Magnetic glassy metal alloy sheets with improved soft magnetic properties

• US 4,268,325 A
• Filed: 01/22/1979
• Issued: 05/19/1981
• Est. Priority Date: 01/22/1979
• Status: Expired due to Term

• Current Assignee: Allied Chemical Corporation (Honeywell International Inc.)
• Original Assignee: Allied Chemical Corporation (Honeywell International Inc.)
• Inventors: O'Handley, Robert C., Sullivan, Michael O.
• Primary Examiner(s): Rutledge, L. Dewayne
• Assistant Examiner(s): Sheehan, John P.
• Application Number:
  US06/005,045
• Time in Patent Office: 848 Days
• Field of Search: 148/103, 148/108, 148/31.55, 148/31.57
• US Class Current: 148/108
• CPC Class Codes: C21D 1/04 with simultaneous application of supersonic waves, magnetic or electric fields
• CPC Class Codes: C22C 45/008 with Fe, Co or Ni as the major constituent C22C45/02, C22C45/04 take precedence
• CPC Class Codes: H01F 1/153 Amorphous metallic alloys, e.g. glassy metals making ferrous amorphous alloys C22C33/003

Abstract

A magnetic glassy metal alloy sheet is annealed at elevated temperature in a first magnetic field oriented in a direction substantially normal to the plane of the sheet. A second anneal may be performed in a weaker magnetic field in a direction substantially normal to the first field to minimize AC hysteresis losses. The annealed magnetic glassy metal alloy sheet has improved soft magnetic properties such as low hysteresis losses and may be used for transformer cores and the like.

Claims

1. In a method of annealing a magnetic glassy metal alloy sheet by heat treatment in a magnetic field, the improvement comprising applying a magnetic field of at least about 1,000 Oersteds at an elevated temperature ranging from above about 225°

C. to below the glass transition temperature of said metal alloy in a direction substantially normal to the sheet surface to induce a magnetization inside the sheet essentially in said direction, whereby said alloy remains glassy after said annealing.

2. The improvement in a method as set forth in claim 1 wherein the glassy metal alloy sheet has a permeability of at least about 1,000 at an induction of from about 10 to 100 Gauss.

3. The improvement in a method as set forth in claim 2 further comprising applying sequentially a second magnetic field weaker than the first field in a direction substantially normal to the first field.

4. The improvement in a method as set forth in claim 3 wherein the fields are pulsating with the first and second field pulses staggered in time.

5. The improvement in a method as set forth in claim 3 wherein the second field is applied successively to the first field.

6. The improvement in a method as set forth in claim 5 wherein the application of the second field is repeated.

7. The improvement in a method as set forth in claim 5 wherein the second field is applied at a temperature between about 25°

C. and 100°

C. lower than the elevated temperature.

8. The improvement in a method as set forth in claim 7 wherein the temperature employed during application of the second field is lowered at a rate of between about 10°

C./min and 1°

C./hour.

9. The improvement in a method as set forth in claim 3 wherein the strength of the second magnetic field is at least about 0.1 oersted.

10. The improvement in a method as set forth in claim 9 wherein the strength of the second magnetic field is between about 1 and 10 oersteds.

11. The improvement in a method as set forth in claim 1 wherein the elevated temperature is above said Curie temperature of the glassy metal alloy employed.

12. The improvement in a method as set forth in claim 1 wherein the magnetic field in oersteds is at least about 1.1 times of the saturation induction in Gauss of the magnetic glassy alloy at the elevated temperature.

13. The improvement in a method as set forth in claim 1 wherein the applied magnetic field induces an internal magnetic field of at least about 1 Oersted in the magnetic glassy metal.

14. The improvement in a method as set forth in claim 1 wherein the glassy metal alloy sheet consists essentially of about 70 to 90 atom percent of at least one metal selected from the group consisting of iron and cobalt, up to about 3/4 of which may be replaced by nickel, and up to one quarter of which may be replaced by at least one metal selected from the group consisting of vanadium, chromium, manganese, copper, molybdenum, niobium, tantalum and tungsten, and the balance at least one metalloid selected from the group consisting of boron, carbon and phosphorus, up to about 3/5 of which may be replaced by silicon, and up to about 1/3 of which may be replaced by aluminum, plus incidental impurities.

15. A magnetic glassy metal alloy sheet produced by the method of claim 1, wherein the coefficient of the parallel contribution to the free magnetic energy density is about equal to the coefficient of the normal contribution to the free magnetic energy density, said sheet consisting essentially of about 70 to 90 atom percent of at least one metal selected from the group consisting of iron and cobalt, up to about 3/4 of which may be replaced by nickel, and up to 1/4 of which may be replaced by at least one metal selected from the group consisting of vanadium, chromium, maganese, copper, molybdenum, niobium, tantalum and tungsten, and the balance at least one metalloid selected from the group consisting of boron, carbon and phosphorus, up to about 3/5 of which may be replaced by silicon and up to about 1/3 of which may be replaced by aluminum plus incidental impurities.