Method of etching aluminum

• US 4,297,184 A
• Filed: 02/19/1980
• Issued: 10/27/1981
• Est. Priority Date: 02/19/1980
• Status: Expired due to Term

• Current Assignee: Chemi-Con Company Limited (Nippon Chemi-Con Corporation)
• Original Assignee: United Chemi-Con, Inc. (Nippon Chemi-Con Corporation)
• Inventors: Dyer, Christopher K.
• Primary Examiner(s): Valentine, Donald R.
• Application Number:
  US06/122,460
• Time in Patent Office: 616 Days
• Field of Search: 204/129.4, 204/129.43, 204/DIG. 9
• US Class Current: 205/646
• CPC Class Codes: C25F 3/04 of light metals
• CPC Class Codes: H01G 9/055 Etched foil electrodes
• CPC Class Codes: Y10S 204/09 Wave forms

Abstract

A method of etching aluminum by applying an alternating electric current to aluminum which is in contact with an electrolyte containing hydrochloric acid, in which the alternating current has a symmetrical waveform wherein the current rises rapidly from zero to a maximum, then subsequently decreases rapidly in a first stage to an intermediate value which is about one-third to about one-half of the maximum, and thereafter decreases more slowly to zero in a second stage. Thereafter the current rises and falls in the opposite direction with the same waveform. The ratio of time of the second stage to time of the first stage of the waveform is in the range from 1 to 6. By this procedure higher capacitance values of the etched aluminum are obtained in comparison to prior procedures.

Claims

1. In a method of etching aluminum by applying an alternating electric current to aluminum which is in contact with an electrolyte containing hydrochloric acid, the improvement in which the alternating current has a wave form wherein the current rises rapidly from zero to a maximum, then subsequently decreases rapidly in a first stage to an intermediate value which is about one-third to about one-half of the maximum, and thereafter decreases more slowly to zero in a second stage, the ratio of time of the second stage to time of the first stage being in the range from 1 to 6, whereby higher capacitance values of the etched aluminum are obtained.

2. The method of claim 1 wherein the ratio of the second stage to the first stage is in the range from 1 to 3.

3. The method of claims 1 or 2 wherein the waveform of the first stage of current is a triangular wave.

4. The method of claims 1 or 2 wherein the waveform of the first stage of current is a sine wave.

5. The method of claims 1 or 2 wherein the waveform of the first stage of current is a square wave.

6. The method of claims 1 or 2 wherein the current density is in the range from 100 to 300 milliamperes (rms) per square centimeter of aluminum.

7. The method of claim 1 or 2 wherein the frequency of the alternating current is in the range from 15 to 25 hertz.