Spent brine concentration using microwave energy

• US 4,267,026 A
• Filed: 12/21/1979
• Issued: 05/12/1981
• Est. Priority Date: 12/21/1979
• Status: Expired due to Term

• Current Assignee: OLIN Corporation
• Original Assignee: OLIN Corporation
• Inventors: Patel, Harshad M.
• Primary Examiner(s): Andrews, R. L.
• Application Number:
  US06/106,180
• Time in Patent Office: 508 Days
• Field of Search: 203/100, 204/48, 204/128
• US Class Current: 205/536
• CPC Class Codes: C01D 3/04 Chlorides
• CPC Class Codes: C25B 15/08 Supplying or removing reactants or electrolytes; Regeneration of electrolytes
• CPC Class Codes: Y10S 203/11 Batch distillation

Abstract

A process for the concentration of spent brine from the membrane electrolytic cell which comprises removing spent brine containing dissolved chlorine from the membrane electrolytic cell, feeding the spent brine to a concentration zone, applying microwave energy to the spent brine to produce concentrated brine and a gaseous mixture of chlorine and steam, feeding the concentrated brine and the gaseous mixture to a separation zone, separating the gaseous mixture from the concentrated brine, and returning the concentrated brine to the membrane electrolytic cell.

Process reduces the operating and equipment costs while effectively recovering chlorine and brine values.

Claims

1. A process for the concentration of spent brine from a membrane electrolytic cell which comprises:

(a) removing spent brine containing dissolved chlorine and from about 14 to about 22 percent by weight of NaCl from said membrane electrolytic cell,

(b) feeding said spent brine to a concentration zone,

(c) applying microwave energy to said spent brine to produce concentrated brine and a gaseous mixture of chlorine and steam,

(d) feeding said concentrated brine and said gaseous mixture to a separation zone,

(e) separating said gaseous mixture from said concentrated brine, and

(f) returning said concentrated brine containing from about 23 to about 26 percent by weight of NaCl to said membrane electrolytic cell.

2. The process of claim 1 in which said microwave energy is applied at a frequency of from about 100 to about 10,000 mHz.

3. The process of claim 2 in which said concentrated brine constitutes from about 30 to about 90 percent by volume of the total amount of brine returned to said membrane electrolytic cell.

4. The process of claim 2 in which said microwave energy is applied for a period of from about 1 to about 120 minutes.