High voltage series connected tandem junction solar battery

• US 4,316,049 A
• Filed: 09/29/1980
• Issued: 02/16/1982
• Est. Priority Date: 08/28/1979
• Status: Expired due to Term

• Current Assignee: RCA Corporation
• Original Assignee: RCA Corporation
• Inventors: Hanak, Joseph J.
• Primary Examiner(s): Weisstuch, Aaron
• Application Number:
  US06/192,333
• Time in Patent Office: 505 Days
• Field of Search: 136/244, 136/249, 136/255, 136/258, 357/2, 357/30
• US Class Current: 136/244
• CPC Class Codes: H01L 31/022466 made of transparent conductive layers, e.g. TCO, ITO layers
• CPC Class Codes: H01L 31/022475 composed of indium tin oxide [ITO]
• CPC Class Codes: H01L 31/046 PV modules composed of a plurality of thin film solar cells deposited on the same substrate
• CPC Class Codes: H01L 31/076 Multiple junction or tandem solar cells
• CPC Class Codes: Y02E 10/548 Amorphous silicon PV cells

Abstract

A high voltage series connected tandem junction solar battery which comprises a plurality of strips of tandem junction solar cells of hydrogenated amorphous silicon having one optical path and electrically interconnected by a tunnel junction. The layers of hydrogenated amorphous silicon, arranged in a tandem configuration, can have the same bandgap or differing bandgaps. The tandem junction strip solar cells are series connected to produce a solar battery of any desired voltage.

Claims

1. An amorphous silicon solar battery comprising:

(a) a transparent substrate having a major surface which is incident to solar radiation and an opposed major surface;

(b) a plurality of spaced apart transparent conductive oxide strips on said opposed major surface;

(c) a plurality of tandem-junction, hydrogenated amorphous silicon solar cells fabricated over and electrically contacting a major portion of each of said transparent conductive oxide strips, said solar cells having a plurality of semiconductor layers of hydrogenated amorphous silicon having regions of differing conductivity type wherein said layers are separated by a tunnel junction, said solar cells having width such that the loss of power is less than the loss of power from the incorporation of a metallic grid electrode into the transparent conductive oxide; and

(d) means for interconnecting said solar cells in series.

2. The solar battery according to claim 1, wherein said layers of hydrogenated amorphous silicon have a region of P type conductivity which forms the incident region of said layer, a region of intrinsic amorphous silicon contiguous to said P type region and a region of N type conductivity contiguous to said intrinsic region.

3. The solar battery according to claim 2 wherein said tunnel junction is formed between the N type region of an incident layer of amorphous silicon and the P type region of the subsequent layer of amorphous silicon.

4. The solar battery according to claim 3 wherein said means for connecting said solar cells in series is an electrically conductive material, wherein said electrically conductive material contacts a side of said solar cell and a surface of said solar cell opposite to a surface which is incident to solar radiation and an adjacent transparent conductive oxide strip.

5. The solar battery according to claim 3 wherein said tunnel junction is a layer of Pt-SiO₂ cermet.

6. The solar battery according to claim 3 wherein said tunnel junction is a layer of Pt-SiO₂ cermet and a transparent metal layer.

7. The solar battery according to claim 6 wherein said transparent metal layer is disposed between said cermet and said N type region of the semiconductor layer.

8. The solar battery according to claim 2 wherein the thickness of each intrinsic region of each semiconductor layer increases from the incident semiconductor layer.

9. The solar battery according to claim 8, wherein said means for interconnecting said solar cells in series is a metal layer.

10. The solar battery according to claim 1 wherein said means for interconnecting said solar cells in series is a metal layer.

11. The solar battery according to claim 1 wherein said means for connecting said solar cells in series is an electrically conductive material, wherein said electrically conductive material contacts a side of said solar cell and a surface of said solar cell opposite to a surface which is incident to solar radiation and an adjacent transparent conductive oxide strip.

12. The solar battery according to claim 1 wherein the energy bandgap of said semiconductor layers decreases from the incident semiconductor layer to subsequent semiconductor layers.

13. The solar battery according to claim 10, wherein the tandem-junction solar cells have from 2 to 5 semiconductor layers.

14. The solar battery according to claim 1 wherein the width of each tandem junction solar cell strip is determined according to the following formula:

##EQU2## wherein V_oc is the total open circuit voltage of the solar battery, J_sc is the short circuit current density, F is the fill factor, R.sub.□

is the sheet resistivity of the transparent conductive oxide, N is the number of solar cell strips in the solar battery, and f is a factor related to the percentage of power lost in the front electrode and is selected so as to be less than the power loss of a grid electrode due to the shielding effect of said grid electrode.

15. The solar battery according to claim 14 wherein W is from about 0.2 cm to about 5.0 cm.

16. The solar battery according to claim 15 wherein W is from about 0.2 cm to about 2.0 cm.