Method and apparatus for converting hazardous material to a relatively harmless condition

• US 4,299,611 A
• Filed: 01/18/1980
• Issued: 11/10/1981
• Est. Priority Date: 01/18/1980
• Status: Expired due to Term

• Current Assignee: Toxgon Corporation
• Original Assignee: Penberthy H. Larry
• Inventors: Penberthy, H. Larry
• Primary Examiner(s): Serwin, Ronald
• Application Number:
  US06/113,346
• Time in Patent Office: 662 Days
• Field of Search: 65/27, 65/134, 65/135, 65/136, 65/336
• US Class Current: 65/27
• CPC Class Codes: B09B 3/29 involving a melting or softening step
• CPC Class Codes: C03B 3/00 Charging the melting furnaces
• CPC Class Codes: C03B 5/005 of glass-forming waste materials disposal or transformation of solid waste in general B09B; treatment of radioactive waste G21F9/00
• CPC Class Codes: C03B 5/03 Tank furnaces
• CPC Class Codes: C03B 5/04 in tank furnaces C03B5/02 takes precedence
• CPC Class Codes: C03B 5/235 Heating the glass C03B5/02, C03B5/18, C03B5/225 take precedence
• CPC Class Codes: C03B 5/26 Outlets , e.g. drains, siphons; Overflows , e.g. for supplying the float tank, tweels
• CPC Class Codes: F23G 5/085 High-temperature heating means, e.g. plasma, for partly melting the waste
• CPC Class Codes: F23G 5/10 electric
• CPC Class Codes: F23J 15/025 using filters
• CPC Class Codes: F23J 2217/104 High temperature resistant (ceramic) type

Abstract

A glass material is directed into an elongate enclosed conversion chamber, where it is either converted to or maintained in a molten state by heating through the Joule effect. Waste material is directed onto the glass material at the inlet end of the conversion chamber, and sufficient oxygen is directed into the chamber to cause combustion of the waste material which is capable of being burned. A portion of the ashes created by combustion fall on the glass material and become a part thereof. The gaseous combustion products proceed horizontally through the elongate conversion chamber, and additional ash material suspended in the gaseous combustion products settles onto the glass material and also becomes a part thereof. The gaseous exhaust is directed through a plurality of ceramic fiber filter components which capture the small particulate material that remains suspended in the gaseous exhaust. These filter components are periodically discharged into the molten glass material to become a part thereof and/or to become oxidized. The glass material, with the other material added thereto, is periodically discharged to a cooling area to form a solidified product incorporating the ash product of the waste material.

Claims

1. A method for converting potentially harmful waste material to a less potentially harmful condition, said method comprising:

a. providing a glass material in an enclosed horizontally extending conversion chamber, said chamber comprising a rear breakdown area and a forward settling area spaced horizontally from the breakdown area, and maintaining said glass material in a molten condition in a lower portion of said chamber,

b. directing said waste material into said conversion chamber at a location proximate said glass material at said breakdown area,

c. maintaining said glass material at a sufficiently high temperature to cause the waste material to be broken down into an ash component and a gaseous component, with at least some of the ash component being particulate ash suspended in said gaseous component,

d. moving said gaseous component generally horizontally from said breakdown area to a location over said molten glass material in said settling area, with at least part of said suspended particulate ash settling onto the molten glass material in the settling area to form a combined ash-glass material,

e. discharging said combined ash-glass material to a cooling zone to form said waste-glass material into a solid waste-glass product.

2. The method as recited in claim 1, wherein at least a portion of said waste material is combustible, said method further comprising maintaining said glass material at a sufficiently high temperature and providing sufficient oxidizing gas to cause combustion of said combustible waste material.

3. The method as recited in claim 1, wherein at least a portion of said waste material is metallic, said method further comprising providing an initial combustion area spaced from said breakdown area, directing at least said metallic portion of the waste material into said initial combustion area, oxidizing said metallic portion to metal oxides, and directing said metal oxides onto said molten glass material.

4. The method as recited in claim 1, wherein

a. at least a portion of said waste material is combustible, said method further comprising maintaining said glass material at a sufficiently high temperature and providing sufficient oxidizing gas to cause combustion of said combustible waste material to form at least a portion of said ash product,

b. at least a portion of said waste material is metallic, said method further comprising providing an initial combustion area spaced from said breakdown area, directing at least said metallic portion of the waste into said initial combustion area, oxidizing said metallic portion to metal oxides, and directing said metal oxides onto said molten glass material.

5. The method as recited in claim 1, further comprising directing said gaseous component from said settling area through at least one filter component made of a filter material which can be combined with said glass material, capturing at least some of said suspended particulate ash in said filter component, then discharging said filter component into said molten glass material so that said filter component with said particulate ash becomes incorporated in said glass material.

6. The method as recited in claim 1, further comprising directing said gaseous component from said settling area through at least one filter component made of a filter material which is at least partly combustible, capturing at least some of said suspended particulate ash in said filter component, then discharging said filter component into said molten glass material so that said particulate ash becomes incorporated in said glass material.

7. The method as recited in claim 5 or 6, further comprising providing a plurality of filter components arranged in series with one another and directing said gaseous component from said settling area through said filter components, said method further comprising discharging said filter components sequentially into said glass material so that particulate ash in the filter component becomes incorporated in said glass material.

8. The method as recited in claim 1, wherein said glass material is heated by passing electric current therethrough.

9. The method as recited in claim 1, wherein

a. at least a portion of said waste material is combustible, said method further comprising maintaining said glass material at a sufficiently high temperature and providing sufficient oxidizing gas to cause combustion of said combustible waste material to form at least a portion of said ash product.

b. at least a portion of said waste material is metallic, said method further comprising providing an initial combustion area spaced from said breakdown area, directing at least said metallic portion of the waste material into said initial combustion area, oxidizing said metallic portion to metal oxides, and directing said metal oxides onto said molten glass material,

c. further comprising providing a plurality of filter components arranged in series with one another and directing said gaseous component from said settling area through said filter components, said method further comprising discharging said filter components sequentially into said glass material so that said filter components with particulate ash therein become incorporated in said glass material.

