Gas generator composition for producing cool effluent gases with reduced hydrogen cyanide content

• US 4,298,412 A
• Filed: 05/04/1979
• Issued: 11/03/1981
• Est. Priority Date: 05/04/1979
• Status: Expired due to Term

• Current Assignee: Thiokol Corporation (Howmet Aerospace, Inc.)
• Original Assignee: Thiokol Corporation (Howmet Aerospace, Inc.)
• Inventors: Biddle, Richard A., Vriesen, Calvin W., Sutton, Ernest S.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US06/035,956
• Time in Patent Office: 914 Days
• Field of Search: 149/19.5, 149/82, 149/83, 149/88, 149/19.1
• US Class Current: 149/19.5
• CPC Class Codes: C06B 23/04 for cooling the explosion gases including antifouling and flash suppressing agents
• CPC Class Codes: C06B 45/10 the organic component containing a resin
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Incorporation of various flame coolants, particularly ferrous oxalate, cupric oxalate and submicron size Fe₃ O₄ in N,N'"'"'-dihydroxyethane diamide containing gas generants results in cooler flame temperature and reduced HCN content. Use of downstream coolants further reduces evolved gas temperature and also further reduces HCN content. Devices incorporating these propellants are useful inflators for many devices such as helicopter flotation bags, cargo pallet soft-landing bags, aircraft escape slides, inflatable life rafts and similar items. They are particularly suitable when these items must be man-rated.

Claims

1. A gas generator composition which produces less than about 0.7 mole percent of HCN upon combustion consisting essentially of a binder component, a polynitrate ester plasticizer component, N,N'"'"'-dihydroxyethane diamide and about 2% to about 8% by weight of a HCN scavenger component selected from the group consisting of cupric oxalate, ferrous oxalate, hydrates of ferrous oxalate, Fe₃ O₄ and mixtures thereof.

2. A gas generator composition as defined in claim 1 wherein the binder component includes a carboxy terminated polyester.

3. A gas generator composition as defined in claim 1 wherein the polynitrate ester plasticizer is trimethylol ethane trinitrate.

4. A gas generator composition as defined in claim 2 wherein the polynitrate ester plasticizer is trimethylol ethane trinitrate.

5. A gas generator composition as defined in claims 1, 2 or 4 wherein the HCN scavenger is a 1:

1 by weight mixture of ferrous oxalate dihydrate and Fe₃ O₄.