Thermal energy storage material comprising hydrated compound and water-swollen cross-linked polymer

• US 4,273,667 A
• Filed: 02/27/1980
• Issued: 06/16/1981
• Est. Priority Date: 11/10/1978
• Status: Expired due to Term

• Current Assignee: IC Gas International Limited
• Original Assignee: Calor Group Limited (SHV Holdings NV)
• Inventors: Page, John K. R., Kent, Peter J. C.
• Primary Examiner(s): Pitlick, Harris A.
• Application Number:
  US05/125,263
• Time in Patent Office: 475 Days
• Field of Search: 252/70, 126/400, 165/104 S, 165/104 M
• US Class Current: 252/70
• CPC Class Codes: C09K 5/063 Materials absorbing or liberating heat during crystallisation; Heat storage materials

Abstract

The thermal energy storage material comprises at least one hydrated compound (such as an inorganic salt) having a reversible transition to the anhydrous or a less hydrated form and a hydrogel, comprising a water-swollen cross-linked polymer formed by cross-linking a synthetic hydrophilic polymer by a covalent cross-linking mechanism, throughout which the compound is dispersed. The hydrogel is made by reacting a water-soluble or water-dispersible synthetic hydrophilic polymer, which is preferably linear and thermoplastic, with a cross-linking agent therefor in an aqueous medium containing the hydrated compound. The hydrophilic polymer, the aqueous medium and the hydrated compound are used in such amounts that the storage material contains a major proportion, by weight, of the hydrated compound and a minor proportion, by weight, of the cross-linked polymer.

Claims

1. In a thermal energy storage material which comprises at least one hydrated compound which has a reversible transition to the anhydrous or a less hydrated form and a minor amount of hydrogel throughout which said compound is dispersed, the improvement comprising that the hydrogel comprises a water-swollen cross-linked polymer formed by cross-linking a synthetic hydrophilic polymer by a covalent cross-linking mechanism.

2. A thermal energy storage material according to claim 1, wherein said synthetic hydrophilic polymer has functional groups selected from the group consisting of hydroxy, carboxy and amide groups, said functional groups being reacted with a cross-linking agent to form said cross-linked polymer.

3. A thermal energy storage material according to claim 1, wherein said synthetic hydrophilic polymer has groups which have been reacted with a cross-linking agent selected from the group consisting of an aldehyde, a polyfunctional isocyanate and a polyfunctional carboxylic acid.

4. A thermal energy storage material according to claim 3, wherein said synthetic hydrophilic polymer is selected from the group consisting of polyvinyl alcohol, a hydroxyalkyl acrylate polymer, a methacrylamide polymer, an acrylamide polymer and a hydroxyalkyl methacrylate polymer.

5. A thermal energy storage material as set forth in claim 3 in which the groups which have been reacted are hydroxy groups.

6. In a method of preparing a thermal energy storage material which comprises a hydrogel having dispersed therein a hydrated compound which has a transition temperature to the anhydrous or a less hydrated form in the range 0°

to 100°

C., the improvement comprising that the hydrogel is formed by reacting a water-soluble synthetic hydrophilic thermoplastic addition polymer having a substantially linear carbon-carbon backbone and active hydrogen atoms in pendant groups thereof with a cross-linking agent therefor in an aqueous medium containing said hydrated compound, such that the resulting hydrogel comprises a water-swollen, covalently cross-linked polymer.

7. A method according to claim 6, wherein said active hydrogen atoms are present in amide groups and said cross-linking agent is formaldehyde.

8. A method according to claim 6, wherein said polymer has pendant acid groups and wherein the reaction is carried out in the presence of a water-soluble salt of a polyvalent metal, such that the cross-linked polymer is cross-linked by cations of said polyvalent metal as well as by said cross-linking agent.

9. In a method of extracting heat by passing a fluid in heat-exchange relationship with a thermal energy storage material comprising at least one hydrated inorganic salt selected from the group consisting of sodium sulphate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium thiosulphate pentahydrate, sodium carbonate decahydrate and calcium chloride hexahydrate and a minor amount of a hydrogel throughout which said salt is dispersed, the improvement comprising that the hydrogel comprises a water-swollen cross-linked polymer formed by cross-linking a water-soluble linear synthetic thermoplastic polymer by a covalent cross-linking mechanism.

10. A method according to claim 9, wherein said polymer contains acrylamide repeating units and acrylic acid repeating units.

11. A method according to claim 10, wherein said polymer has been cross-linked by means of formaldehyde.