Process for oilseed extraction with an isopropanol-based solvent

• US 4,298,540 A
• Filed: 12/15/1980
• Issued: 11/03/1981
• Est. Priority Date: 12/15/1980
• Status: Expired due to Fees

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Youn, Kun C., Wilpers, Dale J.
• Primary Examiner(s): Niebling, John F.
• Application Number:
  US06/216,418
• Time in Patent Office: 323 Days
• Field of Search: 260/412.4
• US Class Current: 554/13
• CPC Class Codes: A23J 1/142 by extracting with organic solvents
• CPC Class Codes: C11B 1/10 by extracting

Abstract

A simplified, energy efficient process for regulating the composition of recycle solvent obtained by the phase separation of the extract of oilseed extraction with an isopropanol-based solvent. In the extraction of oilseeds with such a solvent, there is obtained, by cooling of the extract, a solvent-rich liquid phase. The invention provides for regulation of the composition of this phase for purposes of solvent recycle by a process which comprises steps for dividing the phase into a first fraction (between about 60 and 95 percent) and a second fraction (between about 5 and 40 percent), directly recycling the first fraction as solvent for further extraction, distilling the second fraction to recover an overhead vapor-consisting essentially of a constant boiling mixture of isopropyl alcohol and water and a bottoms liquid, and condensing and recycling said overhead as solvent for further extraction. In combination, the first fraction and overhead product solvent recycle streams have a very desirable composition of several extraction system components.

Claims

1. In the process for the recovery of oils from seeds containing extractable oils, comprising steps for contacting seeds having a water content of between about 9 and 13 percent by weight with an isopropanol-based extraction solvent in an extraction zone to obtain an extract of desired seedoils in the solvent, cooling the extract, and phase-separating the cooled extract into a lower liquid oil phase which is rich in seedoils and an upper liquid solvent phase containing recovered solvent, the improvement which comprises dividing the recovered solvent phase of the phase separation into a first division fraction comprising between about 60 and 95 percent of the solvent phase and a second division fraction comprising between about 5 and 40 percent of the solvent phase, directly recycling said first division fraction to the extraction zone as extraction solvent, distilling the second division fraction to yield a liquid distillation bottoms product comprising water and free fatty acids and a vapor distillation overhead product consisting essentially of a constant boiling mixture of isopropyl alcohol and water, condensing said vapor overhead to a liquid distillation overhead product, and recycling said liquid distillation overhead product to the extraction zone as extraction solvent.

4. The process of any one of claims 1, 2 and 3, wherein the seeds have a water content of between about 10 and 12 percent by weight.

5. The process of any one of claims 1, 2 and 3, wherein the first division fraction consists of between about 65 and 85 percent of the solvent phase and the second division fraction consists of between about 15 and 35 percent of the solvent phase.

2. In the process for the recovery of oils from seeds containing extractable oils, comprising steps for

contacting the seeds, having a water content of between about 9 and 13 percent by weight, with an isopropanol-based extraction solvent to obtain an extract of seedoils in solvent and a seed meal,

cooling and phase-separating the extract into a lower liquid oil phase and an upper liquid solvent phase, and

separating from the oil phase of the phase separation step a recovered oil phase solvent,

the improvement which comprises

dividing said upper liquid solvent phase into a first division fraction consisting of between about 60 and 95 percent of the solvent phase and a second division fraction consisting of between about 5 and 40 percent of the solvent phase,

directly recycling said first division fraction to the extraction zone as extraction solvent,

distilling together the second division fraction and the recovered oil phase solvent to obtain an overhead vapor consisting essentially of a constant boiling mixture of isopropanol alcohol and water, and a liquid bottoms,

condensing said overhead vapor and

recycling the condensed overhead vapor to the extraction zone as extraction solvent.

3. In the process for the recovery of oils from seeds containing extractable oils, comprising steps for

contacting the seeds, having a water content of between about 9 and 13 percent by weight, with an isopropanol-based extraction solvent to obtain an extract of seedoils in solvent and a seed meal,

cooling and phase-separating the extract into a lower liquid oil phase and an upper liquid solvent phase,

separating from the seed meal a recovered meal solvent, and

separating from the oil phase of the phase separation step a recovered oil phase solvent,

the improvement which comprises

dividing said upper liquid solvent phase into a first division fraction consisting of between about 60 and 95 percent of the solvent phase and a second fraction consisting of between about 5 and 40 percent of the solvent phase,

directly recycling said first division fraction to the extraction zone as extraction solvent,

distilling together the second division fraction, the recovered meal solvent, and the recovered oil phase solvent to obtain an overhead vapor consisting essentially of a constant boiling mixture of isopropyl alcohol and water, and a liquid bottoms,

condensing said overhead vapor, and

recycling the condensed overhead vapor to the extraction zone as extraction solvent.