Soft corneal contact lens with tightly cross-linked polymer coating and method of making same
First Claim
1. A soft corneal contact lens comprising a soft, highly oxygen-permeable, polymeric lens having formed on the surface thereof an ultrathin, optically clear, lipid-permeable hydrophilic barrier coating comprising the reaction product resulting from an electrical glow discharge polymerization process conducted in a gaseous atmosphere, said atmosphere consisting essentially of at least one compound selected from the group consisting of(a) hydrocarbons;
- (b) halogenated hydrocarbons;
(c) halogenated hydrocarbons and hydrogen;
(d) hydrocarbons and an elemental halogen; and
(e) mixtures thereof.
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Accused Products
Abstract
A soft corneal contact lens comprising a soft, highly oxygen-permeable, polymeric lens having formed on the surface thereof an ultrathin, optically clear, impermeable barrier coating. The barrier coating is tightly cross-linked and comprises the reaction product resulting from an electrical glow discharge polymerization process conducted in a gaseous atmosphere and will prevent diffusion into the lens of lipids and other large molecules from the eye'"'"'s tear film. The lens is formed from silicone or polyurethane. The gaseous atmosphere consists essentially of compounds selected from the group consisting of hydrocarbons; halogenated hydrocarbons; halogenated hydrocarbons and hydrogen; hydrocarbons and a halogen; and a mixture of any two or more of these compounds. The surface of the fully formed lens is highly hydrophilic which is accomplished during the polymerization process or in an additional step comprising glow discharge in the presence of oxygen or argon.
377 Citations
20 Claims
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1. A soft corneal contact lens comprising a soft, highly oxygen-permeable, polymeric lens having formed on the surface thereof an ultrathin, optically clear, lipid-permeable hydrophilic barrier coating comprising the reaction product resulting from an electrical glow discharge polymerization process conducted in a gaseous atmosphere, said atmosphere consisting essentially of at least one compound selected from the group consisting of
(a) hydrocarbons; -
(b) halogenated hydrocarbons; (c) halogenated hydrocarbons and hydrogen; (d) hydrocarbons and an elemental halogen; and (e) mixtures thereof. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14)
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15. A method of forming a soft, optically clear, lipid-impermeable, highly oxygen-permeable hydrophilic corneal contact lens comprising the steps of
(a) providing a soft, polymeric, oxygen-permeable lens, (b) placing the lens into an electrical glow discharge polymerization apparatus, (c) providing a gaseous atmosphere in the apparatus, the gaseous atmosphere consisting essentially of at least one compound selected from the group consisting of (1) hydrocarbons, (2) halogenated hydrocarbons, (3) halogenated hydrocarbons and hydrogen, (4) hydrocarbons and an elemental halogen, and (5) mixtures thereof; - and
(d) subjecting the gaseous atmosphere to an electrical glow discharge under conditions sufficient to cause the compounds to form a plasma resulting in the formation of a lipid-impermeable, highly oxygen-permeable, optically clear hydrophilic barrier coating on the surface of the lens, the coating being the polymerization reaction product of the compounds and of the lens. - View Dependent Claims (16, 17, 18, 19, 20)
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Specification