Process for injection molding of polyethylene terephthalate compositions at reduced mold temperature

• US 4,313,903 A
• Filed: 11/19/1979
• Issued: 02/02/1982
• Est. Priority Date: 11/19/1979
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Bier, Peter
• Primary Examiner(s): Czaja, Donald E.
• Assistant Examiner(s): Thompson, W.
• Application Number:
  US06/095,275
• Time in Patent Office: 806 Days
• Field of Search: 264/328.1, 260/45.8, 525/6
• US Class Current: 264/328.1
• CPC Class Codes: C08L 2666/36 Nitrogen-containing compounds
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence

Abstract

This disclosure is concerned with a process for injection molding polyethylene terephthalate into colder molds, i.e., less than 120° C., and still obtaining crystalline parts by incorporating an organic imide containing compound having a melting point in excess of 240° C. into the composition. The presence of this additive enhances the crystallization velocity of the composition and permits the achievement of crystalline parts with optimum properties with colder molds and shorter molding cycles than are conventional for polyethylene terephthalate molding compositions.

Claims

1. A process for injection molding a thermoplastic composition comprising:

(a) intimately blending (i) from 80 to 97% by weight of a polyethylene terephthalate having an intrinsic viscosity of at least 0.3 dl/g measured as a 0.5% by solution in in a 1;

1 mixture of phenol and tetrachloroethane at 25°

C.; and

(ii) from 3 to 20% by weight of an organic compound containing at least one imide group and having a melting point greater than 240°

C., and

(b) injecting molding said blend into a mold held at a temperature of no more than 110°

C. and of no less than 80°

C.