Syringe

• US 4,303,070 A
• Filed: 09/22/1980
• Issued: 12/01/1981
• Est. Priority Date: 10/09/1979
• Status: Expired due to Term

• Current Assignee: Terumo Corporation
• Original Assignee: Terumo Corporation
• Inventors: Ichikawa, Toshiji, Watanabe, Teruko
• Primary Examiner(s): Vasko, John D.
• Application Number:
  US06/189,148
• Time in Patent Office: 435 Days
• Field of Search: 128/218 P, 128/218 R, 128/234, 128/215, 128/224, 92/245, 92/249
• US Class Current: 604/222
• CPC Class Codes: A61M 2205/0222 Materials for reducing friction
• CPC Class Codes: A61M 2205/6081 Colour codes
• CPC Class Codes: A61M 5/31513 Piston constructions to improve sealing or sliding

Abstract

A syringe includes an outer cylinder, a gasket having at least one part which slidably contacts the inner wall of the cylinder and being made of an elastomer material including a block copolymer having styrene units at both terminal ends, and means for sliding the gasket inside the cylinder. The slidably contacting part is compressed inside the cylinder at a compressiblity C (%) of a predetermined range selected according to a particular inner diameter of the cylinder. The product of the total contact area S (mm²) at the compressibility C (%) of the contacting part with the inner wall of the cylinder with the compressibility C (%) is about 350 to about 900.

Claims

1. A syringe comprising an outer cylinder;

a gasket having at least one part which slidably contacts the inner wall of said outer cylinder under the compressed condition forming a water-tight seal and being made of a colorable thermoplastic elastomer material including a block copolymer having a mean molecular weight between about 50,000 and about 200,000 and having the general formula

space="preserve" listing-type="equation">(St).sub.m (A).sub.n (St).sub.m '"'"'

(where St represents styrene units, A represents a unit derived from an unsaturated hydrocarbon having 2-5 carbon stoms or combinations thereof, and m, m'"'"' and n represent the mol % of each unit, the sum of m and m'"'"' being 2-20 mol %); and

means for sliding said gasket inside said outer cylinder, said slidably contacting part being compressed inside said outer cylinder at a compressibility C (%) of a predetermined range selected according to a particular inner diameter of said outer cylinder, the product (S×

C) of the total contact area S (mm²) of said slidably contacting part with the inner wall of said outer cylinder with said compressibility C (%) being about 350 to about 900, the value of S (mm²) being measured at said compressibility C (%).

2. A syringe as claimed in claim 1 wherein said elastoner material contains 5 to 200 parts by weight of polyolefin-based resin based on 100 parts by weight of the block copolymer.

3. A syringe as claimed in claim 2 wherein said gasket comprises a cylindrical body defined by a first end face, a second end face and a circumferential face;

a conical head portion integrally formed with said first end face of said body; and

an annular groove formed in said circumferential face of said body, said annular groove forming two slidably contacting parts having flat top faces each defined by part of said circumferentail face.

4. A syringe as claimed in claim 3 wherein said slidably contacting parts have trapezoidal sectional areas.

5. A syringe as claimed in claim 4 wherein the top face of the contacting part and the side of the groove intersects at an angle of 10°

to 30°

.

6. A syringe as claimed in claim 2 wherein A represents a unit derived from a combination of ethylene and isobuthylene, or isoprene.

7. A syringe as claimed in claim 2 wherein said block copolymer has a mean molecular weight between about 50,000 and about 150,000.

8. A syringe as claimed in claim 2 wherein said bock copolymer contains a total of 2 to 10 mol % of the styrene units.

9. A syringe as claimed in claim 2 wherein said polyolefin-based resin is polyethlene, polypropylene or ethylene-propylene copolymer.

10. A syringe as claimed in claim 2 wherein said elastoner material contains the polyolefin-based resin in an amount of 10 to 180 parts by weight based on 100 parts by weight of the block copolymer.

11. A syringe as claimed in any one of claims 1 to 10 wherein said compressibility C (%) is selected from the range of 0.6 to 18.3 % according to the particular inner diameter of the outer cylinder.

12. A syringe as claimed in claim 10, wherein said outer cylinder has an inner diameter of about 4.7 mm, and the compressibility C (%) is selected from the range of 3.9 to 18.3 %.

13. A syringe as claimed in claim 10, wherein said outer cylinder has an inner diameter of about 6.5 mm, and the compressibility C (%) is selected from the range of 2.8 to 11.6 %.

14. A syringe as claimed in claim 10, wherein said outer cylinder has an inner diameter of about 9.0 mm, and the compressibility C (%) is selected from the range of 2.0 to 9.5 %.

15. A syringe as claimed in claim 10, wherein said outer cylinder has an inner diameter of about 13.0 mm, and the compressibility C (%) is selected from the range of 0.6 to 6.8%.

16. A syringe as claimed in claim 10, wherein said outer cylinder has an inner diameter of about 15.8 mm, and the compressibility C (%) is selected from the range of 1.1 to 5.7 %.

17. A syringe as claimed in claim 10, wherein said outer cylinder has an inner diameter of about 20.1 mm, and the compressibility C (%) is selected from the range of 1.0 to 4.7%.

18. A syringe as claimed in claim 10, wherein said outer cylinder has an inner diameter of about 23.1 mm, and the compressibility C (%) is selected from the range of 1.5 to 6.3 %.

19. A syringe as claimed in claim 10, wherein said outer cylinder has an inner diameter of about 29.1 mm, and the compressibility C (%) is selected from the range of 2.5 to 6.3%.

21. A syringe as claimed in claim 1 wherein said elastomer material contains 5 to 200 parts by weight of polyolefin-based resin based on 100 parts by weight of the block copolymer.

20. A gasket for a syringe, made of a colorable elastomer material including a block copolymer having a mean molecular weight between about 50,000 and about 200,000 and having the general formula