Microwave heating package, method and susceptor composition

• US 4,283,427 A
• Filed: 12/19/1978
• Issued: 08/11/1981
• Est. Priority Date: 12/19/1978
• Status: Expired due to Term

• Current Assignee: The Pillsbury Company
• Original Assignee: The Pillsbury Company LLC (General Mills Incorporated)
• Inventors: Sholl, Jeffrey J., Anderson, George R., Winters, William C., Easter, Ross A., Chang, Hsien-Hsin
• Primary Examiner(s): PITLICK, HARRIS
• Application Number:
  US05/970,898
• Time in Patent Office: 966 Days
• Field of Search: 252/70, 252/600, 252/1, 219/10.55 E, 219/10.55 M, 219/10.55 R, 426/107, 426/234, 426/241, 426/242, 426/243, 126/400, 206/524.1, 206/524.3, 206/525
• US Class Current: 426/107
• CPC Class Codes: B65D 2581/3447 Heat attenuators, blocking agents or heat insulators for temperature control
• CPC Class Codes: B65D 2581/3485 Other unusual non-metallic substances, e.g. ivory, wood
• CPC Class Codes: B65D 2581/3494 Microwave susceptor B65D2581/3487 takes precedence
• CPC Class Codes: B65D 81/3446 specially adapted to be heated by microwaves

Abstract

A microwave heating package, and a method of microwave heating. Both the package and the method employ a lossy chemical susceptor which upon continued exposure to microwave radiation becomes substantially microwave transparent, thus building into the system a unique maximum temperature shut off at the point at which the chemical susceptor becomes microwave transparent. The chemical susceptor is comprised of a combination of a solute, such as inorganic salts of Group IA and IIA, and a polar solvent for the solute, such as water. The chemical susceptor may be composed of a hydrated form of the inorganic salts. The package, method and chemical susceptor may be used for microwave heating of many products, including among others, food products.

Claims

1. A lossy susceptor device for microwave energy, which upon continued heating by exposure to microwave radiation has a chemical susceptor portion which becomes substantially microwave transparent, said susceptor device comprising:

a chemical susceptor comprising a combination of a solute and a polar solvent for said solute, the amount of solute present being as a minimum an amount which will depress the vapor pressure of said solvent, at least by 25% when compared to said solvent'"'"'s boiling point at standard pressure; and

a holder for said chemical susceptor said holder including vent means which permits escape of solvent from the holder when said chemical susceptor is exposed to microwave radiation.

2. The chemical susceptor of claim 1 wherein the solute is present in at least a minimum amount sufficient to provide a eutectic mixture of said solute in said solvent.

3. The chemical susceptor of claim 2 wherein the solute is present in at least a minimum amount sufficient to provide a saturated solution, at room temperature, of said solute in said solvent.

4. The chemical susceptor of claim 3 wherein the combination of solute and polar solvent is more lossy than either the solute alone or the solvent alone.

5. The chemical susceptor of claim 3 wherein said vapor pressure of said solvent is depressed at least 50%.

6. The chemical susceptor of claim 3 wherein said vapor pressure of said solvent is depressed of about 70% or greater.

7. The chemical susceptor of claim 3 wherein said vapor pressure of said solvent is depressed in the range of between about 70% and about 80%.

8. The chemical susceptor of claim 3 wherein said solute is an inorganic salt material.

9. The chemical susceptor of claim 8 wherein said inorganic salts are selected from the group consisting of Groups IA and IIA salts, of mixtures thereof.

10. The chemical susceptor of claim 9 wherein said salts are Group IA and IIA salts which when mixed with said polar solvent become paste-like.

11. The chemical susceptor of claim 10 wherein said salts are salts capable of forming water hydrates.

12. The chemical susceptor of claim 8 wherein said polar solvent for said solute is water.

13. The chemical susceptor of claim 10 wherein said salts are Groups IA and IIA inorganic salts which significantly increase their solubility in water at 100°

C. in comparison with their water solubility at 20°

C.

14. The chemical susceptor of claim 13 wherein said salts are capable of forming water hydrates.

15. The chemical susceptor of claim 14 wherein said polar solvent for said solute is water.

16. The chemical susceptor of claim 12 wherein said salts are Groups IA and IIA inorganic salts which significantly increase their solubility in water at 100°

C. in comparison with their water solubility at 20°

C.

17. The chemical susceptor of claim 3 wherein said chemical susceptor includes a heating profile modifier in an amount of from about 0.1% by weight to about 25% by weight of chemical susceptor.

18. The chemical susceptor of claim 17 wherein said heating profile modifier is present at a level of from about 0.2% by weight to about 10% by weight of chemical susceptor.

19. The chemical susceptor of claim 17 wherein said heating profile modifier is an additive which makes said polar solvent more difficult to remove from said system during heating.

20. The chemical susceptor of claim 19 wherein said heating profile modifier is hydrophilic.

21. The chemical susceptor of claim 20 wherein said heating profile modifier is selected from the group consisting of clays, carbohydrates, titanium dioxides, fats, and silicates.

22. The chemical susceptor of claim 12 wherein said salt comprises from about 30% to about 85% by weight of said susceptor.

