Alkali resistant glass article and method of preparation

• US 4,272,294 A
• Filed: 09/20/1979
• Issued: 06/09/1981
• Est. Priority Date: 09/20/1979
• Status: Expired due to Term

• Current Assignee: Johns Manville Corporation (Berkshire Hathaway Incorporated)
• Original Assignee: Johns Manville Corporation (Berkshire Hathaway Incorporated)
• Inventors: Jaunarajs, Karlis L.
• Primary Examiner(s): Kendell, Lorraine T.
• Application Number:
  US06/077,451
• Time in Patent Office: 628 Days
• Field of Search: 428/392, 428/375, 428/379, 428/389, 428/378, 65/3 C, 106/99, 427/390 A, 427/390 R, 260/45.75 W
• US Class Current: 524/5
• CPC Class Codes: C03C 25/103 Organic coatings
• CPC Class Codes: Y10T 428/2958 Metal or metal compound in coating
• CPC Class Codes: Y10T 428/2964 Artificial fiber or filament

Abstract

A glass fiber article having enhanced alkali resistance is described. The glass fiber has thereon a coating comprising zinc stearate and a film forming polymer with the coating being present in an amount of 1 to 60% by weight of solids based on weight of the glass fiber. The polymer is preferably initially in the form of a latex and is selected from the group consisting of acrylic terpolymers, vinyl acetate/ethylene copolymers, vinyl acetate/vinyl chloride/ethylene terpolymers, urethane polymers and epoxy polymers. The glass fiber is used at a rate of approximately 5% to 20% as reinforcing fiber in Portland cement and other alkaline cementitious composites. Such composites are also described, as is a method of imparting alkali resistance to glass fiber by applying such coating to the fiber.

Claims

1. A glass fiber article having enhanced alkali resistance which comprises glass fiber having thereon a coating comprising zinc stearate and a film forming polymer, said coating being present as 1 to 60% by weight of solids based on the weight of glass fiber.

2. An article as in claim 1 wherein said coating is present as 3 to 25% by weight of solids based on the weight of glass fiber.

3. An article as in claim 1 wherein said film forming polymer is selected from the group consisting of acrylic terpolymers, vinyl acetate/ethylene copolymers, vinyl acetate/vinyl chloride/ethylene terpolymers, urethane polymers and epoxy polymers.

4. An article as in claim 2 wherein said film forming polymer is selected from the group consisting of acrylic terpolymers, vinyl acetate/ethylene copolymers, vinyl acetate/vinyl chloride/ethylene terpolymers, urethane polymers and epoxy polymers.

5. An article as in claims 1, 2, 3 or 4 wherein said zinc stearate comprises 10% to 80% by weight of the coating solids and the remainder is the polymer.

6. An article as in claim 5 wherein said zinc stearate comprises 15% to 60% by weight of the coating solids and the remainder is the polymer solids.

7. An article as in claims 1, 2, 3 or 4 wherein said polymer is an acrylic terpolymer.

8. An article as in claims 1, 2, 3 or 4 wherein said polymer is initially in the form of an aqueous emulsion which is dried on the glass fiber to deposit the polymer solids.

9. An article as in claims 1, 2, 3 or 4 wherein said glass fiber is formed from a composition having relatively low alkali resistance.

10. An article as in claim 9 wherein said glass fiber is formed from an "E glass" composition.

11. An article as in claims 1, 2, 3 or 4 wherein said glass fiber is formed from a composition having relatively high alkali resistance.

12. An article as in claim 1, 2, 3 or 4 wherein said coating consists essentially of said zinc stearate and said film forming polymer.

13. A reinforced article comprising an alkaline cementitious matrix having incorporated therein a reinforcing glass fiber article as in claims 1, 2, 3 or 4.

14. A reinforced article as in claim 13 wherein said reinforcing glass article represents a glass fiber concentration in the reinforced article in the range of from 5% to 20% by weight of said reinforced article.

15. A reinforced article as in claim 14 wherein said reinforcing glass article is in the form of a non-woven mat.