Biological sludge-energy recycling method

• US 4,267,049 A
• Filed: 06/27/1979
• Issued: 05/12/1981
• Est. Priority Date: 02/13/1978
• Status: Expired due to Term

• Current Assignee: Waste-Energy Corporation
• Original Assignee: Howard E. Worne, Lennart G. Erickson
• Inventors: Erickson, Lennart G., Worne, Howard E.
• Primary Examiner(s): Castel, Benoit
• Application Number:
  US06/052,644
• Time in Patent Office: 685 Days
• Field of Search: 210/2-12, 210/15, 210/18, 210/38 B, 210/51, 210/54, 210/57-59, 210/65-67, 210/73 S, 210/74, 426/59, 426/52, 426/53, 426/54, 435/253, 435/804, 71/12-14
• US Class Current: 210/606
• CPC Class Codes: A23K 10/10 obtained by microbiological or biochemical processes using chemicals or microorganisms for ensilaging of green fodder A23K30/15
• CPC Class Codes: C02F 1/5272 using specific organic precipitants
• CPC Class Codes: C02F 11/004 Sludge detoxification
• CPC Class Codes: C02F 11/12 by de-watering, drying or thickening
• CPC Class Codes: C02F 2303/06 Sludge reduction, e.g. by lysis
• CPC Class Codes: C02F 3/12 Activated sludge processes
• CPC Class Codes: C02F 3/34 characterised by the microorganisms used
• CPC Class Codes: C02F 9/00 Multistage treatment of water, waste water or sewage
• CPC Class Codes: C05F 17/20 using specific microorganisms or substances, e.g. enzymes, for activating or stimulating the treatment use of invertebrates C05F17/05
• CPC Class Codes: C05F 17/40 Treatment of liquids or slurries
• CPC Class Codes: C05F 17/80 Separation, elimination or disposal of harmful substances during the treatment
• CPC Class Codes: C05F 7/00 Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
• CPC Class Codes: Y02A 40/20 Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
• CPC Class Codes: Y02P 20/145 the feedstock being materials of biological origin
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y02W 30/40 Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
• CPC Class Codes: Y10S 210/912 Heavy metal

Abstract

A method is described for converting treated sludge into an improved concentrated organic feedstock. The method includes conditioning of sludge with hydrolytic enzymes, the mechanical disintegration of tissue and cell components, the removal of heavy metals, autolysis and dewatering to produce an organic fertilizer or feedstock. Product stabilization for long-term storage is achieved by acidification or addition of granular sorbents. Agricultural fertilizers are produced from input raw material such as sludge from municipal waste-water treatment facilities or sludge from biological processing of other organic wastes. Animal feed protein concentrates are produced from cultured cellular biomass sludge inputs. The separated heavy metals fraction may be refined to recover individual minerals. Energy usually expended for disposal of sludge as wastes may be applied to recycling such sludge into useful products of this invention. The commercial equivalents of these products usually are manufactured from petrochemical and other primary energy resources.

Claims

1. A method for converting treated sludge into useful substances, the method comprising the steps of:

hydrolyzing organic materials present in the sludge by adding to the sludge at least one of hydrolytic enzymes and hydrolytic enzyme producing microorganisms;

thereafter disintegrating organic cells present in the sludge into organic particles to thereby form a colloidal slurry including the particles;

holding at least one of the sludge, including the enzymes or the microorganisms, and the slurry, including the particles; and

thereafter separating the slurry into an effluent and a moist product including the organic particles and adapted for a relatively rapid metabolization by living organisms.

2. A method according to claim 1 wherein the step of holding comprises holding the slurry after the step of disintegrating so that the hydrolytic enzymes in the slurry and endocellular enzymes released into the slurry by the organic cells during the step of disintegrating further hydrolyze the particles.

3. A method according to claim 2 wherein the step of holding the slurry is carried out for no more than about 12 hours.

4. A method according to claim 3 wherein the step of holding the slurry is carried out for at least about six hours.

5. A method according to claim 3 including the step of maintaining the temperature of the slurry during the holding step in the range of between about 16°

C. to about 40°

C.

6. A method according to claim 1 wherein the step of holding comprises holding the sludge for no more than about two hours after the step of adding and prior to the step of disintegrating the cells.

7. A method according to claim 6 including the step of maintaining the temperature of the sludge during the holding step at between about 16°

C. to about 40°

C.

8. A method according to claim 7 wherein the temperature is held at about 37°

C.

9. A method according to claim 6 wherein the step of holding the sludge is carried out for between about one to about two hours.

10. A method according to claim 1 including the step of adding to the product an edible acid in an amount sufficient to inhibit microbial and pathogenic activity during storage and transport of the product .

11. A method according to claim 10 including the step of utilizing the acidified product as a fertilizer.

12. A method according to claim 10 including the step of utilizing the acidified product as a feed supplement.

13. A method according to claim 1 including the step of adding to the product a sufficient amount of a sorbent material to reduce the moisture content of the product to a level at which bacteria and pathogens are prevented from being further hydrolyzed by enzymes present in the product.

14. A method according to claim 13 including the step of using the product including the sorbent material as a fertilizer.

15. A method according to claim 13 including the step of using the product including the sorbent material as a feed supplement.

