Electrophoretic display

• US 4,298,448 A
• Filed: 01/24/1980
• Issued: 11/03/1981
• Est. Priority Date: 02/02/1979
• Status: Expired due to Term

• Current Assignee: BBC Brown Boveri & Company Limited (ABB Limited)
• Original Assignee: BBC Brown Boveri & Company Limited (ABB Limited)
• Inventors: Muller, Klaus, Zimmermann, Andreas
• Primary Examiner(s): Prescott, Arthur C.
• Application Number:
  US06/115,016
• Time in Patent Office: 649 Days
• Field of Search: 350/362, 350/355, 204/299 R, 204/180 R, 96/1 A, 357/73, 355/3
• US Class Current: 359/296
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G03G 17/04 using photoelectrophoresis

Abstract

An electrophoretic display including a cell having two plates spaced apart and provided at least regionally with electrodes, where at least one plate and an associated electrode facing the observer are transparent. The cell contains a suspension consisting of an inert dielectric liquid phase and a dispersed solid phase which at least in part are optically discriminable electrophoretic particles. The individual electrophoretic particles each are of practically the same density as the liquid phase, and at least part of the electrophoretic particles are pigment particles provided with a coating of organic material which is solid at the cell operating temperature but which melts at higher temperatures. The coating material contains at least one charge control agent. The charge control agent, preferably a salt of a divalent metal or metal of higher valency and of an organic acid, imparts a well-defined, uniform surface charge and a well defined, uniform surface potential to the particles.

Claims

1. An electrophoretic display comprising:

a cell having two opposed plates spaced relative to each other and at least regionally provided with electrodes of which at least the plate facing an observer and its electrode are transparent,

said cell containing a suspension consisting of an inert continuous dielectric liquid phase and a dispersed solid phase constituted at least in part by optically discriminable electrophoretic particles, said individual electrophoretic particles all having practically the same density as the liquid phase, and at least part of the electrophoretic particles constituted by pigment particles coated with a sheath of organic material solidified at the cell operating temperature but melting at higher temperatures,

wherein the sheath matrial contains at least one charge control agent so as to impart a well-defined and practically uniform surface charge as well as a well-defined and practically uniform surface potential to the electrophoretic particles.

2. A display as claimed in claim 1 wherein the charge control agent comprises:

a compound selected from the group consisting of a salt and a complex compound of an at least divalent metal and an organic acid.

3. A display as claimed in claims 1 or 2 where the charge control agent is contained in the coating material at least partly in the form of a solid solution.

4. A display as claimed in claim 2 where the organic acid contains at least 5 C-atoms.

5. A display as claimed in claim 4 where the organic acid is a carboxylic acid.

6. A display as claimed in claim 5 where the carboxylic acid is a monobasic acid with at least 8 C-atoms.

7. A display as claimed in claim 6 where the organic acid is an alkanoic or alkenoic acid.

8. A display as claimed in claim 7 where the organic acid is a high fatty acid.

9. A display as claimed in claim 5 where the organic acid is an alicyclic carboxylic acid.

10. A display as claimed in claim 2 where the at least divalent metal is selected from groups IIA, IIIA, or the iron metal group, or where it is Cu(II).

11. A display as claimed in claims 1 or 2 where the organic coating material is a material soluble in the range between 50°

and 150°

C. in practically nonpolar aprotic solvents.

12. A display as claimed in claims 1 or 2 where the coating material at least in part consists of a wax.

13. A display according to claim 5, wherein the organic acid is a monocarboxylic acid.

14. A display according to claim 5, wherein said carboxylic acid is a monobasic acid with at least 12 C-atoms.

15. A display according to claim 7 wherein said organic acid is a high fatty acid selected from the group consisting of a stearic acid or oleic acid.

16. A display according to claim 9 wherein said alicyclic acid consists of naphtheic acid.

17. A display according to claim 12 wherein said wax comprises:

a paraffinic wax which melts at a temperature in the range between 50° and

200°

C.

18. A display according to claim 17 wherein said paraffinic wax has a melting temperature in the range between 50°

and 100°

C.