Polyurethane sponges manufactured with additive dispersed therein

• US 4,271,272 A
• Filed: 10/30/1978
• Issued: 06/02/1981
• Est. Priority Date: 11/13/1972
• Status: Expired due to Term

• Current Assignee: John F. Brooks, John W. Cantwell, Melvyn B. Strickman, Rose Strickman
• Original Assignee: Melvyn B. Strickman, Robert L. Strickman
• Inventors: Strickman, Melvyn B., Strickman, Robert L.
• Primary Examiner(s): Cockeram, H. S.
• Application Number:
  US05/955,880
• Time in Patent Office: 946 Days
• Field of Search: 424/28, 424/78, 521/905, 521/110, 521/130, 521/132
• US Class Current: 521/110
• CPC Class Codes: A47K 7/03 containing soap or other cleaning ingredients, e.g. impregnated
• CPC Class Codes: A47L 13/17 containing cleaning agents A47L13/19 takes precedence ; chemical compositions C11D17/049
• CPC Class Codes: A61K 2800/28 Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
• CPC Class Codes: A61K 8/0208 Tissues; Wipes; Patches
• CPC Class Codes: A61K 8/87 Polyurethanes
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 9/00 Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof mechanical aspects of shaping of plastics or substances in a plastic state for the production of porous or cellular articles B29C
• CPC Class Codes: C11D 17/049 Cleaning or scouring pads; Wipes
• CPC Class Codes: Y10S 521/905 Hydrophilic or hydrophobic cellular product

Abstract

This disclosure teaches synthetic polyurethane sponges manufactured with at least 4% of one or more additives dispersed therein. The additives may be soap, lotions, detergents, pesticides, lanolin, scouring particles, silicone oils, bath oils, or the like or combinations thereof. The sponges'"'"' skeletons are developed by reaction of a polyether or a polyester with a suitable isocyanate in the presence of a catalyst with the additives entrapped in voids of the sponges. An additive bearing material, i.e. a carrier material containing the additive is prepared. The carrier material is then mixed into a foam forming reaction mass. By this expedient the additive does not impair desired foam formation. The sponges are provided with high liquid absorbency and fine "hand" by virtue of manufacturing methods and specific catalysts employed.

Claims

1. A resilient polyurethane foam sponge product comprising an amount of a lotion of at least 4 percent by weight of the product sponge dispersed uniformly within the cellular structure of the synthetic polyurethane sponge, said sponge product produced by reaction of a component selected from the group consisting of polyesters and polyethers with an organic polyisocyanate in the presence of a catalyst to obtain a foam forming mass, the lotion being dispersed in the reaction mass prior to the onset of foam formation.

2. The product of claim 1 wherein the lotion is a silicone-containing material.

3. The product of claim 2 wherein the silicone-containing material comprises between 10 and 20 percent by weight of the product sponge.

7. The product of claim 1, 4 or 5 wherein the additives of said claims are first distributed within a dry, vehicular material before incorporation into the reaction mass, the vehicular material being soap.

4. A resilient polurethane foam sponge product comprising an amount of a pesticide of at least 4 percent by weight of the product sponge dispersed uniformly within the cellular structure of the synthetic polyurethane sponge, said sponge product produced by reaction of a component selected from the group consisting of polyesters and polyethers with an organic polyisocyanate in the presence of a catalyst to obtain a foam forming mass, the pesticide being dispersed in the reaction mass prior to the onset of foam formation.

5. A resilient polyurethane foam sponge product comprising an amount of a bath oil of at least 4 percent by weight of the product sponge dispersed uniformly within the cellular structure of the synthetic polyurethane sponge, said sponge product produced by reaction of a component selected from the group consisting of polyesters and polyethers with an organic polyisocyanate in the presence of a catalyst to obtain a foam forming mass, the bath oil being dispersed in the reaction mass prior to the onset of foam formation.

6. The product of claim 5 wherein the bath oil is selected from the group consisting of acetylated lanolin, acetylated lanolin alcohol, isopropyl myristate, mineral oil and compatible combinations of same.