Method for heat-sealing textile materials with polyurethane adhesives

• US 4,310,373 A
• Filed: 02/08/1980
• Issued: 01/12/1982
• Est. Priority Date: 02/17/1979
• Status: Expired due to Term

• Current Assignee: Firma Carl Freudenberg
• Original Assignee: Firma Carl Freudenberg
• Inventors: Schuhmacher, Gunter, Wagner, Sepp, Fahrbach, Erich
• Primary Examiner(s): Gallagher, John J.
• Application Number:
  US06/119,954
• Time in Patent Office: 704 Days
• Field of Search: 156/306.6, 156/331, 156/308.2, 156/331.7, 2/87, 428/200, 428/423.1, 428/246, 428/423.3, 528/65
• US Class Current: 156/308.2
• CPC Class Codes: C08G 18/664 with compounds of group C08G18/3203
• CPC Class Codes: C08G 18/73 acyclic
• CPC Class Codes: C08G 2170/00 Compositions for adhesives
• CPC Class Codes: C08G 2170/20 Compositions for hot melt adhesives
• CPC Class Codes: D06M 17/10 Polyurethanes polyurea
• CPC Class Codes: Y10T 428/24843 with heat sealable or heat releasable adhesive layer
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31554 Next to second layer of polyamidoester
• CPC Class Codes: Y10T 442/3667 Composite consisting of at least two woven fabrics bonded by an interposed adhesive layer [but not two woven fabrics bonded together by an impregnation which penetrates through the thickness of at least one of the woven fabric layers]

Abstract

The invention described herein relates to a method for heat sealing the opposing surfaces of planar textile materials which comprises applying a heat-seal adhesive to at least one of the opposing surfaces of the textiles, and then pressing the opposing surfaces of the textiles together under heat and pressure to heat-seal the textile surfaces together. The heat-seal adhesive employed is a low-melting polyurethane prepared by reacting at least one diisocyanate with at least one polyol having a molecular weight between about 500 and 5000, at least one diol which is branched or includes an ether group, and at least one diol which is unbranched. The diol reactants have an average molecular weight of less than about 500. The total hydroxyl group content of the reactants exceeds or equals the total isocyanate content of the reactants.

Claims

1. A method for heat-sealing planar textile materials which comprises:

(a) applying a heat-seal adhesive in the form of a spun-bonded fabric to a polyurethane coated fabric; and

(b) pressing said spun-bonded adhesive and polyurethane coated fabric together under heat and pressure to heat-seal said spun-bonded fabric to said polyurethane coated fabric;

wherein

(c) said heat-seal adhesive is a polyurethane which melts below about 150°

C., prepared by reacting a solvent-free mixture of at least one diisocyanate, polybutylene glycol-ethylene glycol-adipic acid polyester having a molecular weight of about 1,000 to about 2,000 and an hydroxyl number of about 56, and a mixture of three diols comprising neopentyl glycol, diethylene glycol and 1,4-butane diol; and

in the ratio of isocyanate to hydroxyl groups of the reactants in said reaction mixture times 100 being from about 96 to about 100; and

said heat-seal adhesive has a melting range which is below about 125°

C.

2. The method according to claim 1 wherein said polyurethane coated fabric is a polyurethane coated poplin fabric.

3. The method according to claim 2 wherein said reaction mixture is comprised of about 50 to 70 parts of a diisocyanate which is 1,6-hexamethylene diisocyanate and about 100 parts of said polyester.

4. The method according to claim 1 wherein said reaction mixture further includes a monofunctional compound selected from the group consisting of dibutylamine, ε

-caprolactam, neopentyl alcohol or mixtures thereof, wherein the amount of said monofunctional compound comprises less than about 5 mole percent of the total amount of said diols in said reaction mixture; and

wherein said polyurethane coated fabric is a polyurethane coated poplin fabric.

5. A method of heat-sealing planar textile materials which comprises:

(a) applying a heat-seal adhesive in the form of a spun-bonded fabric to at least one of the surfaces of a textile material, and

(b) pressing said spun-bonded fabric and textile together under heat and pressure;

wherein

(c) said heat-seal adhesive is a polyurethane adhesive which melts below about 150°

C., which is prepared by reacting a solvent-free mixture of a diisocyanate, a polybutylene glycol-ethylene glycol-adipic acid polyester, and a mixture of at least three diols wherein at least one diol is branched or includes an ether group, and at least one diol in said mixture is an unbranched diol, wherein the average molecular weight of said diols is less than about 500; and

wherein the ratio of isocyanate groups to hydroxyl groups in said reaction mixture times 100 is from about 96 to about 100.

6. The method according to claim 5 wherein said polyester has a molecular weight of from about 1,000 to about 2,000.

7. The method according to claim 5 wherein the mole ratio of said branched or ether group containing diols to said unbranched diols is within the range of from about 20:

80 to about 75;

25.

