Piezoelectric polymer antifouling coating

• US 4,283,461 A
• Filed: 05/31/1979
• Issued: 08/11/1981
• Est. Priority Date: 05/31/1979
• Status: Expired due to Term

• Current Assignee: the united states of america as represented by the secretary of the navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: Edelman, Seymour, Wooden, Bruce J.
• Primary Examiner(s): Mc Camish, Marion
• Assistant Examiner(s): BUFFALOW, EDITH
• Application Number:
  US06/044,130
• Time in Patent Office: 803 Days
• Field of Search: 427/100, 252/62.9, 134/1, 134/4, 428/422, 260/255, 106/18.35, 114/222, 114/67 R, 114/67 A
• US Class Current: 428/422
• CPC Class Codes: B08B 17/02 Preventing deposition of fouling or of dust
• CPC Class Codes: B63B 59/04 Preventing hull fouling anti-fouling paints C09D5/16
• CPC Class Codes: C09D 5/1662 Synthetic film-forming substance
• CPC Class Codes: C09D 5/1693 as part of a multilayer system
• CPC Class Codes: Y10S 310/80 Piezoelectric polymers, e.g. PVDF
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated

Abstract

An antifouling coating for marine structures in the form of a film containing piezoelectric polymer material, which, when electrically activated vibrates at a selected frequency to present a surface interfacing with water which is inhospitable for attachment of vegetable and animal life including free-swimming organisms thereby discouraging their attachment and their subsequent growth thereon to the macrofoulant adult stage.

Claims

1. A coating for reducing fouling on marine structures comprising:

a film containing piezoelectric polymer secured over substantially the entire surface of the marine structure and separating said surface from water which contains animal and vegetable fouling organisms;

said film having one of its sides in electrical contact with the surface of the marine structure and its other side in electrical contact with the water with which it interfaces;

an electrical power source applying alternating signal across the film;

said alternating signal having a wave form with a quick reversal of direction at its peak thereby causing the film to flick sharply at the film surface for throwing off attaching organisms.

2. The invention according to claim 1 wherein a sheet of electrically conductive material covers the other side of the film in contact with the water.

3. The invention according to claim 2 wherein the signal is applied to the sheet.

4. The invention according to claims 1, 2 or 3 in which the signal is applied at a sweep frequency ranging from as low as 10 hertz to as high as several hundred megahertz.

5. A coating for a marine structure for reducing marine fouling thereon comprising:

a film containing piezoelectric polymer secured over substantially the entire surface of the marine structure separating said surface from water which contains barnacle forming larvae at their attaching stage in life;

said film comprising plural layers of piezoelectric polymer and an electrically conductive sheet sandwiched between the layers defining a common electrode therefore;

said film having one side in electrical contact with the surface of the marine structure to which it is secured and its other side in electrical contact with the water;

a power source applying an alternating signal between the common electrode and both the marine structure surface and other side of the film for electrically activating the piezoelectric polymer layers therebetween for causing vibration of the film at frequencies which the larvae find inhospitable for attachment.

6. The invention according to claim 5 wherein the film comprises plural common electrodes sandwiched between said plural piezoelectric polymer layers.

7. The invention according to claim 5 wherein the signal applied to the other side of the film is applied through the water.

8. The invention according to claim 5 wherein an electrically conductive sheet covers at least a substantial portion of the other side of the film.

9. The invention according to claim 8 wherein the signal is applied to the electrically conductive sheet.

10. The invention according to claims 5, 6, 7, 8, or 9 wherein the alternating signal is applied at a sweep frequency ranging from as low as ten hertz to as high as several hundred megahertz for effecting many kinds of larvae.

11. The invention according to claims 5, 6, 7, 8 or 9 wherein the alternating signal has a wave form with a quick reversal of direction at its peak thereby causing the film to flick sharply in a manner for increasing inhospitality of the film by throwing off attaching larvae.

12. A coating for a marine structure for reducing marine fouling thereon comprising:

a film containing piezoelectric polymer secured over the marine structure separating its surface from water which contains barnacle forming larvae at their attaching stage in life;

said film comprising plural layers of piezoelectric polymer and an electrically conductive sheet sandwiched between the layers defining a common electrode therefore;

said film having one side in electrical contact with the surface of the marine structure to which it is secured and its other side in electrical contact with the water;

a power source applying an alternating signal between the common electrode and both the marine structure surface and other side of the film for electrically activating the piezoelectric polymer layers therebetween for causing vibration of the film at frequencies which the larvae find inhospitable for attachment;

said signal further having a wave form with a quick reversal of direction at its peak for causing the film to flick sharply for increasing inhospitality of the film by throwing off would be attaching larvae.

13. The invention according to claim 12 wherein the alternating signal is applied at sweep frequencies at ranges from as low as ten hertz to as high as several hundred megahertz for effecting many kinds of larvae.

14. The invention according to claim 12 or 13 wherein an electrically conductive sheet covers at least a substantial portion of the other side of the film.

15. The invention according to claim 14 wherein the signal applied to the other side of the film is applied through the electrically conductive sheet.