Cathode materials

• US 4,271,278 A
• Filed: 09/10/1979
• Issued: 06/02/1981
• Est. Priority Date: 10/16/1978
• Status: Expired due to Term

• Current Assignee: Medtronic Incorporated (Medtronic Plc)
• Original Assignee: Medtronic Incorporated (Medtronic Plc)
• Inventors: Untereker, Darrel F., Phillips, Gary M.
• Primary Examiner(s): Hamrock, William F.
• Application Number:
  US06/074,153
• Time in Patent Office: 631 Days
• Field of Search: 525/356, 525/336, 429/213
• US Class Current: 525/356
• CPC Class Codes: H01M 4/60 of organic compounds
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Preparation and use of polyvinylpyridine and iodine (PVP.n I₂) as cathode materials for electrochemical cells.

Claims

1. A cell including an anode and a cathode wherein the cathode is prepared by a method comprising the steps of mixing polymeric material selected from the group consisting of P2VP, P4VP, and mixtures thereof with a quantity of iodine and heating the resultant mixture in a sealed container in the presence of a protective atmosphere at a temperature of at least about 150°

C.

2. The cell of claim 1 wherein the protective atmosphere is a vacuum.

3. The cell of claim 1 wherein the atmosphere is inert.

4. The cell of claim 1 wherein the heating temperature is in excess of about 150°

C.

5. The cell of claim 1 wherein the heating temperature is between about 150°

C. and 350°

C.

6. The cell of claim 1 wherein the heating temperature is in excess of about 350°

C.

7. The cell according to any of the preceding claims 1, 2, 3, 4, 5 or 6 wherein additional iodine is added to the material following the heating step.

8. The cell according to claim 1 wherein the anode includes lithium.

13. The cell of either of the preceding claims 1 or 9 wherein the inert atmosphere is selected from the group consisting of argon, helium and mixtures thereof.

14. The cell of either of the preceding claims 1 or 9 wherein the time of heating is less than about eight hours.

15. The cell of either of the preceding claims 13 or 14 wherein additional iodine is added to the material following the heating step.

9. A cell including an anode and a cathode wherein the cathode is prepared by a method of comprising the steps of mixing polymeric material selected from the group consisting of P2VP, P4VP and mixtures thereof with a quantity of iodine, and heating the mixture in a container, the heating step being further characterized by a treatment sequence selected from the group consisting of:

A. sealing the mixture in the container under vacuum and heating the mixture for a time at a temperature of at least about 150°

C.,

B. sealing the mixture in the container with an inert atmosphere and heating the mixture for a time at a temperature of at least about 150°

C., and

C. sealing the mixture in the container with an atmosphere selected from the group consisting of ambient, inert, and vacuum, heating the mixture for a time at a temperature of at least about 150°

C., and subjecting the mixture to a vacuum for a time following the heating step to remove volatiles.

10. The cell of claim 9 wherein additional iodine is added to the material following the heating step.

11. The cell of claim 9 wherein the heating temperatures are in excess of about 225°

C.

12. The cell of claim 9 wherein the heating temperatures are between about 150°

C. and 350°

C.