8. The method according to claim 7 wherein at least one diol of the reaction mixture is selected from the group consisting of neopentyl glycol, 2,2'"'"'-diethylpropane-1,3-diol, diethylene glycol and 1,5-pentane diol;

and of the other diols comprising said diol mixture at least one other diol is selected from the group consisting of ethylene glycol, 1,4-butane diol or 1,6-hexane diol.

22. The method according to claim 6 wherein said polyurethane is applied to said fabric in the form of a thermal bonded spun fabric.

9. A method for heat-sealing planar textile materials which comprises:

(a) applying a heat-seal adhesive in the form of a spun-bonded fabric to at least one of the surfaces of a textile, and

(b) pressing the opposing surfaces of said textile and spun-bonded fabric together under heat and pressure to heat-seal them together;

wherein

(c) said heat-seal adhesive is a polyurethane which melts below about 150°

C., prepared by reacting a solvent-free mixture of at least one diisocyanate, a polyester having a molecular weight of from about 500 to about 5,000, and a mixture of at least three diols, wherein said diol mixture is comprised of at least one diol which includes an ether group, at least one branched diol and at least one unbranched diol component, and wherein the average molecular weight of said diols in said mixture is less than about 500; and

wherein the ratio of isocyanate groups to hydroxyl groups in the reaction mixture times 100 is from about 96 to about 100.

10. The method according to claim 9 wherein said polyurethane is prepared from a reaction mixture of polybutylene glycol-ethylene glycol adipic acid polyester having an OH-number of 56, and a molecular weight of 2000;

1,6-hexamethylene diisocyanate, neopentyl glycol, diethylene glycol, and 1,4-butane diol; and

wherein said polyurethane is applied to said fabric in the form of a thermally bonded spun fabric.

11. The method in accordance with claim 9 wherein said mixture of diols is comprised of neopentyl glycol, diethylene glycol and at least one unbranched diol component;

said polyester is a polybutylene glycol-ethylene glycol-adipic acid polyester having a molecular weight of from about 1,000 to 2,000, and wherein the melting range of said adhesive is below about 125°

C.

12. The method according to claim 9 wherein said polyester is a polybutylene glycol-ethylene glycol-adipic acid polyester having a molecular weight of about 1,000 to about 2,000.

13. The method according to claim 11 wherein said polyester is a polybutylene glycol-ethylene glycol-adipic acid polyester having a molecular weight of about 2,000 and an OH number of about 56.

14. The method according to claim 9 wherein said polyurethane is prepared by reacting a solvent-free mixture comprised of about 50 to 70 parts of a diisocyanate and 100 parts by weight of a polyester which is a polybutylene glycol-ethylene glycol-adipic acid polyester having a molecular weight of from about 1,000 to about 2,000, in the presence of a diol mixture comprised of neopentyl glycol, diethylene glycol and a third unbranched diol component.

15. The method according to claim 14 wherein at least one surface of said textile is polyurethane coated.

16. The method according to claim 15 wherein said fabric is a polyurethane coated poplin fabric.

17. The method according to claim 11 or 5 wherein the ratio of isocyanate groups/hydroxyl groups times 100 in said reaction mixture is within the range of from about 97 to about 99.

18. The method according to claim 11 or 5 wherein said diisocyanate is 1,6-hexamethylene-diisocyanate.

19. The method according to claim 11 or 5 wherein said mixture further includes at least one monofunctional compound having an active hydrogen, wherein said monofunctional compounds are selected from the group consisting of the amines, amides and alcohols;

wherein the amount of said monofunctional compounds comprises less than about 5 mole percent of the total amount of said low molecular weight diols in said reaction mixture.

20. The method according to claim 19 wherein said monofunctional compound is selected from the group consisting of dibutylamine, ε

-caprolactam, neopentyl alcohol or mixtures thereof.

21. The method according to claim 11 or 5 wherein said polyurethane is applied to said fabric in the form of a thermally bonded spun fabric.

23. The method according to claim 18 wherein said polyurethane is applied to said fabric in the form of a thermal bonded spun fabric.

24. The method according to claim 19 wherein said polyurethane is applied to said fabric in the form of a thermal bonded spun fabric.

25. The method according to claim 20 wherein said polyurethane is applied to said fabric in the form of a thermal bonded spun fabric.

26. The method according to claim 21 wherein said spun fabric further includes a thermally settable polyester, having a melting range which is about equal to the melting range of said polyurethane.

27. The method according to claim 26 wherein said spun fabric includes from about 33 to about 67 percent by weight of said polyester.

28. The method according to claim 21 wherein at least one of said textiles is a fabric which has been coated with polyurethane.