16. A method according to claim 1 including the step of contacting the slurry with a metal chelating substrate after the step of disintegrating to remove heavy metals therefrom.

17. A method for converting organic cells and other substances in treated sludge into a readily metabolizable product comprising the steps of:

adding to the sludge hydrolytic enzymes to hydrolyze the organic cells and other hydrolyzable substances in the sludge;

rupturing the hydrolyzed cells after the step of adding to form a colloidal slurry including ruptured organic cell particles and to thereby release into the colloidal slurry endocellular enzymes present in the cells;

holding the colloidal slurry for a sufficient length of time so that the hydrolytic enzymes and the endocellular enzymes further hydrolyze organic substances in the slurry and thereby form a readily dewaterable, substantially gel free microparticulate slurry; and

thereafter dewatering the microparticulate slurry to form a moist product comprising microparticulate, organic substances.

18. A method according to claim 17 including the step of inhibiting microbial and pathogenic activity in the product during storage and shipment of the product prior to its use.

19. A method according to claim 17 wherein the treated sludge comprises a cellular biomass substantially free of heavy metals, and including the step of using the product as an animal feed supplement.

20. A method according to claim 17 wherein the step of holding the colloidal slurry in a tank is carried out for no more than about 12 hours and maintaining the temperature of the colloidal slurry in the tank at no more than about 40°

C.

21. A method according to claim 17 wherein the step of adding comprises the steps of adding to the sludge a substance comprising hydrolytic enzymes, thereafter holding the sludge for up to about two hours, and maintaining the temperature of the sludge during its holding step in the range of between about 16°

C. to about 40°

C.

22. A method according to claim 17 wherein the step of adding hydrolytic enzymes comprises the steps of adding to the sludge hydrolytic enzyme producing microorganisms.

23. A method for converting treated sludge into a readily metabolizable product comprising the steps of:

contacting the sludge with hydrolytic enzymes to hydrolyze organic cells in the sludge and thereby to make them more susceptible to rupture when subjected to mechanical forces by adding to the sludge a substance capable of providing the sludge with hydrolytic enzymes;

thereafter rupturing the cells in the sludge to form a colloidal slurry including ruptured organic cell particles, endocellular enzymes and gelled substances released by the cells during their rupture;

holding at least one of the sludge, including the enzymes, and the slurry, including the particles; and

thereafter separating the slurry into an effluent and a moist product.

24. A method according to claim 23 wherein the step of separating includes the step of dewatering the slurry to form the moist product comprising the ruptured cell particles, and wherein the step of holding the slurry is carried out for up to about 12 hours prior to the step of dewatering to thereby further hydrolyze the particles and gelled substances present in the slurry to facilitate the dewatering step.

25. A method according to claim 24 wherein the step of holding is performed no later than about 20 hours after the step of contacting.

26. A method for converting organic cells and other organic substances in treated sludge into a readily metabolizable product comprising the steps of:

adding hydrolytic enzymes or hydrolytic enzyme producing microorganisms to the sludge and holding the sludge including enzymes for a sufficient length of time to hydrolyze the polysaccharide slime coating on the cells, to release into the sludge any heavy metal ions occluded in the coating, and to soften the walls of the cells;

rupturing the cells in the sludge to form a colloidal slurry comprising ruptured cell particles, heavy metal ions endocellular enzymes released by the cells during their rupture and a gel;

thereafter, autolyzing the colloidal slurry by holding it in a tank for a sufficient length of time to permit enzymes present in the colloidal slurry to hydrolyze the particles and the gel and form a microparticulate slurry including the ruptured cell particles; and

thereafter dewatering the microparticulate slurry to form a substantially clear effluent and a moist product comprising the ruptured cell particles previously present in the microparticulate slurry.

27. A method according to claim 26 including the step of removing from the slurry heavy metals present therein by contacting the slurry with a metal chelating substrate.

28. A method for processing treated sludge including organic cells and heavy metals to recover therefrom usable materials comprising the steps of:

adding to the sludge hydrolytic enzymes;

holding the sludge and the added enzymes for a sufficient length of time to at least partially hydrolyze the walls of the cells and any polysaccharide slime coating present on the cells;

thereafter rupturing the cells in the sludge to form a collodial slurry including ruptured cell particles and a gel and to thereby further release into the collodial slurry endocellular enzymes present in the cells;

contacting the slurry with a metal chelating substrate to remove heavy metals therefrom;

further hydrolyzing organic substances in the colloidal slurry by holding the slurry in a tank for sufficient length of time to hydrolyze the particles and the gel and to thereby form a microparticulate slurry;

dewatering the microparticulate slurry and collecting a moist product;

storing the product;

preventing decomposition of the product by inhibiting microbial and pathogenic activity in the product being stored; and

thereafter using the product as a readily metabolizable substance for living organisms.

29. A method according to claim 28 including the step of holding the slurry in a tank for a length of time which exceeds the length of time for which the sludge is held.

30. A method according to claim 29 wherein the step of preventing decomposition of the product comprises the step of acidifying the product to a pH of between about 3 to about 3.5.

31. A method according to claim 28 including the step of adjusting the pH of the sludge to between about 6.5 to about 7.2.