Glass fibers for optical transmission

• US 4,270,840 A
• Filed: 05/25/1979
• Issued: 06/02/1981
• Est. Priority Date: 05/25/1978
• Status: Expired due to Term

• Current Assignee: Nippon Telegraph and Telephone Corporation
• Original Assignee: Nippon Telegraph and Telephone East Corporation (Nippon Telegraph and Telephone Corporation), Sumitomo Electric Industries Limited (Sumitomo Corporation)
• Inventors: Uchida, Naoya, Yamanishi, Toru, Yoshimura, Kozo, Seikai, Shigeyuki
• Primary Examiner(s): KENDELL, LORRAINE
• Application Number:
  US06/042,649
• Time in Patent Office: 739 Days
• Field of Search: 428/375, 428/378, 428/391, 428/392, 428/429, 427/163, 65/36, 350/96.23, 350/96.30, 350/96.33, 350/96.34
• US Class Current: 385/141
• CPC Class Codes: C03C 25/1065 Multiple coatings
• CPC Class Codes: G02B 6/02395 Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture G02B6/02052, G02B6/02057, G02B6/024, G02B6/032, G02B6/105, G02B6/14 take precedence; coating on fibre gratings G02B6/02104; multilayer core or cladding G02B6/036; reinforcing splice joints G02B6/2558; optical cables, i.e. comprising protective structures external to the protective coating such as a jacket or plural coated optical fibres G02B6/44; coating of glass to obtain optical fibres C03C25/104
• CPC Class Codes: G02B 6/03627 arranged - +
• CPC Class Codes: G02B 6/03644 arranged - + -
• CPC Class Codes: G02B 6/03677 arranged - + + -
• CPC Class Codes: G02B 6/03694 Multiple layers differing in properties other than the refractive index, e.g. attenuation, diffusion, stress properties
• CPC Class Codes: G02B 6/4402 with one single optical waveguide G02B6/4429, G02B6/4439, G02B6/4479 take precedence
• CPC Class Codes: Y10T 428/2962 Silane, silicone or siloxane in coating
• CPC Class Codes: Y10T 428/2964 Artificial fiber or filament

Abstract

A reinforced glass fiber for use in optical transmission comprising an optical fiber coated with (1) a coating of a first curable organopolysiloxane composition having a refractive index higher than that of the clad glass which forms the outermost layer of the optical fiber, said first curable organopolysiloxane composition being baked, (2) a coating of a second curable organopolysiloxane composition which can be the same as or different from the first curable organopolysiloxane composition, the second curable organopolysiloxane composition being provided on the first curable organopolysiloxane composition and being baked, and (3) optionally a coating of a thermoplastic resin composition.

Claims

1. A reinforced glass fiber for use in optical transmission comprising an optical fiber having provided thereon (1) a coating of a first curable organopolysiloxane composition having a refractive index higher than the glass which forms the outermost layer of the glass fiber, said first curable organopolysiloxane composition being baked to cure the same, and (2) a coating of a second organopolysiloxane composition which can be the same as or different from the first curable organopolysiloxane composition, said second curable organopolysiloxane composition then being provided on the first curable organopolysiloxane and being baked to cure the same, wherein at least one of the first and second curable organopolysiloxane compositions has a stress absorbing effect and a Young'"'"'s modulus lower than 2.0 kg/mm² at room temperature.

2. The glass fiber of claim 1, wherein at least the first curable organopolysiloxane composition is a phenyl polysiloxane composition.

3. The glass fiber of claim 1, wherein at least one of the first and second curable organopolysiloxane compositions is a photosetting curable organopolysiloxane composition.

4. The glass fiber of claim 1, wherein the second curable organopolysiloxane composition is a dimethyl polysiloxane composition.

5. The glass fiber of claim 1, wherein the second curable organopolysiloxane composition has a multilayer structure composed of the same or different materials.

6. The glass fiber of claim 1, wherein a coating of thermoplastic resin composition is provided on said second curable organopolysiloxane composition.

7. The glass fiber of claim 1, wherein said second curable organopolysiloxane composition is the same as said first curable organopolysiloxane composition.

8. The glass fiber of claim 1, wherein said second curable polyorganopolysiloxane composition is different from said first curable organopolysiloxane composition.

9. The glass fiber of claim 2, wherein said phenylpolysiloxane composition comprises:

(i)(a) a component of the formula ##STR7## (i)(b) a component of the formula ##STR8## a component of the formula ##STR9## wherein R is a substituted or unsubstituted monovalent hydrocarbon group having a aliphatic unsaturation, (ii) an organohydrodiene polysiloxane component having in its molecule at least 3 hydrogen atoms directly bonded to a silicon atom in an amount sufficient to provide 0.7 to 5 such hydrogen atoms per vinyl group of the component (i), and (iii) a catalytic amount of a platinum compound, wherein m and n are positive integers such that the phenylpolysiloxane composition has a refractive index of about 1.40 to about 1.52 and a viscosity at 25°

C. of from 50 to 100,000 centistokes.

10. The glass fiber of claim 9, wherein said second curable organopolysiloxane composition has a refractive index lower than that of glass and comprises (i) a component of the formula ##STR10## wherein R is a substituted or unsubstituted mono-valent hydrocarbon group having no aliphatic unsaturation, (ii) an organohydrodiene polysiloxane component having in its molecule at least 3 hydrogen atoms directly bonded to a silicon atom in an amount sufficient to provide 0.7 to 5 such hydrogen atoms per vinyl group in the above defined component, and (iii) a catalytic amount of a platinum compound, said composition having a refractive index ranging from 1.40 to 1.41, and n being such that such composition has a viscosity at 25°

C. of from 50 to 1,000,000 centisokes.

11. The composition of claim 10, wherein in said second curable organopolysiloxane composition R is a methyl group.

12. The glass fiber of claim 10, wherein said Young'"'"'s modulus is 0.5 kg/mm² or less.

13. The glass fiber of claim 10, wherein said first and second curable organopolysiloxane compositions consist essentially of the recited components.