Piezoelectric polymer antifouling coating and method of use and application

• US 4,297,394 A
• Filed: 03/18/1980
• Issued: 10/27/1981
• Est. Priority Date: 05/31/1979
• Status: Expired due to Term

• Current Assignee: the united states of america as represented by the secretary of the navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: Edelman, Seymour, Wooden, Bruce J.
• Primary Examiner(s): Lesmes, George F.
• Assistant Examiner(s): BUFFALOW, EDITH
• Application Number:
  US06/132,607
• Time in Patent Office: 588 Days
• Field of Search: 252/62.9, 427/100, 428/907, 428/422, 134/1, 106/18.35, 114/222
• US Class Current: 427/100
• CPC Class Codes: B05D 2350/60 Adding a layer before coating
• CPC Class Codes: B05D 5/00 Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
• CPC Class Codes: B05D 5/12 to obtain a coating with specific electrical properties
• CPC Class Codes: B05D 7/14 to metal, e.g. car bodies involving a chemical reaction between the metal and the coating C23
• CPC Class Codes: B05D 7/52 Two layers
• CPC Class Codes: B08B 17/02 Preventing deposition of fouling or of dust
• CPC Class Codes: B63B 59/04 Preventing hull fouling anti-fouling paints C09D5/16
• CPC Class Codes: C09D 5/1662 Synthetic film-forming substance
• CPC Class Codes: C09D 5/1693 as part of a multilayer system
• CPC Class Codes: Y10S 428/907 Resistant against plant or animal attack
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated

Abstract

An antifouling coating with method of use and method of application on marine structures in the form of a film containing piezoelectric polymer material, which, when electrically activated vibrates at a selected frequency to present a surface interfacing with water which is inhospitable for attachment of vegetable and animal life including free-swimming organisms thereby discouraging their attachment and their subsequent growth thereon to the macrofoulant adult stage.

Claims

1. A method of coating the outer surface of an electrically conductive marine structure with a plural layer continuous film for reducing fouling thereon comprising the steps of:

preparing the surface of the structure to insure maximum electrical conductivity;

applying a layer of electrically conductive cement to substantially the entire outer surface to be contacted by water containing fouling organisms;

applying a continuous layer of piezoelectric polymer over the cement;

applying another layer of electrically conductive cement to the polymer layer; and

applying another continuous layer of piezoelectric polymer for interfacing with water.

2. The method according to claim 1 including an additional step of applying a layer of electrically conductive cement on the last layer of polymer to define an electrode therefor.

3. The method according to claim 1 wherein the surface is prepared by sandblasting.

4. The method according to claim 1 wherein the cement is applied by spraying.

5. A method of coating the outer surface of a steel hull ship with a multi-layer film having characteristics to reduce marine fouling thereon comprising the steps of:

providing the ship out of water;

cleaning substantially the entire outer surface of the hull to insure maximum electrical conductivity;

applying a first continuous layer of electrically conductive cement over substantially the entire cleaned surface expected to normally come in contact with water containing fouling organisms;

spraying a continuous layer of statically charged fine grain dry piezoelectric polymer on the conductive coating and applying heat to coalesce;

applying a second layer of electrically conductive cement over the polymer layer;

spraying a continuous layer of statically charged fine grain dry piezoelectric polymer on the second layer of conductive cement and applying heat to coalesce; and

poling the polymer layers.

6. The method according to claim 5 wherein the layers of polymer are poled individually.

7. The method according to claim 5 wherein the polymer layers are poled simultaneously.

8. The method according to claim 5 wherein the hull cleaning step includes sandblasting.

9. The method according to claim 5 wherein the conductive cement is applied by spraying.

10. The method according to claim 5 including an additional step of applying an electrically conductive layer on the outer water facing layer of polymer to define an electrode therefor.

11. The method according to claim 10 wherein the conducting layer is applied by spraying.

12. The method according to claim 5 wherein the ship is provided out of water by drydocking.