Hydrocarbon gas processing

• US 4,278,457 A
• Filed: 07/14/1977
• Issued: 07/14/1981
• Est. Priority Date: 07/14/1977
• Status: Expired due to Term

• Current Assignee: Elcor Corporation
• Original Assignee: The Ortloff Corporation
• Inventors: Wilkinson, John D., Campbell, Roy E.
• Primary Examiner(s): Yudkoff, Norman
• Application Number:
  US05/815,542
• Time in Patent Office: 1,461 Days
• Field of Search: 62/28, 62/27, 62/23, 62/24, 62/38, 62/39
• US Class Current: 62/621
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2210/06 Splitting of the feed stream, e.g. for treating or cooling in different ways
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 2240/40 Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

The processing of gas streams containing hydrocarbons and other gases of similar volatility to recover components such as ethane, propane and heavier hydrocarbons from a residue gas containing methane is disclosed. In prior art processes, it has been customary to cool incoming raw feed gas and to separate the desired products by distillation. A part of the needed cooling is obtained by expanding the raw feed gas from a high feed pressure to a lower pressure at which distillation occurs. In the present invention, the raw feed gas is divided into two gaseous streams before expansion. The first stream is expanded in the usual fashion and supplied to the demethanizer as a mid-column feed. The remaining part is cooled to substantial condensation. The condensed stream is expanded and supplied to the demethanizer column above the feed point of the first stream. The split vapor feed provides unexpected advantages in reducing the risk of carbon dioxide icing in the demethanizer column, thus either eliminating or reducing the need for prior CO₂ removal. Alternately, without increasing the risk of carbon dioxide icing, ethane recovery can be increased.

Claims

1. In a process for the separation of a feed gas containing methane and ethane into a volatile residue gas containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said ethane, said feed gas containing hydrocarbons and at least 0.02 mole percent carbon dioxide, wherein methane and ethane together comprise a major portion of said feed gas, in said process

(a) said feed gas being cooled under pressure to provide a cooled feed stream;

(b) said cooled feed stream being expanded to a lower pressure whereby it is further cooled; and

(c) said further cooled feed stream is fractionated at said lower pressure in a fractionation column, the overhead temperature of said fractionation column being maintained at a temperature whereby the major portion of said ethane is recovered in said relatively less volatile fraction;

the improvement wherein prior to cooling said feed gas is divided into a first gaseous stream and a second gaseous stream prior to said step (a) and

(1) said first stream is cooled to condense substantially all of it, and is thereafter expanded to said lower pressure;

(2) said second stream is cooled under pressure to provide a cooled feed stream and is thereafter expanded to said lower pressure; and

(3) said expanded first and second streams are thereafter supplied to said fractionation column at first and second feed points, respectively, said first feed point being the top liquid feed to said column, and said second feed point being at a mid-column feed position,

the proportion of said feed gas comprising said second stream, and the temperature of said second gas stream prior to expansion being controlled sufficiently that the temperature and amount of the expanded vapor will be effective to reduce the risk of carbon dioxide icing in said fractionation column.

2. The improvement according to claim 1, wherein said fractionation column operates with a top column temperature below about -125°

F.

3. In a process for the separation of a feed gas containing methane and ethane into a volatile residue gas containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said ethane, said feed gas containing hydrocarbons and at least 0.02 mole percent carbon dioxide, wherein methane and ethane together comprise a major portion of said feed gas, in said process

(a) said feed gas being cooled under pressure to provide a cooled feed stream;

(b) said cooled feed stream being expanded to a lower pressure whereby it is further cooled; and

(c) said further cooled feed stream is fractionated at said lower pressure in a fractionation column, the overhead temperature of said fractionation column being maintained at a temperature whereby the major portion of said ethane is recovered in said relatively less volatile fraction;

the improvement wherein following cooling, said cooled feed stream under pressure is divided into a first and second gaseous streams; and

(1) said first stream is cooled to condense substantially all of it, and is thereafter expanded to said lower pressure;

(2) said second stream is expanded to said lower pressure; and

(3) said expanded first and second streams are thereafter supplied to said fractionation column at first and second feed points, respectively, said first feed point being the top liquid feed to said column, and said second feed point being at a mid-column feed position,

the proportion of said feed gas comprising said second stream, and the temperature of said second stream being sufficient to reduce the risk of carbon dioxide icing in said column, and the temperature of said first stream being effective to maintain said overhead temperature of the fractionation column at a temperature whereby the major portion of said ethane is recovered in said relatively less volatile fraction.

4. The improvement according to claim 3, wherein said fractionation column operates with a top column temperature below about -125°

F.

5. In a process for the separation of a feed gas containing methane and ethane into a volatile residue gas containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said ethane, said feed gas containing hydrocarbons and at least 0.02 mole percent carbon dioxide, wherein methane and ethane together comprise a major portion of said feed gas, in said process

(a) said feed gas being cooled under pressure to provide a cooled feed stream;

(b) said cooled feed stream being expanded to a lower pressure whereby it is further cooled; and

(c) said further cooled feed stream is fractionated at said lower pressure in a fractionation column, the overhead temperature of said fractionation column being maintained at a temperature whereby the major portion of said ethane is recovered in said relatively less volatile fraction;

the improvement wherein said feed gas is cooled sufficiently to partially condense it; and

(1) said partially condensed feed is separated thereby to provide a feed gas vapor and a condensed feed;

(2) said feed gas vapor is thereafter divided into first and second gaseous streams;

(3) said first gaseous stream is cooled to condense substantially all of it, is thereafter expanded to said lower pressure and is supplied to said fractionation column at a first feed point, said first feed point being the top liquid feed to the column;

(4) said second gaseous stream is expanded to said lower pressure in a work expansion machine and is supplied to said fractionation column at said second feed point, said second feed point being a mid-column feed position;

(5) said condensed feed is expanded to said lower pressure and supplied to said fractionation column at a third feed point, said third feed point being at a mid-column feed position,

the proportion of said feed gas comprising said second stream, and the temperature of said second stream being sufficient to reduce the risk of carbon dioxide icing in said column, and the temperature of said first stream being effective to maintain said overhead temperature of the fractionation column at a temperature whereby the major portion of said ethane is recovered in said relatively less volatile fraction.

6. The improvement according to claim 5, wherein said feed case contains less than about 4 gallons per thousand cubic feed of C₂ + components.

7. The improvement according to claim 5, wherein said fractionation column operates with a top column temperature below about -125°

F.