Protective coating process for aluminum and aluminum alloys

• US 4,310,390 A
• Filed: 06/27/1980
• Issued: 01/12/1982
• Est. Priority Date: 08/10/1977
• Status: Expired due to Term

• Current Assignee: Lockheed Corporation (Martin Marietta Corporation)
• Original Assignee: Lockheed Corporation (Martin Marietta Corporation)
• Inventors: Bradley, Robert E., Keithler, William R.
• Primary Examiner(s): Metz, Andrew
• Assistant Examiner(s): Leader, William
• Application Number:
  US06/163,821
• Time in Patent Office: 564 Days
• Field of Search: 204/35 N, 204/37 R, 204/38 A, 204/38 E, 427/388, 427/409, 427/388.2, 427/388.4, 427/419.5, 148/6.27
• US Class Current: 205/204
• CPC Class Codes: B05D 2202/25 based on Al
• CPC Class Codes: B05D 2350/40 by adding a porous layer
• CPC Class Codes: B05D 3/102 Pretreatment of metallic substrates C23C takes precedence
• CPC Class Codes: B05D 7/16 using synthetic lacquers or varnishes
• CPC Class Codes: C09D 5/08 Anti-corrosive paints
• CPC Class Codes: C25D 11/18 After-treatment, e.g. pore-sealing

Abstract

A process is described for sealing anodic coatings on aluminum and the alloys of aluminum while simultaneously impregnating the anodic coating with organic resin during the sealing operation, thereby providing a protective coating to the anodized aluminum which, among other things has superior corrosion resistant characteristics.

A specified water-borne resin coating material possessing excellent stability at temperatures in excess of 200° F. is used to convert the unsealed anodic coating to the monohydrate/trihydrate form of aluminum oxide during the sealing step of an otherwise conventional aluminum anodizing process. Subsequently, the sealed anodic film is cured at temperatures up to 500° F. This process provides a total protection system having characteristics superior to separately sealed and organically primed aluminum obtained through conventional processing.

Claims

1. A protective coating process for aluminum and aluminum alloy components comprising the steps of:

anodizing the component to be coated;

applying a coating composition comprising a water soluble acrylic polymer or copolymer and a nitrogenous cross-linking agent to the anodized component at a temperature in the range of approximately 170°

F. to 200°

F. for a period ranging from about 30 to 60 minutes, the time and temperature being inversely related whereby said composition seals the anodized component through hydration and simultaneously primes the anodized component providing a surface coating capable of being cross-linked during a subsequent curing operation; and

curing the sealed and primed component at a temperature in the range of approximately 200°

F. to 500°

F. for approximately 1 to 60 minutes, the time and temperature being inversely related.

2. The process of claim 1 wherein said application of the coating composition is accomplished by immersion of said component in the composition for about one hour and maintaining the temperature at about 175°

F.

3. The process of claim 1 wherein said application of the coating composition is accomplished by immersion of said component in the composition for about 30 minutes and maintaining the temperature at about 180°

F.

4. The process of claim 3 wherein the cross-linking agent is hexamethoxy methyl melamine.

5. The process of claim 1 wherein the cross-linking agent is a polyalkyl ether of a polymethylol melamine wherein each alkyl group contains from 1 to 4 carbon atoms.

6. The process of claim 1 wherein said curing is effected by adding to said coating composition a Friedel-Crafts catalyst in an amount sufficient to promote thorough curing when exposed to temperatures of 200°

F. to 500°

F. for approximately 1 to 60 minutes, the time and temperature being inversely related, followed by curing under the aforesaid conditions.

7. The process of claim 1 wherein the coating composition includes a corrosion inhibitor containing water soluble metallic salts of chromium, molybdenum and tungsten.