Low density cement slurry and its use

• US 4,305,758 A
• Filed: 09/04/1980
• Issued: 12/15/1981
• Est. Priority Date: 06/11/1979
• Status: Expired due to Term

• Current Assignee: Amoco Corporation (BP PLC)
• Original Assignee: Standard Oil Company (BP PLC)
• Inventors: Smith, Robert C., Holman, George B., Powers, Charles A.
• Primary Examiner(s): Poer, James
• Application Number:
  US06/183,888
• Time in Patent Office: 467 Days
• Field of Search: 106/97
• US Class Current: 106/676
• CPC Class Codes: C04B 14/24 porous, e.g. foamed glass
• CPC Class Codes: C09K 8/46 containing inorganic binders, e.g. Portland cement

Abstract

A 9 to 12 ppg (1.08 to 1.4 kg/liter) cement slurry for use in oil well type completions which comprises hydraulic cement about 10 to about 30 weight percent hollow glass microspheres based on the weight of the cement and sufficient water to form a pumpable slurry with an API free water content of no more than about 2 volume percent. This slurry is preferably mixed with an amount of water required to produce a slurry with the hydraulic cement having at least an API minimum water content and an API free water content of no more than about 2 volume percent and an additional amount of water equal to about 1.3 to about 1.8 weight percent water based on the weight of the hydraulic cement for each weight percent of the microspheres. The microspheres have true particle densities of about 0.2 to about 0.5 gm/cm³, hydrostatic collapse strengths of at least 500 psi (3447 kPa) and average particle diameters of less than about 500 microns.

Claims

1. A hydraulic cement slurry which comprises as its essential components:

hydraulic cement, about 8 to about 50 weight percent hollow glass microspheres by weight of the cement and sufficient water to form a pumpable slurry, wherein the API free water content of said slurry is no more than about 2 volume percent based only on said hydraulic cement and said microspheres, and said microspheres have ANSI/ASTM D 2840-69 average true particle densities of about 0.2 to about 0.5 gm/cm³, ANSI/ASTM D 3102-72 hydrostatic collapse strengths of at least 500 psi (3447 kPa) and average particle diameters of less than about 500 microns.

7. The cement slurry of claim 1, 2, 3, 4, 5 or 6 which comprises sufficient water to form a pumpable slurry with at least an API minimum water content and an API free water content of no more than 2 volume percent.

8. The cement slurry of claim 1, 2, 3, 4, 5 or 6 which comprises sufficient water to form a pumpable slurry with at least an API minimum water content and an API free water content of less than about 1 volume percent.

9. The cement slurry of claim 1, 2, 3, 4, 5, or 6 which comprises sufficient water to form a pumpable slurry with an API normal water content.

10. The cement slurry of claim 1, 2, 3, 4, 5, or 6 wherein said microspheres have ANSI/ASTM average true particle densities of about 0.3 to about 0.4 gm/cm³.

11. The cement slurry of claim 1, 2, 3, 4, 5, or 6 wherein the average particle diameters of said microspheres are about 10 to about 300 microns.

12. The cement slurry of claim 1, 2, 3, 4, 5, or 6 wherein said hydraulic cement is portland cement.

13. The cement slurry of claim 1, 2, 3, 4, 5, or 6 wherein said slurry comprises about 10 to about 30 weight percent hollow glass microspheres based on the weight of the cement.

14. The cement slurry of claim 1, 2, 3, 4, 5, or 6 wherein said slurry comprises, as substantially all of the water in the slurry, an amount of water required to produce a slurry with the hydraulic cement having at least an API minimum water content and an API free water content of no more than about 2 volume percent and an additional amount of water equal to about 1.2 to about 2.2 weight percent water based on the weight of the cement for each weight percent of said microsphere.

15. The cement slurry of claim 13 wherein said slurry comprises, as substantially all of the water in the slurry, an amount of water required to produce a slurry with the hydraulic cement having at least an API minimum water content and an API free water content of no more than about 2 volume percent and an additional amount of water equal to about 1.3 to about 1.8 weight percent water based on the weight of the cement for each weight percent of said microsphere.

16. The cement slurry of claim 1, 2, 3, 4, or 6 wherein said hollow glass microspheres are further characterized in that said microspheres having ANSI/ASTM average true particle densities of about 0.3 gm/cm³ have ANSI/ASTM hydrostatic collapse strengths after collapse of about 10 volume percent of said microspheres of at least about 1000 psi (6895 kPa).

17. The cement slurry of claim 16 wherein said hollow glass microspheres are further characterized in that said microspheres having ANSI/ASTM average true particle densities of about 0.4 gm/cm³ have ANSI/ASTM hydrostatic collapse strengths after collapse of about 10 volume percent of said microspheres of least about 4000 psi (27,579 kPa).

18. The cement slurry of claim 1, 2, 3, 4, or 6 wherein said microspheres are further characterized in that said microspheres have ANSI/ASTM hydrostatic collapse strengths after collapse of about 10 volume percent of said microspheres substantially as shown in FIG. 2.

19. The cement slurry of claim 1, 2, 3, 4, or 5 wherein said microspheres are manufactured by the procedure described in Beck, et al, U.S. Pat. No. 3,365,315.

