Reaction apparatus for producing a hydrogen containing gas

• US 4,293,315 A
• Filed: 07/02/1980
• Issued: 10/06/1981
• Est. Priority Date: 03/16/1979
• Status: Expired due to Term

• Current Assignee: United Technologies Corporation (Rtx Corporation)
• Original Assignee: United Technologies Corporation (Rtx Corporation)
• Inventors: Sederquist, Richard A.
• Primary Examiner(s): Kratz, Peter F.
• Application Number:
  US06/165,180
• Time in Patent Office: 461 Days
• Field of Search: 48/197 R, 48/214 R, 48/214 A, 48/196 R, 48/196 A, 48/61, 48/94, 48/95, 48/105, 48/118, 252/373, 423/650, 423/652, 423/653, 423/654, 422/190, 422/191, 422/223
• US Class Current: 48/94
• CPC Class Codes: B01J 2208/025 Two or more types of catalyst
• CPC Class Codes: B01J 2219/185 vertical
• CPC Class Codes: B01J 8/0278 Feeding reactive fluids for solid material B01J8/0015
• CPC Class Codes: B01J 8/0453 the beds being superimposed one above the other
• CPC Class Codes: B01J 8/06 in tube reactors; the solid particles being arranged in tubes
• CPC Class Codes: C01B 3/346 using heat generated by superheated steam
• CPC Class Codes: C01B 3/46 using discontinuously preheated non-moving solid materials, e.g. blast and run

Abstract

A catalytic reaction vessel makes hydrogen from a hydrocarbon feedstock and steam using heat stored in the vessel, and the vessel is then regenerated to restore the heat. Regeneration is done by preheating, separately and within the vessel, an oxygen containing gas and a hydrogen purge gas, and mixing these preheated gases so that they combust within the vessel and heat material disposed in the vessel. This is the heat which is used in converting the hydrocarbon feedstock to hydrogen.

Claims

1. Reaction apparatus constructed to alternately:

(a) make a hydrogen containing gas by the cracking and catalytic steam reforming of a hydrocarbon feedstock; and

(b) be regenerated, comprising;

at least one reaction vessel having an upstream end and downstream end, said vessel having disposed therein, in sequence from its upstream to downstream end, a first volume of inert packing material containing no reform catalyst, a second volume of material substantially adjacent said first volume and including a first region of reform catalyst material, and a third volume of material substantially adjacent said second volume;

said vessel including first inlet means upstream of said second volume for introducing a hydrocarbon feedstock and steam into said first volume during the making of the hydrocarbon containing gas, and first outlet means at said downstream end of said vessel for exhausting the hydrogen containing gas produced in the vessel;

said vessel including second inlet means at its downstream end for introducing a hydrogen purge gas into said third volume during the regeneration of the apparatus, and second outlet means at said upstream end for exhausting gases produced during regeneration; and

conduit means disposed in said vessel and surrounded by at least some of said materials, said conduit means having an inlet means communicating outside said vessel for carrying an oxygen containing gas from outside said vessel into indirect heat exchange relationship with said surrounding materials during regeneration of the apparatus, said conduit means including outlet means within said second volume of material located upstream of said first region of reform catalyst material, said conduit means constructed and arranged with respect to said first region of reform catalyst material to prevent mixing of the oxygen containing gas and hydrogen purge gas downstream of or within said first region of reform catalyst material.

2. The reaction apparatus according to claim 1 wherein said third volume of material includes shift catalyst.

3. The reaction apparatus according to claims 1 or 2 wherein said conduit means passes through said third volume of material and wherein said oxygen containing gas inlet means of said conduit means is located near the downstream end of said third volume of material.

4. The reaction apparatus according to claims 1 or 2 wherein said conduit means is disposed entirely upstream of said first region of reform catalyst.

5. The reaction apparatus according to claims 1 or 2 wherein said second volume of material includes, along the length of said vessel, at least two spaced apart combustion regions of inert packing material containing no reform catalyst, said combustion regions alternating with regions of reform catalyst disposed downstream thereof, and said outlet means of said conduit means including an outlet at the downstream end of each of said combustion regions for introducing a portion of the oxygen containing gas carried by said conduit means during regeneration into each of said combustion regions.

6. The reaction apparatus according to claim 4 wherein said second volume of material includes, along the length of said vessel, at least two spaced apart combustion regions of inert packing material containing no reform catalyst, said combustion regions alternating with regions of reform catalyst disposed downstream thereof, and said outlet means of said conduit means including an outlet at the downstream end of each of said combustion regions for introducing a portion of the oxygen containing gas carried by said conduit means during regeneration into each of said combustion regions.