Slip coated polyester film

• US 4,302,506 A
• Filed: 06/12/1980
• Issued: 11/24/1981
• Est. Priority Date: 01/05/1979
• Status: Expired due to Term

• Current Assignee: Hoechst Diafoil Company
• Original Assignee: American Hoechst Corporation (Sanofi )
• Inventors: Heberger, John M.
• Primary Examiner(s): Cannon, James C.
• Application Number:
  US06/158,661
• Time in Patent Office: 530 Days
• Field of Search: 428/341, 428/483, 428/524
• US Class Current: 428/341
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 2433/00 Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: Y10T 428/273 of coating
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31942 Of aldehyde or ketone condensation product

Abstract

A polyester film coated with a slip composition is provided. The film includes a polyester film support coated on at least one side with a latex coating. The coating includes stearamidopropyldimethyl-β-hydroxy-ethylammonium nitrate present in a coating weight in the range of up to 0.003 pounds per thousand square feet of biaxially oriented polyester film. The coating further includes a cross-linkable methylmethacrylate-ethylacrylate-methacrylamide terpolymer having a glass transition temperature in the range of between about 40° C. and 50° C. The terpolymer is present in a concentration in the range of between about 0.75 percent and 1.25 percent by weight, based on the total weight of the latex coating. The weight ratio of the nitrate to the terpolymer ranges between about 2.75:1 to below 3:1.

A process for forming the above film is also disclosed. In this process a latex coating of the composition described above is coated onto a uniaxially drawn polyester film support. The uniaxially drawn film is then heated to drive off the water and thereafter the uniaxially coated film is stretched in a direction normal to the uniaxial drawn film.

Claims

1. A biaxially oriented polyester film comprising a polyester film support coated on one or both sides with a latex coating, said coating comprising:

stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate, present in a concentration in the range of between 2.75 percent and 3.25 percent by weight, based on the total weight of the latex coating; and

a cross-linkable methylmethacrylate-ethyl acrylatemethacrylamide terpolymer, having a glass transition temperature in the range of between about 40°

C. and 50°

C., present in a concentration in the range of between about 0.75 percent and 1.25 percent by weight based on the total weight of the latex coating wherein the weight ratio of said stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate to said cross-linkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer is in the range of between about 2.75;

1 and 3.25;

1 and wherein the total dry coating weight of said coating on said polyester film is less than 0.003 pounds per thousand square feet of biaxially oriented film.

2. A polyester film in accordance with claim 1 wherein said total dry coating weight is at least about 0.001 but less than 0.003 pounds per thousand square feet of biaxially stretched film.

3. A film in accordance with claim 1 wherein the weight ratio of said stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate to said cross-linkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer is in the range of between about 2.75;

1 and 3.0;

1.

4. A film in accordance with claim 1 wherein said polyester is polyethylene terephthalate.

5. A film in accordance with claim 1 wherein said stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate is present in said latex coating in a concentration in the range of between about 2.9 percent and 3.1 percent by weight, based on the total weight of said latex coating.

6. A film in accordance with claim 5 wherein said stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate is present in said latex coating in a concentration of about 3.0 percent by weight, based on the total weight of said latex coating.

7. A film in accordance with claim 1 wherein said cross-linkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer is present in said latex coating in a concentration in the range of between about 0.9 percent and 1.1 percent by weight based on the total weight of said latex coating.

8. A film in accordance with claim 7 wherein said cross-linkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer is present in said latex coating in a concentration of about 1.0 percent by weight, based on the total weight of said latex coating.

9. A film in accordance with claim 1 wherein said cross-linkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer has a glass transition temperature of between about 43°

C. and 47°

C.

10. A film in accordance with claim 9 wherein said crosslinkable methylmethacrylate-ethylacrylate-methacrylamide terpolymer has a glass transition temperature of 45°

C.

11. A film in accordance with claim 2 or 4 wherein said total dry coating weight is from about 0.001 to about 0.00285 pounds per thousand square feet of biaxially oriented polyester film.

12. A film in accordance with claim 2 or 4 wherein said total dry coating weight is from about 0.002 to about 0.00285 pounds per thousand square feet of biaxially oriented polyester film.