Pressure-sensitive electrically conductive elastomeric composition

• US 4,273,682 A
• Filed: 10/10/1979
• Issued: 06/16/1981
• Est. Priority Date: 12/24/1976
• Status: Expired due to Term

• Current Assignee: Yokohama Rubber Company Limited
• Original Assignee: Yokohama Rubber Company Limited
• Inventors: Kanamori, Katsuhiko
• Primary Examiner(s): Padgett, Benjamin R.
• Assistant Examiner(s): Barr, J. L.
• Application Number:
  US06/083,367
• Time in Patent Office: 615 Days
• Field of Search: 252/511, 338/114
• US Class Current: 252/511
• CPC Class Codes: C08K 9/00 Use of pretreated ingredients
• CPC Class Codes: H01C 10/106 on resistive material dispersed in an elastic material H01C10/103 and H01C10/12 take precedence; for electric switches H01H1/029
• CPC Class Codes: H01H 1/029 comprising conducting material dispersed in an elastic support or binding material

Abstract

Disclosed is a pressure-sensitive, electrically conductive elastomeric composition comprising a substrate composed of an organic flexible material and electrically conductive particles consisting of angle-chipped, roundish pebble-like particles of artificial graphite incorporated and dispersed therein. An elastomeric material comprising this composition has such a characteristic property that the electric resistivity is conspicuously and gradiently reduced under application of a pressure from the level maintained when no pressure is applied. This characteristic property is very durable and therefore, the material can be used advantageously for switch elements and the like.

Claims

1. A pressure-sensitive, electrically conductive elastomeric composition consisting essentially of a substrate composed of an organic flexible material and electrically conductive particles incorporated and dispersed therein, wherein said electrically conductive particles are angle-chipped, roundish pebble-like particles of artificial graphite having:

(a) a Wadell roundness of at least 0.7;

(b) a size passable through a sieve having a mesh size of 180 μ

m but not passable through a sieve having a mesh size of 40 μ

m; and

(c) a particle size distribution such that the ratio of the size of the minimum particle to the size of the maximum particle is in the range of 1;

1 to 1;

1.7.

2. A pressure-sensitive composition as set forth in claim 1, wherein the organic flexible material is a silicone rubber.

3. A pressure-sensitive composition as set forth in claim 1, wherein the organic flexible material is a polyvinyl chloride containng a plasticizer incorporated therein.

4. A pressure-sensitive composition as set forth in claim 1, wherein the artificial graphite particles have a degree of size passable through a sieve having a mesh size of 160 μ

m but not passable through a sieve having a mesh size of 45 μ

m.

5. A pressure-sensitive composition as set forth in claim 1, wherein the amount of the artificial graphite particles is 25 to 55% by volume based on the composition.

6. A pressure-sensitive composition as set forth in claim 1, wherein the amount of the artificial graphite particles is 25 to 45% by volume based on the composition.