Transfer sheet for polyamide articles

• US 4,275,106 A
• Filed: 10/30/1978
• Issued: 06/23/1981
• Est. Priority Date: 11/01/1977
• Status: Expired due to Term

• Current Assignee: Toppan Printing Co., Ltd. (TOPPAN Holdings, Inc.)
• Original Assignee: Toppan Printing Co., Ltd. (TOPPAN Holdings, Inc.)
• Inventors: Watanabe, Tadao
• Primary Examiner(s): Hess, Bruce H.
• Application Number:
  US05/955,949
• Time in Patent Office: 967 Days
• Field of Search: 156/234, 156/240, 156/249, 156/277, 427/148, 428/200, 428/202, 428/204, 428/207, 428/211, 428/347, 428/349, 428/352-355, 428/913, 428/914, 428/209, 428/344
• US Class Current: 428/200
• CPC Class Codes: B41M 3/12 Transfer pictures or the like, e.g. decalcomanias processes for producing decorative surface effects B44C1/00; B41M5/0256 takes precedence
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 428/914 Transfer or decalcomania
• CPC Class Codes: Y10T 428/24843 with heat sealable or heat releasable adhesive layer
• CPC Class Codes: Y10T 428/2486 with outer strippable or release layer
• CPC Class Codes: Y10T 428/24901 including coloring matter
• CPC Class Codes: Y10T 428/24917 including metal layer
• CPC Class Codes: Y10T 428/2804 Next to metal
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/2852 Adhesive compositions
• CPC Class Codes: Y10T 428/287 including epoxy group or epoxy polymer

Abstract

A transfer sheet which is used for transferring designs on to the surface of articles made of polyamide resin. The transferred design on the polyamide articles are excellent in appearance, durability and adhesiveness to the polyamide surfaces. The transfer sheet is basically composed of a backing material, a design layer and an adhesive layer and the invention is characterized in that said adhesive layer contains a varnish which is composed of: (A) nitrocellulose and (B) one member or a mixture of more members selected from the group consisting of phthalic ester plasticizers, fatty acid ester plasticizers, phosphoric ester plasticizers, epoxy plasticizers, alkyd resins and maleic acid resins.

Claims

1. A heat release decalcomania for polyamide articles comprising a backing material layer, a design layer comprising a film forming component and a coloring pigment, and an adhesive layer on said design layer, said adhesive layer consists essentially of (a) 30 to 90 parts by weight of nitrocellulose having a degree of nitration of from about 10 to about 14%, a degree of polymerization of from about 40 to about 450 and a specific gravity of from about 1.5 to about 1.6, and (b) 70 to 10 parts by weight of a member selected from the group consisting of phthalic ester plasticizers, fatty acid ester plasticizers, phosphoric ester plasticizers, epoxy plasticizers, alkyd resins, maleic acid resins and mixtures thereof.

2. A heat release decalcomania according to claim 1, further including in said adhesive layer from about 5 to about 60 parts by weight of thermoplastic urethane resin or vinyl chloride copolymer, per 100 parts by weight of said nitrocellulose and said member.

3. A heat release decalcomania for polyamide articles according to claim 1 wherein said backing material layer is comprised of a member selected from the group consisting of regenerated cellulose films, polyester films and paper coated with a synthetic resin.

4. A heat release decalcomania for polyamide articles according to claim 1 wherein a resinous release layer is formed between said backing layer and said design layer.

5. A heat release decalcomania for polyamide articles according to claim 4, wherein said release layer is comprised of a member selected from the group consisting of chlorinated rubber, thermoplastic acrylic resin, chlorinated polyolefin, vinyl resin, cellulose resin, cyclized rubber and mixtures thereof.

6. A heat release decalcomania for polyamide articles according to claim 4, wherein a resinous undercoating layer is formed between said backing layer and said release layer.

7. A heat release decalcomania for polyamide articles according to claim 6, wherein said undercoating layer is selected from the group consisting of polyethylene glycol having molecular weight of 200 to 10,000 and microcrystalline wax.

8. A heat release decalcomania for polyamide articles according to claim 4, wherein a resinous intermediate layer is formed between said release layer and said design layer.

9. A heat release decalcomania for polyamide articles according to claim 1, wherein a resinous intermediate layer is formed between said design layer and said adhesive layer.

10. A heat release decalcomania for polyamide articles according to claim 8 or 9, wherein said intermediate layer comprises a member selected from the group consisting of urethane resin, alkyd resin and acrylonitrile butadiene-styrene copolymer.

11. A heat release decalcomania for polyamide articles according to claim 1, wherein a resinous vacuum deposition undercoating layer and a vacuum deposition metallic layer are formed between said design layer and said adhesive layer.

12. A heat release decalcomania for polyamide articles according to claim 11, wherein said vacuum deposition undercoating layer is a member selected from the group consisting of nitrocellulose, acrylic resin, polyesters and polyvinyl chloride.

13. A heat release decalcomania for polyamide articles according to claim 11, wherein said vacuum deposition metallic layer is comprised of aluminium.

14. A heat release decalcomania for polyamide articles according to claim 11, wherein a resinous anchor coating layer is formed between said vacuum deposition metallic layer and said adhesive layer.

15. A heat release decalcomania for polyamide articles according to claim 14, wherein said anchor coating layer is comprised of a member selected from the group consisting of polyesters, polystyrene, vinyl resin, acrylic resin and mixtures thereof.

16. A heat release decalcomania for polyamide articles comprising a backing material layer, a design layer comprising a film forming component and a coloring pigment, an adhesive layer on said design layer, and a resinous vacuum deposition undercoating and a vacuum deposition metallic layer between said design layer and said adhesive layer, wherein said adhesive layer comprises (a) nitrocellulose having a degree of nitration of from about 10 to about 14%, a degree of polymerization of from about 40 to aboaut 450 and a specific gravity of from about 1.5 to about 1.6, and (b) a member selected from the group consisting of phthalic ester plasticizers, fatty acid ester plasticizers, phosphoric ester plasticizers, epoxy plasticizers, alkyd resins, maleic acid resins and mixtures thereof.