Electrical devices containing a grease compatible, mineral oil extended polyurethane

• US 4,281,210 A
• Filed: 04/06/1979
• Issued: 07/28/1981
• Est. Priority Date: 02/15/1978
• Status: Expired due to Term

• Current Assignee: CasChem, Inc.
• Original Assignee: NL Industries Incorporated (Valhi Holding Company)
• Inventors: Brauer, Melvin, Kroplinski, Thaddeus F.
• Primary Examiner(s): KENDELL, LORRAINE
• Application Number:
  US06/027,820
• Time in Patent Office: 844 Days
• Field of Search: 428/375, 428/379, 174/23 C, 174/23 R, 174/110 R, 174/110 SR, 260/33.6 UB, 260/31.8 R, 260/32.8 N, 260/18 TN, 260/31.2 N, 260/31.6, 260/31.8 B, 260/31.8 C, 260/31.8 N, 528/60
• US Class Current: 174/23.00C
• CPC Class Codes: C08G 18/36 Hydroxylated esters of higher fatty acids
• CPC Class Codes: C08G 18/69 Polymers of conjugated dienes hydrogenated polymers of conjugated dienes C08G18/6208
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: C08L 91/06 Waxes
• CPC Class Codes: C10M 2203/10 Petroleum or coal fractions, e.g. tars, solvents, bitumen
• CPC Class Codes: C10M 2203/102 Aliphatic fractions
• CPC Class Codes: C10M 2203/104 Aromatic fractions
• CPC Class Codes: C10M 2203/106 Naphthenic fractions
• CPC Class Codes: C10M 2203/108 Residual fractions, e.g. bright stocks
• CPC Class Codes: H01B 3/302 Polyurethanes or polythiourethanes; Polyurea or polythiourea
• CPC Class Codes: Y10T 428/2933 Coated or with bond, impregnation or core
• CPC Class Codes: Y10T 428/294 including metal or compound thereof [excluding glass, ceramic and asbestos]

Abstract

A cured, cross-linked, mineral oil extended polyurethane which is non-spewing. The mineral oil extended polyurethane is further characterized by being grease compatible in that the tendency of the mineral oil to migrate is substantially reduced or eliminated. The mineral oil extended polyurethane is comprised of a defined polyurethane, mineral oil, and coupling agent. In other aspects, the present invention relates to a process for reclaiming or sealing an insulated electrical device and to an insulated electrical device which is formed by such process.

Claims

1. An insulated electrical device containing a plurality of insulated wire conductors, said device having interior spaces between the insulated wire conductors which contain a grease compatible, cured, cross-linked, mineral oil extended polyurethane which is non-spewing, comprising:

(a) from about 8 to about 45 parts, by weight, of polyurethane, said polyurethane being prepared by reacting

(i) a polyisocyanate compound or a polyisocyanate prepolymer prepared by the reaction of a polyisocyanate compound with a polyol selected from the group consisting of castor oil, polyether polyols, hydroxyl bearing homopolymers of dienes, hydroxyl bearing copolymers of dienes, and combinations thereof, wherein at least about 0.25 equivalents of the polyisocyanate compound per 1.0 equivalents of the polyisocyanate compound used is a liquid long chain aliphatic polyisocyanate, with

(ii) a polyol selected from the group consisting of castor oil, polyether polyols, hydroxyl bearing homopolymers of dienes, hydroxyl bearing copolymers of dienes, and combinations thereof,

(b) from about 20 to about 75 parts, by weight, of mineral oil, said mineral oil being characterized by having from about 1.0 to about 30% aromatic carbon atoms, based on the total number of carbon atoms present in the mineral oil, and

(c) from about 10 to about 47 parts, by weight, of coupling agent, said coupling agent being characterized by

(i) being miscible in all proportions with said mineral oil,

(ii) having a total solubility parameter from about 7.0 to about 9.5,

(iii) having a hydrogen bonding index number from about 6.0 to about 12.0, and

(iv) being substantially non-reactive with said polyisocyanate prepolymer and said polyol, and

wherein the grease compatible, cured, cross-linked, mineral oil extended polyurethane is further characterized by the presence of a polydiene moiety in the polyurethane structure.

2. The insulated electrical device of claim 1 wherein the hydroxyl bearing homopolymers of dienes of claim 1, (a)(i) and (a)(ii) are hydroxyl bearing homopolymers of butadiene and wherein the hydroxyl bearing copolymers of dienes of claim 1 (a)(i) and (a)(ii) are hydroxyl bearing copolymers of butadiene.

3. The insulated electrical device of claim 1 wherein said liquid long chain aliphatic polyisocyanate contains from about 12 to about 50 carbon atoms in the carbon chain.

