X-Ray image converters utilizing rare earth admixtures

• US 4,316,092 A
• Filed: 08/25/1980
• Issued: 02/16/1982
• Est. Priority Date: 12/13/1976
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Rabatin, Jacob G.
• Primary Examiner(s): Dixon, Harold A.
• Application Number:
  US06/180,845
• Time in Patent Office: 540 Days
• Field of Search: 250/483, 250/460, 250/475
• US Class Current: 250/483.1
• CPC Class Codes: C09K 11/7767 Chalcogenides
• CPC Class Codes: G21K 4/00 Conversion screens for the conversion of the spatial distribution of X-rays or particle radiation into visible images, e.g. fluoroscopic screens photographic processes using X-ray intensifiers G03C5/17; discharge tubes comprising luminescent screens H01J1/62; cathode ray tubes for X-ray conversion with optical output H01J31/50

Abstract

Various rare earth phosphor admixtures are described utilizing thulium-activated oxyhalides of lanthanum and/or gadolinium to provide improved performance in x-ray image converter devices. These phosphor admixtures are used in radiographic screens in combination with either blue sensitive or green sensitive photographic film.

Claims

1. An improved multi-layer x-ray screen construction which comprises:

(a) a photographic film having emulsion layers disposed on each major surface and separated by an optically transparent support,

(b) a pair of phosphor layers being positioned on each side of said photographic film to form a sandwich configuration, and

(c) each of said phosphor layers comprising an admixture of polyhedral terbium activated gadolinium oxysulfide phosphor crystals having an average particle size in the range of approximately 6 to about 20 microns

in combination with plate-like crystals having an average particle size in the range from approximately 2 to about 12 microns having the general formula;

space="preserve" listing-type="equation">LnOX;

Tm.sup.3+

wherein

Ln is one or more of La and Gd,

X is one or more of Cl and Br, and

Tm is present as an activator ion from about 0.05 to about 1 mole percent,

said phosphor admixture exhibiting improved resolution capability and reduced crossover problem.

2. An improved x-ray screen as in claim 1 wherein said phosphor admixture contains approximately 20-80 parts by weight of said terbium activated gadolinium oxysulfide phosphor with approximately 20-80 parts by weight of said other phosphor.

3. An improved x-ray screen as in claim 1 wherein said photographic film is particularly sensitive to light in the blue color region and said phosphor admixture contains less parts by weight of said terbium activated gadolinium oxysulfide phosphor than parts by weight of said other phosphor.

4. An improved x-ray screen as in claim 1 wherein said photographic film is particularly sensitive to light in the green color region and said phosphor admixture contains about equal parts by weight of both phosphors.

5. An improved x-ray screen as in claim 1 wherein said photographic film further includes an ultraviolet absorbing dye for cooperation in reducing the crossover through said support.

6. An improved x-ray screen as in claim 1 which further includes light reflecting layers positioned adjacent the exteriormost major surfaces of the phosphor layers.

7. An improved x-ray screen as in claim 1 wherein said photographic film is particularly sensitive to light in the green color region and the terbium activator level in the terbium activated gadolinium oxysulfide phosphor is from about 0.1 to about 15.0 mole percent.

8. An improved x-ray screen as in claim 1 wherein said photographic film is particularly sensitive to light in the blue color region and the terbium activator level in the gadolinium oxysulfide phosphor is from about 0.1 to about 0.5 mole percent.