Method of treating coal to remove sulfur and ash

• US 4,305,726 A
• Filed: 12/21/1979
• Issued: 12/15/1981
• Est. Priority Date: 12/21/1979
• Status: Expired due to Term

• Current Assignee: George E. Brown Jr
• Original Assignee: George E. Brown Jr
• Inventors: Brown, George E. Jr.
• Primary Examiner(s): DEES, CARL
• Application Number:
  US06/106,278
• Time in Patent Office: 725 Days
• Field of Search: 44/1 SR, 201/17
• US Class Current: 44/605
• CPC Class Codes: C10L 9/02 by chemical means

Abstract

The present invention is directed to an improved method of chemically treating coal to remove sulfur and ash. It is especially adapted for use on high sulfur, refuse coal. In practice the coal is treated with hydrochloric acid and hypochlorous acid in the presence of ferric and ferrous sulfate to convert the iron pyrites to other sulfur compounds. These are then converted to various salts of calcium through neutralization with lime.

Claims

1. A method of treating pulverized coal to remove sulfur comprising:

adding spent sulfuric acid pickle liquor to said coal,

adding to said coal a mixture of water with chlorine gas added thereto, the amount of pickle liquor and chlorine gas being an amount sufficient to provide a mixture having a pH of less than about 3, and

physically separating said coal from said mixture.

2. The method of claim 1 wherein the mixture remaining after the coal has been removed is neutralized so as to provide a precipitate comprising in substantial part inorganic sulfates.

3. The method of claim 1 wherein a substantial amount of ash is physically separated from the mixture simultaneously with the separation of the coal from the mixture.

4. The method of claim 3 wherein the mixture remaining after the removal of the coal and ash fractions is neutralized so as to provide a precipitate comprising in substantial part inorganic sulfates.

5. The method of claim 2 or claim 4 wherein lime is used as the neutralizing agent.

6. The method of claim 5 wherein the precipitate is used to treat dead bodies of water.

7. The method of claim 3 wherein the coal and ash are separated from the mixture through the use of a water flow.

8. The method of claim 7 wherein the coal is refuse coal.

9. A process for removing ash and sulfur from coal wherein sulfur is present consisting essentially of the following steps:

(a) forming a coal and water mixture,

(b) treating the mixture with an acidic oxidizing agent so as to convert the sulfur to a sulfur containing acid(s), said oxidizing agent comprising HCL, HOCL and nascent oxygen formed through the addition of CL₂ to water, the amount of CL₂ being an amount sufficient to convert the sulfur to a sulfur containing acid(s),

(c) physically separating any ash from the mixture,

(d) treating the remaining coal mixture containing the sulfur containing acid(s) with lime whereby the sulfur is precipitated as calcium salts, and

(e) physically separating the calcium salts from the coal.

10. The method of claim 9 wherein the coal to be treated is refuse coal and the coal after treatment has less than 6% ash, less than about 1% sulfur and a BTU content of about 14,000 per pound.

11. The method of claim 9 wherein the amount of water is about 10-20% by weight of the coal.