Method of protecting carbon-containing component parts of metallurgical units from oxidation

• US 4,292,345 A
• Filed: 02/04/1980
• Issued: 09/29/1981
• Est. Priority Date: 02/04/1980
• Status: Expired due to Term

• Current Assignee: Alexei V. Vasiliev, Anatoly A. Kuznetsov, Anatoly P. Egorov, Anatoly P. Gobov, Gennady V. Pisarev, Jury M. Ryabukhin, Jury M. Zheleznov, Mikhail I. Kolesnik, Viktor A. Rudakov
• Original Assignee: Alexei V. Vasiliev, Anatoly A. Kuznetsov, Anatoly P. Egorov, Anatoly P. Gobov, Gennady V. Pisarev, Jury M. Ryabukhin, Jury M. Zheleznov, Mikhail I. Kolesnik, Viktor A. Rudakov
• Inventors: Ryabukhin, Jury M., Kuznetsov, Anatoly A., Rudakov, Viktor A., Vasiliev, Alexei V., Egorov, Anatoly P., Zheleznov, Jury M., Kolesnik, Mikhail I., Gobov, Anatoly P., Pisarev, Gennady V.
• Primary Examiner(s): Lusignan, Michael R.
• Application Number:
  US06/118,637
• Time in Patent Office: 603 Days
• Field of Search: 204/290 R, 427/113, 427/314, 427/380, 427/387, 428/408, 252/506, 252/507, 252/508
• US Class Current: 427/113
• CPC Class Codes: C04B 35/52 based on carbon, e.g. graphite
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/4554 the coating or impregnating material being an organic or organo-metallic precursor of an inorganic material
• CPC Class Codes: C04B 41/5092 Phosphate cements
• CPC Class Codes: C04B 41/52 Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
• CPC Class Codes: C04B 41/85 with inorganic materials
• CPC Class Codes: C25C 3/08 Cell construction, e.g. bottoms, walls, cathodes
• CPC Class Codes: C25C 7/025 used in cells for the electrolysis of melts
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

A method of protecting carbon-containing component parts of metallurgical units from oxidation comprises impregnating a component part with orthophosphoric acid to form a glassy mass in the pores of the component part when the latter is heated, drying the component part until the moisture is removed from the pores thereof, additionally impregnating the component part with an elemental organic compound comprising an element: Si, or Ti, or Al and capable of forming a phosphate, and heating the impregnated component part to the temperature at which phosphates are formed.

Claims

1. A method of producing carbon-containing component parts of metallurgical units which are protected against oxidation, comprising the steps of:

(a) impregnating a porous carbon-containing component part with orthophosphoric acid to substantially fill the pores thereof with said orthophosphoric acid;

(b) drying said component part until the moisture is completely removed from the pores of the carbon-containing material;

(c) further impregnating the thus orthophosphoric acid-impregnated component part with an organoelement compound based on an element selected from the group consisting of Si, Ti, and Al, which organoelement compound is capable of reacting with orthophosphoric acid to form phosphates of said elements; and

(d) heating the thus further impregnated component part to a temperature at which said organoelement compound reacts with orthophosphoric acid to form the corresponding phosphates, said phosphates being formed both in the pores and on the surface of the carbon-containing material.

2. The method of claim 1, wherein the further impregnation of the component parts is effected with solutions of silicon organic polymers in organic solvents.

3. The method of claim 2, wherein the component parts after being further impregnated with the solutions of silicon organic polymers are heated to a temperature of 300°

to 350°

C.

4. The method of claim 1, wherein the further impregnation of the component parts is effected with solutions of polyorganosiloxanes in organic solvents.

5. The method of claim 1, wherein the further impregnation of the component parts is effected with solutions of polyalumoorganosiloxanes in organic solvents.

6. The method of claim 1, wherein the further impregnation of the component parts is effected with solutions of polytitanoorganosiloxanes in organic solvents.

7. The method of claim 1, wherein the further impregnation of the component parts is effected with monomeric organoelement compounds having the following formula:

space="preserve" listing-type="equation">(R.sub.1 --O).sub.n --E--(R.sub.2).sub.m

where;

E is an element selected from the group consisting of Si, Ti, Al;

R₁ is a radical selected from the group consisting of alkyl, aryl, aralkyl;

R₂ is alkyl C₁ -C₆,

and quantitative indices range within the following limits;

n is from 1 to 4;

m is from 0 to 3.

8. The method of claim 7, wherein the further impregnation of the component parts is effected with a solution of tetraethoxysilane.

9. The method of claim 7, wherein the further impregnation of the component parts is effected with a solution of triethoxyaluminium.

10. The method of claim 7, wherein the further impregnation of the component parts is effected with a solution of tetraethoxytitanium.

11. The method of claim 1, wherein after further impregnating the component part, the surface thereof is covered with a layer of an elementoorganic compound, whereupon the component part is heated to the temperature at which phosphates are formed.

12. The method of claim 11, wherein the surface of the component part is covered with a suspension of the organoelement compound with a filler, which filler is a finely divided powder of metals and/or their oxides.

13. The method of claim 12, wherein the size of particles of the organoelement compound suspension filler is 5 to 10 μ

m.

14. The method of claim 11, wherein after covering the surface of the component part with a layer of the organoelement compound, heating the component part to the temperature at which phosphates are formed is carried out by step-wise raising of the temperature.

15. The method of claim 14, wherein in further impregnating the component part and covering the surfaces thereof with solutions of silicon organic polymers, the temperature is first raised to 140°

C., then to 240°

C. and finally to 300°

to 350°

C., the rise of temperature being carried out at a rate of 0.5°

to 1.0°

C. per minute and with a holding of the temperature at each of the steps of from 2 to 4 hours.

16. The method of claim 14, wherein in further impregnating the component part and covering the surface thereof with a solution of tetraethoxysilane, the temperature is first raised to 100 to 150°

C., then to 250°

at a rate of 0.5°

to 1.0°

C. per minute and finally to 300°

to 400°

C. at a rate of 1.5°

to 3°

C. per minute, the holding of the temperature at each of the steps ranging from 3 to 6 hours.

17. The method of claim 14, wherein in further impregnating the component part and covering the surface thereof with a solution of triethoxyaluminium, the temperature is first raised to 100°

to 150°

C., then to 250°

C. at a rate of 0.5°

to 1.0°

C. per minute and finally to 350°

to 600°

C. at a rate of 1.5°

to 3.0°

C. per minute, the holding of the temperature at each of the steps ranging from 3 to 6 hours.

18. The method of claim 14, wherein in further impregnating the component part and covering the surface thereof with a solution of tetraethoxytitanium, the temperature is first raised to 100°

to 150°

C., then to 250°

C. at a rate of 0.5°

to 1.0°

C. per minute and finally to 600°

to 800°

C. at a rate of 1.5°

to 3°

C. per minute, the holding of the temperature at each of the steps ranging from 3 to 6 hours.