4. The insulated electrical device of claim 1 wherein the polyisocyanate compound used in the preparation of the polyurethane comprises about 0.25 equivalents of a mixture of polyisocyanate isomers derived from a 36 carbon dimer aliphatic acid and about 0.75 equivalents of polymethylene polyphenylisocyanate per 1.0 equivalents of polyisocyanate compound used.

5. The insulated electrical device of claim 1 which comprises from about 25 to about 45 parts of polyurethane, from about 20 to about 40 parts of mineral oil and from about 25 to about 47 parts of coupling agent, all parts expressed on a weight basis, wherein said coupling agent is further characterized by having a boiling temperature above about 220°

F. and being selected from the group consisting of a ketone and an ester, and wherein said mineral oil is characterized by having from about 5.0 to about 25% aromatic carbon atoms, based on the total number of carbon atoms present in the mineral oil.

6. The insulated electrical device of claim 1 wherein the polyisocyanate compound used in the preparation of the polyurethane is a mixture of polyisocyanate isomers derived from a 36 carbon dimer aliphatic acid.

13. The electrical device of claim 2 wherein the coupling agent is characterized by

(i) being miscible in all proportions with said mineral oil,

(ii) having a total solubility parameter from about 8.2 to about 9.4,

(iii) having a polar and hydrogen bonding solubility parameter from about 3.2 to about 4.3,

(iv) having a non-polar solubility parameter from about 7.6 to about 8.4,

(v) having a hydrogen bonding index number from about 6.0 to about 12.0, and

(vi) being substantially non-reactive with said polyisocyanate prepolymer and said polyol.

7. An insulated electrical device containing a plurality of insulated wire conductors, said device having interior spaces between the insulated wire conductors which contain a grease compatible, cured, cross-linked, mineral oil extended polyurethane which is non-spewing, comprising:

(a) from about 8 to about 45 parts, by weight, of polyurethane, said polyurethane being prepared by reacting

(i) a polyisocyanate compound or a polyisocyanate prepolymer prepared by the reaction of a polyisocyanate compound with a polyol selected from the group consisting of castor oil, polyether polyols, hydroxyl bearing homopolymers of dienes, hydroxyl bearing copolymers of dienes, and combinations thereof, wherein at least about 0.25 equivalents of the polyisocyanate compound per 1.0 equivalents of the polyisocyanate compound used is a liquid long chain aliphatic polyisocyanate, with

(ii) a polyol selected from the group consisting of castor oil, polyether polyols, hydroxyl bearing homopolymers of dienes, hydroxyl bearing copolymers of dienes, and combinations thereof,

(b) from about 20 to about 75 parts, by weight, of mineral oil, and

(c) from about 10 to about 47 parts, by weight, of coupling agent, said coupling agent being characterized by

(i) being miscible in all proportions with said mineral oil,

(ii) having a total solubility parameter from about 8.2 to about 9.4,

(iii) having a polar and hydrogen bonding solubility parameter from about 3.2 to about 4.3,

(iv) having a non-polar solubility parameter from about 7.6 to about 8.4,

(v) having a hydrogen bonding index number from about 6.0 to about 12.0, and

(vi) being substantially non-reactive with said polyisocyanate prepolymer and said polyol, and

wherein the grease compatible, cured, cross-linked, mineral oil extended polyurethane is further characterized by the presence of a polydiene moiety in the polyurethane structure.

8. The insulated electrical device of claim 7 wherein said liquid long chain aliphatic polyisocyanate contains from about 12 to about 50 carbon atoms in the carbon chain.

9. The insulated electrical device of claim 7 which comprises from about 20 to about 45 parts of polyurethane, from about 20 to about 40 parts of mineral oil and from about 25 to about 47 parts of coupling agent, all parts expressed on a weight basis, wherein said coupling agent is further characterized by having a boiling temperature above about 220°

F. and being selected from the group consisting of a ketone and an ester, and wherein said mineral oil is characterized by having from about 5.0 to about 25% aromatic carbon atoms, based on the total number of carbon atoms present in the mineral oil.

10. The insulated electrical device of claim 7 wherein the hydroxyl bearing homopolymers of dienes of claim 7, (a) (i) and (a) (ii) are hydroxyl bearing homopolymers of butadiene and wherein the hydroxyl bearing copolymers of dienes of claim 7, (a) (i) and (a) (ii) are hydroxyl bearing copolymers of butadiene.

11. The insulated electrical device of claim 7 wherein the polyisocyanate compound used in the preparation of the polyurethane comprises about 0.25 equivalents of a mixture of polyisocyanate isomers derived from a 36 carbon dimer aliphatic acid and about 0.75 equivalents of polymethylene polyphenylisocyanate per 1.0 equivalents of polyisocyanate compound used.

12. The insulated electrical device of claim 7 wherein the polyisocyanate compound used in the preparation of the polyurethane is a mixture of polyisocyanate isomers derived from a 36 carbon dimer aliphatic acid.