Process for preparing improved silvered glass mirrors

• US 4,285,992 A
• Filed: 01/28/1980
• Issued: 08/25/1981
• Est. Priority Date: 01/28/1980
• Status: Expired due to Term

• Current Assignee: United States Of America As Represented By The Department Of Energy
• Original Assignee: United States Department of Energy (Government of the United States of America)
• Inventors: Buckwalter, Charles Q. Jr.
• Primary Examiner(s): Hoffman, James R.
• Application Number:
  US06/115,868
• Time in Patent Office: 575 Days
• Field of Search: 427/168, 427/165, 428/622
• US Class Current: 427/165
• CPC Class Codes: C03C 17/10 by deposition from the liquid phase
• CPC Class Codes: C23C 18/44 using reducing agents

Abstract

Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

Claims

1. In the method for preparing silvered mirrors of glass, wherein one surface of the glass is scrubbed with a slurry of an abrasive to clean the surface, a solution of a soluble compound of tin or palladium is applied to the cleaned surface to sensitize the glass, and the sensitized surface is contacted simultaneously with a solution of a soluble silver compound and one or more solutions of caustic and reducer which together with the silver solution react to precipitate a layer of silver on the sensitized surface of the glass, a layer of copper is applied over the layer of silver, and a layer of paint is applied over the layer of copper, the improvement which comprises applying a solution of a soluble compound of lanthanide rare earth ions to the cleaned surface of the glass before the silver is precipitated on the sensitized surface whereby the layer of silver has increased resistance to delamination from the surface of the glass in the presence of moisture.

2. The process of claim 1 wherein the cleaned glass surface is contacted with the solution of rare earth ions before the surface is sensitized, the solution being acidic and containing from 0.01 to 1.0 weight percent rare earths.

3. The process of claim 2 wherein the rare earths are selected from the group consisting of neodymium, praseodymium, erbium, lanthanum, samarium, and dysprosium.

4. The process of claim 1 wherein the cleaned glass surface is contacted with the solution of rare earth after the surface has been sensitized, the solution being acidic and containing from about 0.01 to 1.0 weight percent of rare earths.

5. The process of claim 4 wherein the rare earths are selected from the group consisting of neodymium, praseodymium, erbium, lanthanum, samarium, and dysprosium.

6. The process of claim 5 wherein the sensitizing solution also contains from 0.01 to 1.0 weight percent rare earths whereby the cleaned glass surface is contacted simultaneously with the tin or palladium and the rare earths.

7. The process of claim 6 wherein the rare earths are selected from the group consisting of neodymium, praseodymium, erbium, lanthanum, samarium, and dysprosium.