Non-woven fabrics bonded by radiation-curable, hazard-free binders

• US 4,291,087 A
• Filed: 06/12/1979
• Issued: 09/22/1981
• Est. Priority Date: 06/12/1979
• Status: Expired due to Term

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Warburton, Charles E. Jr.
• Primary Examiner(s): CANNON, JAMES
• Application Number:
  US06/047,839
• Time in Patent Office: 833 Days
• Field of Search: 204/159.14, 427/44, 427/54, 427/54.1, 427/375, 428/288, 428/290
• US Class Current: 442/148
• CPC Class Codes: D04H 1/587 characterised by the bonding agents used
• CPC Class Codes: D04H 1/64 the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
• CPC Class Codes: Y10T 442/273 Coating or impregnation provides wear or abrasion resistance

Abstract

Non-woven fabrics of fibers, at least 50% by weight of which are hydrophobic, impregnated with a water-insoluble binder of a polymer derived from a monomer mixture of at least one mono-ethylenically unsaturated monomer selected from the group of acrylic and methacrylic acids and ester and amide and nitrile derivatives thereof, vinyl aromatic compounds, vinyl and vinylidine halides, vinyl esters of saturated carboxylic acids, polymerizable ethylenically unsaturated carboxylic acids and esters thereof, alpha-olefins, and diene monomers are disclosed. Optionally, the binder can contain a photosensitive compound of either or both the polymerizable and non-polymerizable types. The polymers are sensitive to radiation, such as electron beam and ultraviolet radiation, and readily cure to a crosslinked condition upon exposure to such radiation. The cured non-woven fabrics have sufficient wet strength and wet abrasion resistance for a variety of uses, for example, use as a durable or permanent fabric for covering mattresses and use as a non-durable or disposable fabric as is used in disposable diapers.

Claims

1. A process for making a non-woven fabric comprising:

a. providing a mass of fibers associated in a random or regular pattern to form a web or mat, at least 50% by weight of the fibers being hydrophobic;

b. contacting with the fibers a hydrophobic binder, which does not contain conventional polymerizable crosslinking agents or unpolymerized ethylenic unsaturation and which does not contain a photosensitive group or compound, comprising a polymer polymerized from a monomer mixture comprising at least one polymerizable mono-ethylenically unsaturated monomer selected from the group consisting of C₂ -C₁₈ alkyl acrylates, C₂ -C₁₈ alkyl methacrylates, vinyl aromatic compounds, vinyl halides, vinylidene halides, vinyl esters of saturated carboxylic acids, polymerizable ethylenically unsaturated mono-carboxylic and dicarboxylic acids and esters thereof, acrylonitrile, methacrylonitrile, alpha-olefins, and diene monomers, the polymer having a molecular weight of from about 50,000 to 10,000,000 and a glass transition temperature of from about -60°

C. to 40°

C.;

c. drying the binder-containing mass of fibers at a temperature above the glass transition temperature of the polymer to effect fusion of the polymer and bonding of the mass of fibers thereby; and

d. exposing the dried binder-containing mass of fibers to a source of radiation, wherein the radiation consists of ultraviolet radiation and electron beam radiation, for a period of time sufficient to effect cure of the polymer by crosslinking the polymer chains, thereby rendering the resulting non-woven fabric resistant to organic dry-cleaning solvents and laundering and increasing the wet strength of the resulting non-woven fabric.

2. The process of claim 1 wherein the hydrophobic fibers are selected from the group consisting of polyolefin and polyester fibers.

3. The process of claim 1 wherein the binder comprises an aqueous emulsion polymer, containing from about 5% to 60% by weight of resin solids, the amount of binder dispersion being about 10% to 80% by weight based on the amount of fiber and binder combined.

4. The process of claim 2 wherein the source of radiation to effect cure of the polymer consists of ultraviolet radiation.

5. The process of claim 2 or 4 wherein the binder comprises an aqueous dispersion of a hydrophobic binder comprising an emulsion polymer, containing from about 5% to 60% by weight of resin solids, the amount of binder dispersion being about 10% to 80% by weight based on the amount of fiber and binder combined.

6. The process of claim 5 wherein the binder comprises an emulsion polymer polymerized from a monomer mixture comprising

(1) about 30-99.5% by weight of at least one C₄ -C₉ alkyl acrylate;

(2) about 0-8% by weight of at least one member selected from the group of acrylic acid, methacrylic acid, itaconic acid and crotonic acid; and

(3) about 0.5-65% by weight of at least one member selected from the group consisting of styrene and vinyl toluene,

wherein the polymer has a glass transition temperature of from -30°

C. to 10°

C., and wherein the fibers are selected from the group consisting of a mass of at least 50% polyester fibers and a mass of at least 50% polypropylene fibers.

7. The process of claim 6 wherein the binder is polymerized from a monomer mixture of

(1) about 40-95% by weight of at least one member selected from the group consisting of butyl acrylate and 2-ethylhexyl acrylate;

(2) about 0-5% by weight of at least one member selected from the group consisting of acrylic acid and methacrylic acid; and

(3) about 20-55% by weight of at least one member selected from the group consisting of styrene wherein the fibers comprise a mass of at least 50% polypropylene fibers.

8. The process of claim 5 wherein the binder comprises an emulsion polymer polymerized from a monomer mixture comprising

(1) about 25-70% by weight of at least one diene monomer selected from the group consisting of butadiene and chloroprene;

(2) about 0-8% by weight of at least one member selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, and crotonic acid; and

(3) about 30-75% by weight of at least one member selected from the group consisting of styrene, vinyltoluene and acrylontrile,

wherein the polymer has a glass transition temperature of from -30°

C. to 10°

C. and wherein the fibers are selected from the group consisting of a mass of at least 50% polyester fibers and a mass of at least 50% polypropylene fibers.

9. The process of claim 8 wherein the binder comprises an emulsion polymer polymerized from a monomer mixture comprising

(1) about 35-55% by weight of butadiene;

(2) about 0-5% by weight of at least one monomer selected from the group consisting of acrylic acid and methacrylic acid; and

(3) about 65-45% by weight of styrene, wherein the fibers comprise a mass of at least 50% polypropylene fibers.

10. An article of manufacture produced by the process of claim 1.

11. An article of manufacture produced by the process of claim 3.

12. An article of manufacture produced by the process of claim 5.