Radioactivation method for simultaneous determination of nitrogen, phosphorus and potassium content in plants and fertilizers

• US 4,268,754 A
• Filed: 04/09/1979
• Issued: 05/19/1981
• Est. Priority Date: 04/09/1979
• Status: Expired due to Term

• Current Assignee: Alexandr V. Sidorov, Igor B. Saveliev, Jury L. Kovtun, Kim S. Tsagolov, Nadezhda N. Miroshnikova, Rigo A. Srapeniants
• Original Assignee: Alexandr V. Sidorov, Igor B. Saveliev, Jury L. Kovtun, Kim S. Tsagolov, Nadezhda N. Miroshnikova, Rigo A. Srapeniants
• Inventors: Sidorov, Alexandr V., Kovtun, Jury L., Saveliev, Igor B., Miroshnikova, Nadezhda N., Srapeniants, Rigo A., Tsagolov, Kim S.
• Primary Examiner(s): Smith, Alfred E.
• Assistant Examiner(s): Howell, Janice A.
• Application Number:
  US06/028,397
• Time in Patent Office: 771 Days
• Field of Search: 250/253, 250/390, 250/391, 250/392, 176/19 R
• US Class Current: 250/391
• CPC Class Codes: G01N 2223/0745 neutron-gamma activation analysis
• CPC Class Codes: G01N 2223/302 comparative arrangements
• CPC Class Codes: G01N 2223/612 biological material
• CPC Class Codes: G01N 23/222 using neutron activation analysis [NAA]

Abstract

According to the invention, the radioactivation method for simultaneous determination of the nitrogen, phosphorus and potassium content in plants and fertilizers consists in exposing samples to be analyzed and standard samples to neutron irradiation and recording the spectra of the gamma radiation induced in said samples, whereupon the samples are laid aside for a period of time determined by the half-life of the interfering isotope. This is followed by again recording the spectra of the samples being analyzed and of the standard samples and superposing the first and second spectra of the samples being analyzed and of the standard samples. These spectra are then shifted relative to each other along the energy axis, and the contents of the elements being analyzed are determined by thus comparing the spectra of the samples being analyzed and of the standard samples.

Claims

1. A radioactivation method for simultaneous determination of the nitrogen, phosphorus and potassium content in plants and fertilizers which also contain isotopes which interfere with gamma radiation analysis, said isotopes having a specific half-life, which comprises exposing samples to be analyzed and standard samples to neutron irradiation to induce gamma radiation which is plotted as a spectrum of gamma radiation energy in proportion to number of pulses of the neutron irradiation, recording the spectra of gamma radiation induced in said samples, setting said samples aside for a period of time corresponding to the half-life of the interfering isotope, again exposing said samples being analyzed and said standard samples to neutron irradiation and recording the resulting spectra of gamma radiation, superposing the first and second spectra of the samples being analyzed and standard samples and shifting the same relative to each other along the energy axis, and comparing the spectra of the samples being analyzed and the standard samples to determine the content of the elements being analyzed.