Heat-reactivatable adsorbent gas fractionator and process

• US 4,312,641 A
• Filed: 05/25/1979
• Issued: 01/26/1982
• Est. Priority Date: 05/25/1979
• Status: Expired due to Term

• Current Assignee: First Union National Bank of North Carolina One First Union Center
• Original Assignee: Pall Corporation (Danaher Corporation)
• Inventors: White, Donald H. Jr., Verrando, Marcel G.
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US06/042,397
• Time in Patent Office: 977 Days
• Field of Search: 55/33, 55/28, 55/208, 55/179, 55/387, 55/389, 55/58, 55/62, 55/68, 55/74, 55/75, 55/180, 55/196, 219/10.55 R, 34/1, 34/4, 34/10, 34/39
• US Class Current: 95/105
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2259/40094 by applying microwaves
• CPC Class Codes: B01D 2259/401 using a single bed
• CPC Class Codes: B01D 2259/402 using two beds
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0423 Beds in columns
• CPC Class Codes: B01D 53/261 by adsorption
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes
• CPC Class Codes: B01J 20/3441 Regeneration or reactivation by electric current, ultrasound or irradiation, e.g. electromagnetic radiation such as X-rays, UV, light, microwaves

Abstract

A process and appartus are provided for removing a first gas from a mixture thereof with a second gas. The gas mixture is passed through a sorbent bed having a preferential affinity for the first gas and comprising a microwave absorbent capable of absorbing microwave energy and the first gas is sorbed on the sorbent so as to produce a gaseous effluent which has a concentration of first gas therein below a predetermined maximum. Then the first gas sorbed on the sorbent bed is removed therefrom by application of microwave energy, at a temperature at which the microwve absorbent absorbs such energy and activates the first gas sufficiently to desorb the first gas, while passing a purge flow of gas in contact with the bed to flush out desorbed first gas from the bed. The bed is allowed to cool to a relatively efficient temperature for adsorption. The gas mixture is then again passed in contact with the bed. If two beds are used, one bed can be desorbed while the other is on-stream, thereby maintaining a substantially continuous flow of effluent gas.

The apparatus of the invention provides a sorbent bed assembly having a microwave energy generator positioned to direct such energy into a sorbent bed comprising a microwave absorbent capable of absorbing microwave energy for desorption of first gas from the sorbent bed.

Claims

1. In the process for removing a first gas from a mixture thereof with a second gas by flow of the gas mixture continuously through a sorbent bed having a preferential affinity for the first gas which includes the steps of passing the gas mixture in contact with and from one end to another end of a first bed of the sorbent;

sorbing first gas thereon and, as the sorption of the first gas continues, forming a concentration gradient of first gas in the first bed progressively decreasing from one end to the other end of the bed ranging from a substantial proportion of the first sorbent capacity therefor at one end to less than 20% of its capacity therefor at the other end, so as to produce a gaseous effluent which has a concentration of the first gas therein below a predetermined maximum;

removing first gas sorbed on the second sorbent bed by passing a purge flow of effluent gas in contact with the sorbent bed, discontinuing the purge flow, and then resuming passing the gas mixture in contact with the sorbent bed, the improvement which consists essentially in utilizing a sorbent transparent to microwave energy having a frequency within the range of about 0.03 to about 3000 giga Hertz, and combining with the sorbent a microwave absorbent capable of absorbing microwave energy within said range in an amount sufficient to activate and desorb sorbed first gas on the sorbent, and then desorbing first gas by applying during the purge flow microwave energy having a frequency within the range of about 0.03 to about 3000 giga Hertz at a temperature at which the sorbent is transparent to microwave energy, the microwave energy being preferentially adsorbed by the microwave absorbent and then activating first gas sorbed on the sorbent and thereby desorbing first gas, and halting application of the microwave energy when desorption of first gas is substantially complete, and before water of hydration of the sorbent is removed.

2. A process according to claim 1 in which the application of microwave energy is at a temperature below about 500°

F.