23. The chemical susceptor of claim 22 wherein said salt comprises from about 45% to about 80% by weight of said chemical susceptor.

24. The chemical susceptor of claim 9 wherein said salt is calcium chloride.

25. The chemical susceptor of claim 9 wherein said salt is lithium chloride.

26. The susceptor device of claim 3 wherein said holder includes a pair of sheet members with at least a portion of the one said sheet member being substantially microwave transparent, said chemical susceptor is interposed between the sheet members, said sheet members being secured to one another substantially enclosing the chemical susceptor, vent means for allowing the venting of the solvent from the holder during heating of the chemical susceptor.

27. The susceptor device of claim 26 wherein both of said sheet members are substantially microwave transparent and said chemical susceptor is adhered to at least one of said sheet members.

28. The susceptor device of claim 1 wherein said device is positioned adjacent a food product whereby said chemical susceptor is in heat transfer relationship with said food product and will heat said food product upon exposure to micowave radiation.

29. The susceptor device of claim 1 positioned in a microwave radiation field sufficiently strong to cause said chemical susceptor to heat.

30. The susceptor device of claim 1 wherein said holder is of a low lossy material.

31. The susceptor device of claim 1 wherein said holder substantially encloses the chemical susceptor and has at least one substantially microwave transparent portion.

32. The susceptor device of claim 1 wherein the thickness of the chemical susceptor is up to about 0.1 centimeters.

33. A lossy susceptor device for microwave energy, which upon continued exposure to microwave radiation has a chemical susceptor portion which becomes substantially microwave transparent, said susceptor device comprising:

a low lossy holder for said chemical susceptor, and a chemical susceptor in heat transfer association with said holder comprising an inorganic salt selected from Group IA and Group IIA salts in combination with water as a polar solvent for said salts, and a heating profile modifier, the amount of said salt being sufficient to depress the vapor pressure of water at least by 25% when compared to the vapor pressure of water at standard pressure, said holder including vent means which permits escape of solvent from the holder when said chemical susceptor is exposed to microwave radiation.

34. The chemical susceptor of claim 33 which comprises about 45% by weight calcium chloride as the inorganic salt, about 45% by weight and about 10% by weight silica gel as a heating profile modifier.

35. A method of microwave heating products which simultaneously heats internal portions of said product and selectively raises to a higher temperature pre-selected areas of said products, said method comprising:

locating a lossy susceptor device in a microwave environment, said susceptor device including a chemical susceptor comprising a solute and a polar solvent for said solute, the amount of said solute being as a minimum an amount sufficient to provide a saturated solution of said solute in said polar solvent and an amount which will depress the vapor pressure of said solvent at least 25% when compared to the vapor pressure of said solvent at its boiling point at standard pressure, placing said product which is to be heated in heat transfer association with at least a portion of said susceptor device, and exposing said susceptor device to microwave radiation energy to heat said chemical susceptor, said chemical susceptor being heated to a higher temperature than said product until said polar solvent is driven off, and thereafter said chemical susceptor becoming substantially non-lossy.

36. A disposable package for use in microwave ovens, said package comprising:

a container of substantially non-lossy material for holding of a product to be treated with microwave radiation, and a chemical susceptor for microwave energy associated with said container for thermal contact with at least one surface of a product which is to be placed in said container, said chemical comprising an inorganic salt selected from the group consisting of Group IA and Group IIA salts, and a polar solvent for said salt, and a low lossy substantially microwave transparent holder surface for said susceptor.

37. The package of claim 36 wherein said package includes on selected surfaces a microwave shield to directionally control the microwave exposure.

38. The package of claim 37 wherein said package includes on some surfaces apertures sufficiently small to at least partially restrict microwave penetration.

39. A method of microwave heating products which simultaneously heats the internal portions of said product and selectively raises to a higher temperature pre-selected areas of said products, said method comprising:

locating a lossy chemical susceptor in a microwave environment, said chemical susceptor comprising a solute and a polar solvent for said solute, the amount of said solute being as a minimum an amount sufficient to provide a saturated solution of said solute in said polar solvent, and an amount which will depress the vapor pressure of said solvent at least 25% when compared to the vapor pressure of said solvent at its boiling point at standard pressure, placing said product which is to be treated in heat transfer association with at least a portion of said chemical susceptor and exposing said chemical susceptor to microwave radiation to heat said chemical susceptor, said chemical susceptor being heated to a higher temperature than said product, and a higher temperature than the fusion point of said solute portion of the chemical susceptor resulting in said solute portion changing to a liquid phase, and thereafter said solute portion continuing to heat in a steady state as long as said solute portion remains in said liquid phase and is exposed to sufficient microwave radiation energy to remain in said liquid phase.

40. A disposable microwave package comprising:

a container of substantially non-lossy material for holding of a food product to be treated with microwave radiation energy, a chemical susceptor for microwave energy associated with said container for thermal contact with at least one surface of a product which is to be placed in said container, said chemical comprising an inorganic salt selected from the group consisting of Group IA and Group IIA salts, and a polar solvent for said salt, a low lossy substantially microwave transparent holder surface for said susceptor, a food product within said package, said food product having a low moisture content and a low density in order to change its heat load characteristics.