2. A hydraulic cement slurry which comprises:

hydraulic cement, from about 8 to about 50 weight percent hollow glass microspheres by weight of the cement and sufficient water to form a pumpable slurry with an API free water content of no more than about 2 volume percent, wherein said slurry is free from effective amounts of sodium metasilicate and said microspheres have ANSI/ASTM D 2840-69 average true particle densities of about 0.2 to about 0.5 gm/cm³, ANSI/ASTM D 3102-72 hydrostatic collapse strengths of at least 500 psi (3447 kPa) and average particle diameters of less than about 500 microns.

3. A cement slurry which comprises:

hydraulic cement, about 8 to about 50 weight percent hollow glass microspheres based on the weight of the cement and, as substantially all of the water in the slurry, an amount of water required to produce a pumpable slurry with the hydraulic cement and microspheres having an API free water content of no more than about 2 volume percent, wherein said microspheres have ANSI/ASTM D 2840-69 true particle densities of about 0.2 to about 0.5 gm/cm³, ANSI/ASTM D 3102-72 hydrostatic collapse strengths of at least 500 psi (3447 kPa) and average particle diameters of less than about 500 microns.

4. A cement slurry which comprises:

hydraulic cement, about 8 to about 50 weight percent hollow glass microspheres based on the weight of the cement and, as substantially all of the water in the slurry, an amount of water required to produce a pumpable slurry with the hydraulic cement having an API free water content of no more than about 2 volume percent and an additional amount of water equal to about the amount shown in FIG. 4 for each weight percent of said microspheres, wherein said microspheres have ANSI/ASTM D 2840-69 true particle densities of about 0.2 to about 0.5 gm/cm³, ANSI/ASTM D 3102-72 hydrostatic collapse strengths of at least 500 psi (3447 kPa) and average particle diameters of less than about 500 microns.

5. A cement slurry which comprises:

hydraulic cement, about 8 to about 50 weight percent hollow glass microspheres based on the weight of the cement and an amount of water required to produce a pumpable slurry with an API free water content of less than about 2 volume percent, wherein said microspheres have ANSI/ASTM D 2840-69 average true particle densities of about 0.2 to about 0.5 gm/cm³, average particle diameters of less than about 500 microns and ANSI/ASTM D 3102-72 hydrostatic collapse strength after collapse of about 10 volume percent of said microspheres substantially as shown in FIG. 2.

6. A cement slurry which comprises:

hydraulic cement, about 8 to about 50 weight percent hollow glass microspheres based on the weight of the cement and an amount of water required to produce the pumpable slurry with an API free water content of less than about 2 volume percent, wherein said microspheres are manufactured by the procedure described in Beck, et al, U.S. Pat. No. 3,365,315, have ANSI/ASTM D 2840-69 average true particle densities of about 0.2 to about 0.5 gm/cm³, ANSI/ASTM D 3102-72 hydrostatic collapse strengths of at least 500 psi (3447 kPa) and average particle diameters of less than about 500 microns.

20. A pumpable, lightweight hydraulic cement slurry useful for oilfield cementing and the like comprising a mixture of a finely-ground hydraulic cement;

between about 8 and 50 weight percent (by weight of cement) of finely-divided hollow glass microspheres having a density not substantially exceeding an ANSI/ASTM average true particle density of 0.5 gm/cm³, an ANSI/ASTM hydrostatic collapse strength of at least 500 psi (3447 kPa), and a softening temperature not less than about 480°

C., said microspheres having an average particle diameter in the range of about 10 to about 300 microns; and

water in an amount to produce a maximum slurry consistency not substantially exceeding 30 B_c (API) and less than that producing 2 volume percent free water content (API).

21. A slurry in accordance with claim 20 in which the amount of water in said slurry is in excess of the API normal water content for said hydraulic cement by an amount ranging substantially between 1.2 weight percent to 2.2 weight percent (by weight of cement) per each weight percent of said hollow spheres (by weight of cement).

22. A slurry in accordance with claim 21 in which said hollow spheres are made of sodium borosilicate glass and said excess of water is of the order of 1.3% to 1.8 weight percent (by weight of cement) per each weight percent of said hollow spheres (by weight of cement).

23. A set hydraulic cement slurry of relatively high strength and low thermal conductivity at elevated temperatures (that is, at temperatures of the order of at least 230°

F. or 110°

C.)

comprising an essentially homogeneous mixture of commercially available portland cement and a density reducer comprising between 8 and 50 weight percent (by weight of cement) of finely-divided hollow glass microspheres having an ANSI/ASTM true particle density in the range of about 0.2 to about 0.5 gm/cm³, an ANSI/ASTM hydrostatic collapse strength of at least about 500 psi (3447 kPa), average particle diameters in the range of about 10 to about 300 microns, and a thermal conductivity of the order of 8 to 11 (Kcal)(cm)(hr)(sq m)(°

C.), to which was added during slurrying an amount of water, (in excess of the conventional amount of water based on the cement for producing a slurry with said cement having an API normal water content), amounting to between about 1.2 and about 2.2 weight percent times the weight percent of said spheres.