Process of making permanent magnets

• US 4,297,388 A
• Filed: 04/08/1980
• Issued: 10/27/1981
• Est. Priority Date: 11/06/1978
• Status: Expired due to Term

• Current Assignee: Charles Stark Draper Laboratory Incorporated
• Original Assignee: Charles Stark Draper Laboratory Incorporated
• Inventors: Kumar, Kaplesh, Wettstein, Ernest C., Das, Dilip K.
• Primary Examiner(s): Pianalto, Bernard D.
• Application Number:
  US06/138,650
• Time in Patent Office: 567 Days
• Field of Search: 427/127-132, 427/48, 427/47, 427/34
• US Class Current: 427/550
• CPC Class Codes: C23C 4/134 Plasma spraying
• CPC Class Codes: H01F 1/0551 in the form of particles, e.g. rapid quenched powders or ribbon flakes
• CPC Class Codes: H01F 1/066 obtained by liquid dynamic compaction
• CPC Class Codes: H01F 41/14 for applying magnetic films to substrates

Abstract

Process and apparatus for forming plasma sprayed high density, high coercivity permanent magnet material and permanent magnets formed therefrom. The plasma sprayed permanent magnet material is obtained in a substantially amorphous state resulting from specifically controlled plasma spray parameters. The amorphous deposition possesses high coercivity, density and potential residual magnetism. The as-sprayed magnetic material is preferably heat treated and then densified to nearly maximum theoretical density. The amorphous structure permits retention of substantially all of the coercivity after heat treatment as well as densification to well over 95% of maximum theoretical density. In addition, magnetic materials, preferably fabricated in accordance with this plasma spraying technique as an amorphous deposit of permanent magnet material, are aligned in a magnetic field and thermally aged to produce permanent magnets in the presence of a thermal gradient or mechanical strain resulting in a high coercivity permanent magnet. Controlled crystalline deposits may also be utilized as the starting material for fabrication of the aligned magnets. The invention has application primarily with the use of permanent magnets formed of rare earth-cobalt alloys and in particular of samarium-cobalt alloys.

Claims

1. A process for producing permanent magnet alloy material comprising the steps of:

directing a spray of a molten particulate rare earth-cobalt alloy toward a substrate;

depositing said molten particulate alloy on said substrate; and

controlling the substrate temperature to a temperature below the crystallization temperature of said alloy during deposition to produce a substantially amorphous state deposition for said alloy.

2. The process of claim 1 adapted for producing a rare earth-alloy permanent magnet material comprising the step of:

aligning said deposition in a magnetic field at a predetermined temperature for a predetermined period of time.

3. A process for producing aligned permanent magnets comprising the steps of:

depositing molten particulate rare earth-cobalt alloy magnet material on a substrate in a crystalline state.

controlling the temperature of said substrate during deposition to provide a unidirectional heat flow across the deposit of magnet material; and

magnetically aligning said material.