3. A process according to claim 2 in which the sorbent is a desiccant.

4. A process according to claim 1 in which the sorbed material is water.

5. A process according to claim 4 in which the sorbent is a molecular sieve.

6. A process according to claim 4 in which the sorbent is alumina.

7. A process according to claim 4 in which the sorbent is silica gel.

8. A process according to claim 1 in which the microwave absorbent is graphite.

9. A process according to claim 1 in which the purge gas is at effluent gas temperature and is not heated.

10. A process according to claim 1 in which the microwave absorbent is mixed with the sorbent.

11. A process according to claim 1 in which the microwave absorbent is coated on the sorbent.

12. A process according to claim 1 in which the microwave absorbent is adsorbed on the sorbent.

13. A process for reducing the concentration of a first gas in a mixture thereof with a second gas to below a limiting maximum concentration thereof in the second gas, which consists essentially in passing the mixture in contact with and from one end to another of a stationary bed of a sorbent having a preferential affinity for the first gas and transparent to microwave energy having a frequency within the range of about 0.03 to about 3000 giga Hertz;

and comprising a microwave absorbent capable of absorbing microwave energy within said range;

adsorbing first gas on the sorbent to form a gaseous effluent having a concentration thereof below the maximum, and as the adsorption continues forming a concentration gradient of first gas on the bed progressively decreasing from the one end to the other end, and an increasing concentration of first gas in the second gas defining a concentration front progressively advancing in the bed from the one end to the other end as sorbent capacity therefor decreases;

discontinuing passing the gaseous mixture in contact with the bed before the front can leave the bed, and the limiting maximum concentration of first gas in the second gas can be exceeded; and

then desorbing the first gas adsorbed on the sorbent bed by application of microwave energy having a frequency within the range of about 0.03 to about 3000 giga Hertz at a temperature at which the microwave absorbent absorbs such energy and activates and thereby desorbs first gas adsorbed on the sorbent bed while passing therethrough a purge gas flow to flush desorbed first gas from the bed.

14. A process according to claim 13 in which the application of microwave energy is at a temperature below about 500°

F.

15. A process according to claim 13 in which purge gas is gaseous effluent from the adsorption.

16. A process according to claim 13 in which the desorption is at a gas pressure lower than that during adsorption.

17. A process according to claim 13 in which the desorption is of a duration less than the sorption, and application of microwave energy is discontinued when desorption is substantially complete.

18. A process according to claim 13 in which at least two sorbent beds are used, and adsorption is carried on in one sorbent bed while another sorbent bed is being desorbed, so that adsorption is continuous and always in progress in at least one of the sorbent beds.

19. A process in accordance with claim 13 in which the first gas is water vapor.

20. A process in accordance with claim 13 in which the sorbent is silica gel.

21. A process in accordance with claim 13 in which the microwave absorbent is graphite.

22. A process in accordance with claim 13 wherein the purge flow is of effluent gas from the bed sorbing the first gas.

23. A process in accordance with claim 13 which comprises removing sorbed first gas at a reduced pressure relative to the pressure of adsorption.

24. A process in accordance with claim 13 in which the microwave absorbent is mixed with the sorbent.

25. A process in accordance with claim 13 in which the microwave absorbent is coated on the sorbent.

26. A process in accordance with claim 13 in which the microwave absorbent is adsorbed on the sorbent.

27. An apparatus for reducing the concentration of a first gas in a mixture thereof with a second gas to below a limiting maximum concentration thereof comprising, in combination, a stationary bed of sorbent having a preferential affinity for the first gas;

and transparent to microwave energy having a frequency within the range of about 0.03 to about 3000 giga Hertz; and

comprising a microwave absorbent capable of absorbing microwave energy within said range;

an inlet line for delivering influent gas at an inlet end of the bed; and

an outlet line for delivering effluent gas from an outlet end of the bed;

means for applying to the sorbent bed microwave energy having a frequency within the range of about 0.03 to about 3000 giga Hertz for desorbing first gas from the bed at the conclusion of an adsorption cycle; and

means for supplying a flushing flow of purge gas during application of microwave energy to remove desorbed first gas from the bed.

28. An apparatus according to claim 27 comprising at least two sorbent beds disposed in separate chambers and connected to the lines for reception of influent gas to be dried, and for delivery of effluent gas;

and at least one valve for cycling the flow of influent gas to one of the beds at a time, and for receiving the flow of effluent gas from one of the beds at a time.

29. An apparatus according to claim 28 comprising a pressure-reducing valve for reducing pressure during desorption.

30. An apparatus according to claim 28 comprising a valve to divert a portion of the dried effluent gas as purge through the bed being desorbed.

31. An apparatus according to claim 28 comprising a valve to divert a portion of the dried effluent gas as purge in counterflow through the bed being desorbed.

32. An apparatus according to claim 27 in which the microwave generator comprises a magnetron tube as a source of microwave energy.

33. An apparatus according to claim 27 in which the microwave generator comprises an amplitron tube as a source of microwave energy.