Method of preparing ultraphosphoric acid

• US 4,309,394 A
• Filed: 04/09/1980
• Issued: 01/05/1982
• Est. Priority Date: 04/09/1980
• Status: Expired due to Term

• Current Assignee: Astaris LLC (ICL Group Ltd.)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Hudson, Robert B.
• Primary Examiner(s): Vertiz, O. R.
• Assistant Examiner(s): HELLER, GREGORY
• Application Number:
  US06/138,616
• Time in Patent Office: 636 Days
• Field of Search: 423/317, 423/318, 423/319, 423/320, 423/321 R, 423/321 S, 423/316
• US Class Current: 423/317
• CPC Class Codes: C01B 25/16 Oxyacids of phosphorus; Salts thereof peroxyacids or salts thereof C01B15/00
• CPC Class Codes: C01B 25/20 Preparation from elemental phosphorus or phosphoric anhydride
• CPC Class Codes: C01B 25/24 Condensed phosphoric acids

Abstract

Ultraphosphoric acid containing a phosphorus to hydrogen ratio of greater than 1 can be prepared by bringing together in a reaction zone elemental phosphorus and a sufficient amount of oxygen in a free-oxygen containing gas to form phosphorus pentoxide, and a sufficient amount of water to form ultraphosphoric acid. The mole ratio of water to phosphorus pentoxide is maintained less than 1:1. Heat is removed from the product stream of the reaction zone to condense at least some of the ultraphosphoric acid which is then collected. In the preferred embodiment, a heat exchange fluid such as pressurized water is circulated through a cooling coil positioned to remove heat from the product stream of the reaction zone. The ultraphosphoric acid can be combined with water to provide polyphosphoric acid.

Claims

1. A process for preparing ultraphosphoric acid which comprises:

(a) bringing together in a reaction zone elemental phosphorus, a sufficient amount of oxygen in a free-oxygen containing gas to form phosphorus pentoxide, and sufficient water to form ultraphosphoric acid, the mole ratio of water to phosphorus pentoxide being less than 1;

1, to form a product stream;

(b) removing heat from the product stream to cool the product stream below the dew point of ultraphosphoric acid; and

(c) collecting the ultraphosphoric acid.

2. A process of claim 1 wherein the mole ratio of water to phosphorus pentoxide is at least 1:

5 but less than 1;

1.

3. A process of claim 1 wherein the mole ratio of water to phosphorus pentoxide is at least about 0.6:

1 but less than about 0.9;

1.

4. A process of claim 3 wherein the free-oxygen containing gas is air and at least about 30 percent over the amount required to form phosphorus pentoxide is introduced into the reaction zone.

5. A process of claim 3 wherein the free-oxygen containing gas is air and less than about 200 percent over the stoichiometric amount required to form phosphorus pentoxide is introduced into the reaction zone.

6. A process of claim 1 wherein heat is removed by circulating a heat exchange fluid through a cooling surface placed in the product stream.

7. A process of claim 6 wherein the cooling surface is maintained between about 150°

C. and about 800°

C.

8. A process of claim 6 wherein the heat exchange fluid is selected from the group consisting of noble gases, free-nitrogen containing gases, eutectic salt mixtures, pressurized water and steam.

9. A process of claim 6 wherein the heat exchange fluid is pressurized water.

10. A process of claim 6, 7 or 9 wherein the cooling surface is a cooling coil positioned to remove heat from the product of the reaction zone.

11. A process of claim 1 wherein the collected ultraphosphoric acid is combined with sufficient water to provide polyphosphoric acid.

12. A process for preparing ultraphosphoric acid in a phosphorus burner which comprises:

(a) bringing together in a reaction zone elemental phosphorus, a free-oxygen containing gas containing at least 30 percent in excess of stoichiometric amount of oxygen required to form phosphorus pentoxide, and sufficient water to form ultraphosphoric acid, the mole ratio of water to phosphorus pentoxide being at least about 1;

5 but less than 1;

1;

(b) removing heat from the product stream by placing a cooling surface maintained between about 150°

C. and about 300°

C. to cool the product stream to below the dew point of ultraphosphoric acid;

(c) condensing at least some of the ultraphosphoric acid on the cooling surface; and

(d) recovering the ultraphosphoric acid.

13. A process of claim 12 wherein the mole ratio of water to phosphorus pentoxide is at least about 0.6:

1 but less than about 0.9;

1.

14. A process of claim 13 wherein heat is removed from the product stream by circulating pressurized water through the cooling surface.