Fluid sample cell

• US 4,278,887 A
• Filed: 02/04/1980
• Issued: 07/14/1981
• Est. Priority Date: 02/04/1980
• Status: Expired due to Term

• Current Assignee: ALFA Laval AB
• Original Assignee: Technicon Instruments Corporation (Bayer AG)
• Inventors: Stark, Edward, Lipshutz, Victor G.
• Primary Examiner(s): Anderson, Bruce C.
• Application Number:
  US06/118,563
• Time in Patent Office: 526 Days
• Field of Search: 250/432, 250/435, 250/437, 250/438, 250/343, 250/341, 250/344, 250/349, 356/236, 356/246
• US Class Current: 250/432.00R
• CPC Class Codes: G01N 21/0303 Optical path conditioning in cuvettes, e.g. windows; adapted optical elements or systems; path modifying or adjustment G01N21/031 - G01N21/15 take precedence
• CPC Class Codes: G01N 2201/065 Integrating spheres

Abstract

A fluid sample cell comprising a sample compartment of precisely predetermined depth bounded by opposed surfaces of a transparent window and a diffuse mirror is disclosed, and comprises inlet and outlet ports for the flow of a series of successive samples into and through said sample compartment and the spectroscopic analysis thereof by irradiation and detection of transmitted and reflected radiation.

Claims

1. A fluid sample cell for the spectroscopic analysis of a fluid sample, comprising:

a sample compartment formed in said cell for the containment of a fluid sample, said compartment being defined on opposite sides by a radiation energy-transmitting window and a diffuse reflector spaced from said window, and means for supporting opposing surfaces of said window and said diffuse reflector in spaced fashion, said diffuse reflector being adapted to redirect light incident thereon through a fluid sample contained therebetween and said window, whereby all of said redirected light passing through said window has the character of being diffusely reflected.

2. The fluid sample of claim 1, further comprising inlet and outlet ports for passing successive fluid samples into and out of said compartment.

3. The fluid sample cell of claim 1, wherein said opposing surfaces of said window and said diffuse reflector are planar and are supported by said supporting means in spaced parallel fashion, so as to define a substantially constant sample path length through said sample in a direction normal to said opposing surfaces.

4. The fluid sample cell of claim 2, further comprising:

means defining a viewing area through said window, said inlet and outlet ports being disposed outside said viewing area and extending into said sample compartment, and an access groove extending between said inlet and outlet ports and disposed outside said viewing area.

5. A spectroscopic analysis apparatus, comprising:

a fluid sample cell including a sample compartment for the containment of a fluid sample to be analyzed, said compartment being defined by a radiation-transmitting window and a diffuse reflector spaced from said window, opposing surface portions of said window and said diffuse reflector being supported in spaced fashion, inlet and outlet ports extending into said compartment for passing successive fluids samples, in turn, through said compartment, a radiation energy source for directing energy through said window and into said compartment, and means for collecting radiation scattered, whether in a forward or back direction, and radiation transmitted by said sample contained within said compartment, at least a portion of said forward scattered and transmitted radiation being reflected back from said diffuse reflector and through said sample, so as to minimize the effects of variations in light scattering on the accuracy of the spectroscopic measurement.

6. The spectroscopic analysis apparatus of claim 5, wherein opposing surface portions of said window and said diffuse reflector are planar and are supported in spaced parallel fashion, so as to define a constant sample path length in a direction normal to said opposing surfaces.

7. The spectroscopic analysis apparatus of claim 5, wherein said opposing surface portions of said window and said diffuse reflector are substantially planar.

8. The spectroscopic analysis apparatus of claim 5, wherein said collecting means comprises a radiation-integrating arrangement, and detector means responsive to radiation which has been integrated by said arrangement.

9. The spectroscopic analysis apparatus of claim 8, further comprising:

signal processing means responsive to said detector means, and display means responsive to said processing means.

10. The spectroscopic analysis apparatus of claim 5, further comprising:

means disposed over said window for defining a viewing area through said chamber, opposing surfaces of said window and diffuse reflector outside of said viewing area being spaced at least in excess of said sample path length.

11. A method for the spectroscopic analysis of a property of a fluid sample, comprising the steps of:

locating a fluid sample between a radiant energy-transmitting window and a diffuse reflector, said window and said diffuse reflector being supported in spaced fashion, for irradiating said fluid sample with selected wavelengths of radiant energy, collecting at least a representative portion of radiation scattered, whether in a forward or backward direction, and radiation transmitted by said fluid sample, at least a portion of said forward scattered and transmitted radiation being reflected back from said diffuse reflector and through said fluid sample for collection, integrating said collected radiation, and generating a signal in accordance with said collected radiation, as an indication of said property, so as to minimize the effects of variations in light scattering on the accuracy of the spectroscopic measurement.