Laser pyrographic reflective recording layer in a carbon containing absorptive matrix

• US 4,314,260 A
• Filed: 03/18/1980
• Issued: 02/02/1982
• Est. Priority Date: 02/14/1979
• Status: Expired due to Term

• Current Assignee: LaserCard Corp. (Assa Abloy AB)
• Original Assignee: Drexler Technology Corporation (Assa Abloy AB)
• Inventors: Drexler, Jerome
• Primary Examiner(s): MILLER JR, GEORGE
• Application Number:
  US06/131,288
• Time in Patent Office: 686 Days
• Field of Search: 346/76 L, 346/135.1
• US Class Current: 346/135.1
• CPC Class Codes: G03C 5/40 Chemically transforming developed images G03C5/50 takes precedence
• CPC Class Codes: G11B 7/0045 Recording G11B7/006, G11B7/0065 take precedence
• CPC Class Codes: G11B 7/007 Arrangement of the information on the record carrier, e.g. form of tracks , actual track shape, e.g. wobbled, or cross-section, e.g. v-shaped; Sequential information structures, e.g. sectoring or header formats within a track
• CPC Class Codes: G11B 7/00736 Auxiliary data, e.g. lead-in, lead-out, Power Calibration Area [PCA], Burst Cutting Area [BCA], control information sector headers or adresses in prepits G11B7/00745; address data in track wobble G11B7/24082
• CPC Class Codes: G11B 7/251 comprising inorganic materials dispersed in an organic matrix

Abstract

A recording medium for laser writing and a method of making same wherein a silver-halide emulsion coating disposed on a substrate is strongly exposed to actinic radiation and then developed, or otherwise processed for maximum blackness. The black opaque emulsion is converted to a reflective recording medium by heating at least to 270° C. in an oxygen containing environment until the emulsion coating assumes a shiny reflective appearance and the gelatin partially pyrolyzes creating a carbon containing absorptive matrix. Prior to developing, patterns may be photographically imposed on the medium to provide control indicia for the recording system or data base information to a playback system or to provide a means of replicating master recordings.

Claims

1. An information storage medium for pyrographically recording laser writing comprising a reflective surface coating of at least 15% reflectivity disposed on a sheet substrate, the reflective coating comprising reflective silver particles distributed within a gelatin matrix.

2. The information storage medium of claim 1 wherein said reflective coating has a reddish or amber color underlayer disposed between said reflective coating and the substrate.

3. The medium of claim 2 wherein said reddish or amber color is derived from carbon molecules.

4. The information storage medium of claim 1 or 2 wherein said substrate is capable of withstanding temperatures of at least 270°

C.

5. In laser pyrographic information recording and storage, the recording and storage medium comprising,

a sheet substrate capable of withstanding temperatures of at least 270°

C., said substrate supporting a photographic gelatin coating, said gelatin coating having silver particles distributed within a gelatin matrix, said gelatin matrix optically characterized by a surface reflective silver component of at least 15% reflectivity thereon and an underlying reddish or amber color derived from unreacted carbon molecules.

6. The medium of claim 5 wherein said reflective silver component has a concentration gradient whereby the silver concentration is greatest at the surface of said component and diminishes in a direction away from said surface.

7. The medium of claim 5 wherein said reflective silver component extends throughout said coating.

8. The recording and storage medium of claim 5 wherein said gelatin matrix contains a density of carbon molecules sufficient to create an optical absorptivity at 633 nanometers of at least 10%.

9. The medium of claim 5 wherein said substrate is transparent.

10. The medium of claim 5 wherein said substrate is absorptive of radiation of wavelengths of a recording beam.

11. The medium of claim 5 wherein said substrate is absorptive of radiation of wavelengths of a reading beam.

12. The medium of claim 5 wherein said substrate is absorptive of radiation of wavelengths of both a recording beam and a reading beam.

13. A medium of claim 5 wherein substrate is glass.

14. The medium of claim 5 wherein the substrate is ceramic.

15. The medium of claim 5 wherein the substrate is a thermoset polyimide plastic.

16. The medium of claim 5 wherein the substrate is a thermoplastic polyimide plastic.

17. The medium of claim 5 wherein said photographic emulsion is of the type used in the manufacture of photomasks for semiconductor integrated circuits.

18. The medium of claim 5 wherein said photographic gelatin coating comprises silver grains having primarily grain sizes less than 0.07 microns.

24. The method of claim 18 wherein said step of photographic processing includes photographically defining in the emulsion areas for recording data by laser pyrographic means and areas set aside for no laser pyrographic recording.

25. The method of claim 18 wherein said step of photographic processing includes photographically defining in the emulsion lines defining servo tracks.

26. The method of claim 18 wherein said step of photographic processing includes photographically defining in the emulsion lines defining control indicia.

27. The method of claim 24 wherein said step of photographic processing includes recording data base data indicia in a photographically defined area set aside for no laser pyrographic recording.

19. A method of making a laser pyrographic information and storage medium comprising,

photographically processing a silver-halide gelatin coating on a substrate to blackness, and

thermally converting said black photographically processed silver-halide gelatin coating by heating at least to 270°

in an atmosphere having a substantial percentage of oxygen at least until a reflective component of at least 15% reflectivity appears on the emulsion coating.

20. The method of claim 19 wherein said heating is carried out in an oxygen atmosphere.

21. The method of claim 19 wherein said heating is carried out in air.

22. The method of claim 19 wherein said heating is carried out at least until the gelatin is pyrolyzed to the extent that the gelatin has at least a 10% optical absorptivity at 633 nanometers.

23. The method of claim 19 wherein said heating is by means of radiant heating.

28. The method of claim 19 wherein said heating is carried out for a time of between one-half minute and 20 minutes.

29. The method of claim 19 wherein said heating is carried out for a time of between four and six minutes.

30. The method of claim 19 wherein said step of photographically processing said silver-halide emulsion is by applying a fogging developer.

31. The method of claim 19 wherein said blackness of said processed emulsion coating has an optical density to white light of 2.5 or greater.

32. The method of claim 19 wherein said step of photographically processing said silver-halide emulsion is further defined by the steps of

exposing said silver-halide emulsion coating on a substate to actinic radiation, and

developing said silver-halide enulsion coating.

33. The method of claim 32 wherein said developing is by heating.

34. The method of claim 32 wherein said developing is by chemical means.

35. The method of claim 34 wherein said developing by chemical means is by negative processing.

36. The method of claim 34 wherein said developing by chemical means is by reversal processing.