Furnace and method with sensor

• US 4,290,586 A
• Filed: 02/04/1980
• Issued: 09/22/1981
• Est. Priority Date: 02/04/1980
• Status: Expired due to Term

• Current Assignee: United Process Control Inc. (Micronics Filtration Holdings, Inc.)
• Original Assignee: Corning Glass Works (Corning Incorporated)
• Inventors: Kane, William T., Whitney, William P. II
• Primary Examiner(s): Rutledge, L. Dewayne
• Assistant Examiner(s): Sheehan, John P.
• Application Number:
  US06/118,479
• Time in Patent Office: 596 Days
• Field of Search: 266/80, 266/81, 266/87, 266/90, 266/88, 266/251, 204/195 S, 432/37, 432/42, 73/23, 324/425
• US Class Current: 266/80
• CPC Class Codes: F27B 17/0016 Chamber type furnaces
• CPC Class Codes: F27D 2019/0012 Monitoring the composition of the atmosphere or of one of their components
• CPC Class Codes: F27D 21/00 Arrangements of monitoring devices; Arrangements of safety devices

Abstract

Oxygen sensor comprising solid oxygen-ion-conducting electrolyte with a platinum group metal film electrode contacts and monitors nonoxidizing or reducing gas atmosphere in a metal heat treatment (gas carburizing) furnace after a getter of the same platinum group metal as in the film electrode removes platinum group metal contaminants from such atmosphere before it contacts the electrode. Getter is held in a thin-walled, multi-passaged honeycomb body.

Claims

1. A furnace for heat treatment of metal workpieces in nonoxidizing gas atmosphere containing platinum group metal contaminants, which furnace comprises

an enclosure defining a chamber adapted to contain the workpieces and the atmosphere, the enclosure including at least one wall portion having an oxygen sensor device extending therethrough to monitor the oxygen potential of the atmosphere,

the sensor device comprising a casing with one portion thereof mounted in an opening in the wall portion and a second portion of the casing protruding into the chamber,

the casing having an inlet in the second portion for the atmosphere to continuously enter and flow within the casing from the chamber,

an oxygen sensor mounted within the casing with an electroded portion of the sensor intermediate of the inlet and the one portion of the casing,

the electroded portion comprising a solid oxygen-ion-conducting electrolyte and a film electrode of platinum group metal attached on a surface of the electrolyte arranged to contact the atmosphere flowing within the casing, and

a platinum group metal contaminant getter consisting essentially of the same platinum group metal as in the electrode and arranged in the casing between the inlet and the electroded portion so that the atmosphere passes into contact therewith to effect gettering of the platinum group metal contaminants from the atmosphere.

2. The furnace of claim 1 wherein the getter comprises a thin-walled honeycomb body extending across the casing, having a plurality of passages arranged for the atmosphere to pass therethrough, and having the platinum group metal of the getter contained on the walls of the passages and exposed to the atmosphere passing therethrough.

3. The furnace of claim 1 wherein the electrolyte is stabilized zirconia.

4. The furnace of claim 2 wherein the honeycomb body is of a refractory ceramic.

5. The furnace of claim 4 wherein the ceramic consists essentially of two crystal phase:

zirconia and magnesium aluminate spinel.