Self-contained gaseous contaminant dosimeter

• US 4,269,804 A
• Filed: 12/03/1979
• Issued: 05/26/1981
• Est. Priority Date: 08/24/1979
• Status: Expired due to Term

• Current Assignee: Pro-Tek Systems Incorporated
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Kring, Elbert V.
• Primary Examiner(s): Marcus, Michael S.
• Application Number:
  US06/099,704
• Time in Patent Office: 540 Days
• Field of Search: 422/61, 422/83-88, 422/119, 23/232 R, 73/23, 73/421.5, 116/206, 55/16, 55/158
• US Class Current: 422/86
• CPC Class Codes: G01N 31/223 for investigating presence of specific gases or aerosols G01N31/221, G01N31/222 take precedence; actuation of fire alarm by presence of smoke or gases G08B17/10
• CPC Class Codes: Y10S 436/902 Dosimeter
• CPC Class Codes: Y10T 436/175383 Ammonia
• CPC Class Codes: Y10T 436/178459 Only nitrogen dioxide
• CPC Class Codes: Y10T 436/186 Sulfur dioxide

Abstract

A personal dosimeter for measuring the average concentration of a gaseous contaminant over a given period of time is provided. The dosimeter comprises a sealed pouch having a reaction chamber, which contains a gas-collecting medium, and at least one compartment. Each compartment can be separately sealed and can contain a different reagent, the seals being individually breakable such that the reagents can be separately released into the reaction chamber. Into the pouch is sealed a gas diffusion device that permits the contaminant to diffuse into the reaction chamber where it is collected in proportion to its ambient concentration.

Claims

1. A personal dosimeter for measuring the average concentration of a gaseous contaminant over a given period of time comprising:

a pouch-like receptacle of polymeric material having at least one compartment, the compartment occupying less than the total volume of the receptacle, leaving a reaction chamber, the compartment containing a pre-determined quantity of a color-forming reagent and being adapted to release the reagent into the reaction chamber independently of any other reagents present in any other compartments, and the reaction chamber containing a collecting medium for the gaseous contaminant; and

a gas diffusion device which is sealed into a boundary of the receptacle and through which the contaminant diffuses at a rate in linear proportion to its concentration in the atmosphere, the diffusion device providing the only communication between the atmosphere and the interior of the reaction chamber.

2. The dosimeter of claim 1 in which the gas diffusion device contains a plurality of through-and-through channels by which said communication is provided.

3. The dosimeter of claim 2 in which there are 5-500 channels, each having a diameter of 50-1000 microns and a length of 1.0-25.0 mm.

4. The dosimeter of claim 1 in which the gas diffusion device is a membrane through which the gaseous contaminant passes at a rate in linear proportion to its concentration in the atmosphere.

5. The dosimeter of claim 4 in which the membrane is constructed of silicone rubber, polytetrafluoroethylene, or copolymers of silicone and polycarbonate.

6. The dosimeter of claim 1, 2, 3, 4, or 5 wherein the collecting medium is in the form of an absorbing solution.

7. The dosimeter of claim 6 wherein the absorbing solution is for sulfur dioxide, nitrogen dioxide, or ammonia.

8. The dosimeter of claim 7 further containing at least one color-forming reagent.

9. The dosimeter of claim 8 wherein the absorbing solution is a solution of sodium tetrachloromercurate or potassium tetrachloromercurate in water and the reagent is for determining the presence of sulfur dioxide.

10. The dosimeter of claim 8 wherein the absorbing solution is a solution of triethanol amine in water and the reagent is for determining the presence of nitrogen dioxide.

11. The dosimeter of claim 8 wherein the absorbing solution is a solution of sulfuric acid in water and the reagent is for determining the presence of ammonia.