10. A method for converting waste material to a relatively harmless condition, said method comprising:

a. directing a glass material into an enclosed conversion chamber and maintaining said glass material in a molten condition in said chamber

b. directing said waste material onto said glass material in the conversion chamber

c. maintaining said glass material at a sufficiently high temperature to cause said material to be broken down into an ash component and a gaseous component, with at least some of said ash component being particulate ash suspended in said gaseous component,

d. moving said gaseous component through at least one filter component comprising a material which can be combined with said glass material,

e. capturing at least some of said particulate ash in said filter component,

f. then moving said filter component into said glass component so that said filter component with the particular ash contained therein becomes incorporated in said glass material, so that there is a combined ash-glass material,

g. discharging said combined ash-glass material to a cooling zone to form said ash-glass material into a solid waste glass product.

11. The method as recited in claim 10, further comprising providing a plurality of filter components arranged in series with one another and directing said gaseous component from said settling area through said filter components, said method further comprising discharging said filter components sequentially into said glass material so that at least a portion of said filter components with particulate ash therein become incorporated in said glass material.

12. An apparatus for converting waste material to a relatively harmless condition, said apparatus comprising:

a. means defining an enclosed horizontally extending conversion chamber, said chamber having a rear breakdown area and a forward settling area spaced horizontally from the breakdown area, said chamber further having a lower elongate portion adapted to contain a molten glass material, and an upper portion adapted to contain a gaseous component,

b. rear inlet means leading into the breakdown area, said inlet means adapted to direct said waste material and said glass material into said conversion chamber

c. forward discharge means adapted to discharge a combined ash-glass material from said settling area,

d. means to discharge said gaseous component from said settling area

e. means to maintain said glass material in said conversion chamber at an adequately high temperature to cause breakdown of waste material in said breakdown area,

whereby when the hazarous waste material is directed onto the molten glass material in the breakdown area, the waste material is broken down into an ash component and a gaseous component, with at least some of the ash component being particulate ash suspended in the gaseous component, and said gaseous component moves over said settling area with at least part of suspended particulate ash settling onto the molten glass in the settling area to form the combined ash-glass material which can then be discharged from the settling area to a cooling zone to form a solid waste-glass product.

13. The apparatus as recited in claim 12, further comprising means defining an initial combustion area spaced from the breakdown area, said initial combustion area being adapted to receive a metallic portion of the waste material, and adapted to maintain said metallic portion at a sufficiently high temperature to cause oxidation of the metallic portion, said initial combustion area leading into said breakdown area so that metal oxides formed from said metallic portion can be directed onto said molten glass material in the breakdown area.

14. The apparatus as recited in claim 12, further comprising means defining a gaseous discharge passageway leading from said settling area, at least one filter component positioned in said gaseous discharge passageway, said filter component comprising a filter material which can be combined with the glass material, means to discharge said filter component into the molten glass material so that the filter component with particulate ash being captured therein can be incorporated in said glass material.

15. The apparatus as recited in claim 12, further comprising means defining a gaseous discharge passageway leading from said settling area, at least one filter component positioned in said gaseous discharge passageway, said filter component comprising a filter material which is at least partly combustible, means to discharge said filter component into the molten glass material so that particulate ash being captured therein can be incorporated in said glass material.

16. The apparatus as recited in claim 14 or 15, further comprising a plurality of filter components arranged in series in the gas discharge passageway, said discharge means being adapted to discharge said filter components sequentially into said glass material.

17. An apparatus for converting waste material to a relatively harmless condition, said apparatus comprising:

a. means defining an enclosed conversion chamber, said chamber having a lower portion adapted to contain a molten glass material, and an upper portion adapted to contain a gaseous component,

b. inlet means leading into said conversion chamber and adapted to direct the waste material and glass material into the conversion chamber,

c. discharge means adapted to discharge a combined ash-glass material from the conversion chamber

d. means defining a discharge passageway for said gaseous component,

e. means to maintain said glass material in the conversion chamber at an adequately high temperature to cause breakdown of waste material in the conversion chamber

f. at least one filter component positioned in said discharge passageway, said filter component comprising a filter material which can be combined with the glass material,

g. means to discharge the filter component into the glass material so that the filter component with particulate ash being captured therein can be incorporated in the glass material.

18. The apparatus as recited in claim 17, wherein there is a plurality of filter components arranged in series in the discharge passageway, with said discharge means being adapted to discharge said filter components sequentially into the glass material.

19. An apparatus for converting waste material to a relatively harmless condition, said apparatus comprising:

a. means defining an enclosed conversion chamber, said chamber having a lower portion adapted to contain a molten glass material, and an upper portion adapted to contain a gaseous component,

b. inlet means leading into said conversion chamber and adapted to direct the waste material and glass material into the conversion chamber,

c. discharge means adapted to discharge a combined ash-glass material from the conversion chamber,

d. means defining a discharge passageway for said gaseous component,

e. means to maintain said glass material in the conversion chamber at an adequately high temperature to cause breakdown of waste material in the conversion chamber,

f. at least one filter component positioned in said discharge passageway, said filter component comprising a filter material which is combustible,

g. means to discharge the filter component into the glass material so that particulate ash being captured therein can be incorporated in the glass material.

20. The apparatus as recited in claim 19, wherein there is a plurality of filter components arranged in series in the discharge passageway, with said discharge means being adapted to discharge said filter components sequentially into the glass material.