Methods and apparatus for generating plasmas

• US 4,282,267 A
• Filed: 03/05/1980
• Issued: 08/04/1981
• Est. Priority Date: 09/20/1979
• Status: Expired due to Term

• Current Assignee: AT&T, Inc.
• Original Assignee: Western Electric Co., Inc. (Nokia Corporation)
• Inventors: Kuyel, Birol
• Primary Examiner(s): Newsome, John H.
• Application Number:
  US06/127,296
• Time in Patent Office: 517 Days
• Field of Search: 427/38, 427/39, 427/40, 427/45, 427/94, 427/95, 427/93, 204/164, 204/177, 204/193, 118/50.1, 118/620, 315/111.2
• US Class Current: 427/568
• CPC Class Codes: B01J 19/126 Microwaves
• CPC Class Codes: B01J 2219/0894 Processes carried out in the presence of a plasma
• CPC Class Codes: C23C 16/517 using a combination of discharges covered by two or more of groups C23C16/503 - C23C16/515
• CPC Class Codes: H05H 1/46 using applied electromagnetic fields, e.g. high frequency or microwave energy H05H1/26 takes precedence

Abstract

An RF-excited radial-flow, cylindrical plasma reactor (10) includes a toroidal waveguide (17) of rectangular cross-section connected to a microwave source (21). One of the reactive species (37) is flowed through the waveguide and pre-ionized, thus, permitting independent control over the activation of both reactive species.

Claims

1. A method of separately activating at least two potentially reactive species to form a reactive plasma when combined, each of said potentially reactive species having a different activation level, said method comprising the steps of:

(a) forming a non-reactive plasma so as to create therein an activated species of at least one of said potentially reactive species;

(b) separately activating the other of said potentially reactive species having the higher activation level; and

(c) flowing the activated species having the higher activation level into said non-reactive plasma to create a reactive plasma.

2. The method according to claim 1 wherein said forming a non-reactive plasma step comprises:

combining an inert carrier with said at least one potentially reactive species; and

then

ionizing said combination to form said non-reactive plasma.

3. The method according to claim 1 wherein said forming a non-reactive plasma step comprises:

subjecting said at least one potentially reactive species to an electric field.

4. The method according to claim 2 wherein said forming a non-reactive plasma step comprises:

subjecting said combination to an electric field.

5. The method according to claims 1 or 2 wherein said separately activating step comprises:

passing a beam of microwave radiation through said potentially reactive species to form a plasma.

6. The method according to claims 3 or 4 wherein said separately activating step comprises:

passing a beam of microwave radiation through said potentially reactive species to form a plasma.

7. The method according to claim 1 including the further step of:

selectively controlling the energy supplied (1) to form a non-reactive plasma, and (2) to separately activate the other of said reactive species having the higher activation level, thereby to control the relative concentrations of activated species in said reactive plasma.

8. The method according to claim 2 including the further step of:

selectively controlling the energy supplied (1) to ionize said combination, and (2) to separately activate the other of said reactive species having the higher activation level, thereby to control the relative concentrations of activated species in said reactive plasma.

9. The method according to claims 1, 3 or 7 wherein said at least one potentially reactive species comprises SiH₄, the other of said potentially reactive species having the higher activation level comprises NH₃, and said method comprises the further step of:

exposing a workpiece to said reactive plasma, whereby said plasma deposits a layer of Si₃ N₄ onto said workpiece.

10. The method according to claim 9 including the further step of:

heating said workpiece to a temperature in excess of approximately 200°

C.

11. The method according to claim 9 wherein said separately activating step comprises:

passing a beam of microwave radiation through the other of said potentially reactive species.

12. The method according to claims 2, 4 or 8 wherein said at least one potentially reactive species comprises SiH₄, said inert carrier comprises Ar, the other of said potentially reactive species having the higher activation level comprises NH₃, and said method comprises the further step of:

exposing a workpiece to said reactive plasma whereby said reactive plasma deposits a layer of Si₃ N₄ onto said workpiece.

13. The method according to claim 12 wherein said workpiece is heated to a temperature in excess of approximately 200°

C.

14. The method according to claim 12 wherein said separately activating step comprises:

passing a beam of microwave radiation through the other of said potentially reactive species.

15. The method according to claims 1, 3 or 7 wherein said at least one potentially reactive species comprises O₂, the other of said potentially reactive species having the higher activation level comprises CF₄, and said method comprises the further step of:

exposing a workpiece to said reactive plasma whereby said workpiece is etched by said plasma.

16. The method according to claim 15 wherein said separately activating step comprises:

passing a beam of microwave radiation through the other of said potentially reactive species.

17. Apparatus for separately activating at least two potentially reactive species to form a reactive plasma when combined, each of said potentially reactive species having a different activation level, said apparatus comprising:

means for forming a non-reactive plasma so as to create therein an activated species of at least one of said potentially reactive species;

means for separately activating the other of said potentially reactive species having the higher activation level; and

means for flowing the activated species having the higher activation level into said non-reactive plasma to create a reactive plasma.

18. The apparatus according to claim 17 wherein said means for forming a non-reactive plasma comprises:

a sealed reaction chamber;

first and second spaced-apart electrodes positioned in said chamber; and

means for establishing an electric field between said first and second electrodes thereby to form a non-reactive plasma.

19. Apparatus for separately activating at least two potentially reactive species to form a reactive plasma when combined, each of said potentially reactive species having a different activation level, said apparatus comprising:

means for forming a non-reactive plasma so as to create therein an activated species of at least one of said potentially reactive species;

means for separately activating the other of said potentially reactive species having the higher activation level, said separately activating means further comprising;

a waveguide positioned within said apparatus, said reactive species having the higher activation level flowing through said waveguide; and

a source of a beam of microwave energy connected to said waveguide.

20. The apparatus according to claim 19 wherein said reaction chamber is cylindrical in shape, said first and second electrodes are disc-shaped and are coaxially positioned within said chamber, and said waveguide comprises a toroid of rectangular cross-section coaxial to and aligned with said first disc-shaped electrode.

21. The apparatus according to claim 20 further comprising:

means, intermediate said source of microwave energy and said waveguide for passing microwave energy therethrough but for maintaining the vacuum within said chamber.

22. The apparatus according to claim 21 wherein said means for applying an electric field comprises:

a source of radio frequency energy connected across said first and second electrodes; and

impedance-matching means intermediate said radio frequency source and said electrodes.

23. The apparatus according to claim 22 wherein said waveguide includes a plurality of circumferentially disposed apertures to permit the flow of activated reactive species out of said waveguide.

24. The apparatus according to claim 23 further comprising:

at least one ring-shaped supply pipe positioned proximate the other one of said electrodes and connected to a source of said at least one potentially reactive species.

25. The apparatus according to claim 24 including means for exhausting spent gases from said chamber.