixture, the portland cement aggregate, and the α

-hydroxy carbonyl compound being the only constituents of the plugging compound influencing its setting time.